• Title/Summary/Keyword: Precipitation change

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A Study on the High Frequency Ultrasonic Attenuation Characterization in Artificially Aging Degraded 2.25Cr-1Mo Steel (2.25Cr-1Mo 강 인공 열화재의 고주파수 초음파 감쇠특성에 관한 연구)

  • Park, Ik-Keun;Park, Un-Su;Kim, Chung-Seok;Kim, Hyun-Mook;Kwun, Sook-In;Byeon, Jai-Won
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.4
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    • pp.439-445
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    • 2001
  • The destructive method is reliable and widely used lot the estimation of material degradation but, it have time-consuming and a great difficulty in preparing specimens from in-service industrial facilities. Therefore, the estimation of degraded structural materials used at high temperature by nondestructive evaluation such as electric resistance method, replica method, Barkhausen noise method, electro-chemical method and ultrasonic method are strongly desired. Ultrasonic nondestructive evaluation technique has been reported good to attain efficiency of measurement, high sensitivity of measurement, and rapidity and reliability of result interpretation. In this study, it was verified experimentally the feasibility of the evaluation of degraded 2.25Cr-1Mo steel specimens which were prepared by the isothermal aging heat treatment at $630^{\circ}C$ by high frequency longitudinal wave method investigating the change of attenuation coefficient by FFT analysis and wavelet transform. Because of carbide precipitation increase and spheroidization near grain boundary of microstructure to aging degradation, attenuation coefficient had a tendency to increase as degradation proceeded. It was identified possibly to evaluate degradation using the characteristics of high-frequency ultrasonics. Frequency dependence of ultrasonic attenuation coefficient to aging degradation appeared large, which made sure that attenuation coefficient is an important parameter for evaluation of aging degradation.

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Development of Realtime Dam's Hydrologic Variables Prediction Model using Observed Data Assimilation and Reservoir Operation Techniques (관측자료 동화기법과 댐운영을 고려한 실시간 댐 수문량 예측모형 개발)

  • Lee, Byong Ju;Jung, Il-Won;Jung, Hyun-Sook;Bae, Deg Hyo
    • Journal of Korea Water Resources Association
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    • v.46 no.7
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    • pp.755-765
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    • 2013
  • This study developed a real-time dam's hydrologic variables prediction model (DHVPM) and evaluated its performance for simulating historical dam inflow and outflow in the Chungju dam basin. The DHVPM consists of the Sejong University River Forecast (SURF) model for hydrologic modeling and an autoreservoir operation method (Auto ROM) for dam operation. SURF model is continuous rainfall-runoff model with data assimilation using an ensemble Kalman filter technique. The four extreme events including the maximum inflow of each year for 2006~2009 were selected to examine the performance of DHVPM. The statistical criteria, the relative error in peak flow, root mean square error, and model efficiency, demonstrated that DHVPM with data assimilation can simulate more close to observed inflow than those with no data assimilation at both 1-hour lead time, except the relative error in peak flow in 2007. Especially, DHVPM with data assimilation until 10-hour lead time reduced the biases of inflow forecast attributed to observed precipitation error. In conclusion, DHVPM with data assimilation can be useful to improve the accuracy of inflow forecast in the basin where real-time observed inflow are available.

High temperature oxidation behavior and surface modification of Ni-based superalloys (니켈기 초합금의 고온산화거동과 표면개질에 관한 연구)

  • Seol, Gyeong-Won
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.166-176
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    • 1994
  • Ni base superalloys are composed of solid sohltion hardening elements(Co, Cr. Mo. W and so on) and $\gamma '$ precipitation hardening elements(A1, Ti, Nb, Ta and so on). To Improve the mechanical properties and oxidation resistanre of superalloys, rare earth elements(%r, Hf, Y and so on) are added to the inner substrate, or are used as coating materials. Their pffects on the growth rate and adhes~on of oxide are changed according to the kinds of oxides such as $AI_2O_3$ and $Cr_2O_3$. The effect of yttrium on the oxidation rate, grain size of oxide, internal structure, and crack resistance was investigated for two kinds of Ni-base superalloys. One in AF'115 superalloy containing Hf and the other is MA6000 superalloy containing $Y_2O_3$. They werr owid~zed at high temperature after yttrium surface modification using ion coater. Yttrium coating on the AF115 and MA6000 superalloys results in a marked change in the growth of the inner oxide. For AF115 superalloy, the degree of gram boundary segregation of $Cr_2O_3$, and prefer en^ tial oxidation of Hf are decreased, and the shape of inner oxidation layer was changed from triangle to plate type. For MA6000 superalloy, $Cr_2O_3$ oxide scale was transformed as outer oxidation layer of CrZOI and inner oxidation layer of $Cr_2O_3$.

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Screening of saline tolerant plants and development of biological monitoring technique for saline stress . 1. Survey of vegetation in saline region and determination of saline tolerance of the plant species of the region. (내염성 식물의 탐색 및 생물학적 염해 모니터링 기술의 개발 1. 염해지 식생분석 및 식물종의 내염성 평가)

  • Kang, Byeung-Hoa;Shim, Sang-In
    • Korean Journal of Environmental Agriculture
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    • v.17 no.1
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    • pp.26-33
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    • 1998
  • This experiment was conducted to classify the plant species occurring in the saline reclaimed land by saline tolerance. The vegetation of reclaimed land was composed of various plant species from halophyte to glycophyte showing different saline tolerances. In the investigated saline region, reclaimed land of Youngjong island, Inchun city, 175 species belonging to 32 families were found. Our survey was carried out in two region, having different salinity due to different desalinization. The electricalconductivity (EC) of more saline region showed 48.0mS/cm nd the other region showed 13.0mS/cm. It is assumed that intensity of precipitation and runoff of rainfall may cause salinity gradient in the investigated region. The plant species occurred in the experimental region were classified as 72 species of annual, 42 species of biennial, and 61 species of perennial according to life cycle. For knowing relationship between vegetation of saline region and saline tolerance of occurring species, we tested the saline susceptibility of plant species collected at the saline regions. Testing plants were cultured by nutrient solution containing 200 mM NaCl, the critical concentration of survival in glycophytes. The saline tolerance was graded by the growing capacity in the sand-culture system. The more saline-tolerant species screened by sand culture were Atriplex gmelini, Suaeda asparagoides, Aster tripolium, Suaeda maritima, Salicornia herbacea, and Suaeda japonica. The most saline tolerant family was Chenopodiaceae. Poaceae, Cyperaceae, and Brassicaceae showed relatively high tolerance to saline stress. In the course of growth under the high saline condition, the most noticeable change was the darkening of leaves by increasing of chlorophyll content. The chlorophyll contents were increased with saline stress in most species.

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Genetic Environments of Hydrothermal Copper Deposits in Ogsan Mineralized Area, Gyeongsangbukdo Province (경북 옥산지역 열수동광상의 성인연구)

  • Choi, Seon-Gyu;Choi, Sang-Hoon;Yun, Seong-Taek;Lee, Jae-Ho;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.25 no.3
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    • pp.233-243
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    • 1992
  • Ore mineralization of the Hwanghak copper deposit in the Ogsan area occurred in three stages of quartz (stage I and II) and calcite (stage III) veining along fissures in Early Cretaceous sedimentary rocks. Ore minerals are pyrite, pyrrhotite, chalcopyrite (dominant), sphalerite, hematite, galena, and Ag-, Pb-, and Bi-sulfosalts. These were deposited during the first stage at temperatures between $370^{\circ}C$ and < $200^{\circ}C$ from fluids with salinities between 0.5 and 7.6 equiv. wt. % NaCl. There is evidence of boiling and this suggests pressures of less than 180 bars during the first stage. Equilibrium thermodynamic interpretation accompanying with mineral paragenesis and fluid inclusion data indicates that copper precipitation in the hydrothermal system occurred due to cooling and changing in chemical conditions ($fs_2$, $fo_2$, pH). Gradual temperature decrease from $350^{\circ}$ to $250^{\circ}C$ of ore fluids by boiling and mixing with less-evolved meteoric waters mainly led to copper deposition through destabilization of copper chloride complexes. Sulfur isotope values of sulfide minerals decrease systematically with paragenetic time from calculated ${\delta}^{34}S_{H_2S}$ values of 8.2 to 4.7‰. These values, together with the observed change from sulfide-only to sulfide-hematite assemblages and fluid inclusion data, suggest progressively more oxidizing conditions, with a corresponding increase of the $sulfate/H_2S$ ratio of hydrothermal fluids. Measured and calculated hydrogen and oxygen isotope valutls of ore-forming fluids suggest meteoric water dominance, approaching unexchanged meteoric water values.

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Studies on Fluid Inclusion and Pyrite Geochemistry in the Moisan Au-Ag Deposit, Haenam District, Korea (해남 모이산 금-은 광상의 유체포유물 및 황화물 지구화학 연구)

  • Park, Sol;Seo, Jung Hun;Kim, Chang Seong;Yang, Yoon-Seok;Oh, Jihye;Kim, Jonguk
    • Economic and Environmental Geology
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    • v.53 no.3
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    • pp.221-234
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    • 2020
  • We occur together with telluride minerals. Fluid inclusions in the euhedral quartz crystals are mainly aqueous liquid-rich inclusions, which have salinities about 0.18-2.24 wt% NaCl equivalent. Some quartz vein contains aqueous vapor-rich inclusions as well. Homogenization temperatures of the assemblages of the liquid-rich inclusions are about 141-384 ℃, and the temperatures are lower at the shallower vein samples. In the high Au-Ag grade depth intervals, relatively deeper fluids have relatively higher salinities and homogenization temperatures, while shallower fluids show somewhat wider ranges. These might indicate that the deep Au-Ag bearing hydrothermal fluids at the Moisan area experienced phase separation as well as mixing with meteoric water by decreasing pressure. Au-Ag precipitation in the Moisan deposit is not associated with pyrite, but pyrite include Au-Ag bearing phase as an inclusion, which might possibly be tellurides or electrum. Au/Ag ratios in the Au-Ag bearing phase do not change with different depth.

Thermal Behavior of (Co0.5 Mn0.5)Fe2O4 for Hydrogen Generation by Thermochemical Cycle (열화학 사이클 H2 제조를 위한 (Co0.5 Mn0.5)Fe2O4의 열적 거동)

  • Shin, H.C.;Choi, S.C.;Kim, C.S.;Kim, J.W.;Joo, O.S.;Jung, K.D.
    • Journal of Hydrogen and New Energy
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    • v.13 no.2
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    • pp.143-150
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    • 2002
  • The thermal behavior of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ prepared by a co-precipitation wasinvestigated for Hz generation by the thermochemical cycle. The reduction reaction of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ started from $480^{\circ}C$, and the weight loss was 1.6 wt% up to $1100^{\circ}C$. At this reaction, $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ was reduced by release of oxygen bonded with the $Fe^{3+}$ ion in the B site of ($CO_{0.5}$ $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidationof reduced $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$. The crystal structure of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ for reduction reaction maintained spinel structure and the lattice constant of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ ($8.41\AA$) was enlarged to $8.45\AA$. But the lattice constant of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ after $H_2O$ decomposition reaction did not change to $8.45\AA$. Then, $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ is excellent material in the thermochemical cyclic reaction due to release oxygen at low temperature for the reduction reaction and produce $H_2$ maintaining crystal structure for redox reaction.

Antibacterial Activity and Probiotic Potential of Lactobacillus plantarum HKN01: A New Insight into the Morphological Changes of Antibacterial Compound-Treated Escherichia coli by Electron Microscopy

  • Sharafi, Hakimeh;Maleki, Hadi;Ahmadian, Gholamreza;Zahiri, Hossein Shahbani;Sajedinejad, Neda;Houshmand, Behzad;Vali, Hojatollah;Noghabi, Kambiz Akbari
    • Journal of Microbiology and Biotechnology
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    • v.23 no.2
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    • pp.225-236
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    • 2013
  • Among several bacteria examined, an antibacterial-producing Lactobacillus strain with probiotic characteristics was selected and identified based on 16S rRNA gene sequencing. Subsequent purification and mode of action of the antibacterial compounds on target cells including E. coli were investigated. Maximum production of the antibacterial compound was recorded at 18 h incubation at $30^{\circ}C$. Interestingly, antibacterial activity remained unchanged after heating at $121^{\circ}C$ for 45 min, 24 h storage in temperature range of $70^{\circ}C$ to room temperature, and 15 min exposure to UV light, and it was stable in the pH of range 2-10. The active compounds were inactivated by proteolytic enzymes, indicating their proteinaceous nature, and, therefore, referred to as bacteriocin-like inhibitory substances. Isolation and partial purification of the effective agent was done by performing ammonium sulfate precipitation and gel filtration chromatography. The molecular mass of the GFC-purified active compound (~3 kDa) was determined by Tris-Tricine SDS-PAGE. To predict the mechanisms of action, transmission electron microscopy (TEM) analysis of ultrathin sections of E. coli before and after antibacterial treatment was carried out. TEM analysis of antibacterial compounds-treated E. coli demonstrated that the completely altered bacteria appear much darker compared with the less altered bacteria, suggesting a change in the cytoplasmic composition. There were also some membrane-bound convoluted structures visible within the completely altered bacteria, which could be attributed to the response of the E. coli to the treatment with the antibacterial compound. According to the in vivo experiments oral administration of L. plantarum HKN01 resulted in recovery of infected BALB/c mice with Salmonella enterica ser. Typhimurium.

Atmospheric Dispersion Characteristics of Radioactive Materials according to the Local Weather and Emission Conditions

  • An, Hye Yeon;Kang, Yoon-Hee;Song, Sang-Keun;Kim, Yoo-Keun
    • Journal of Radiation Protection and Research
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    • v.41 no.4
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    • pp.315-327
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    • 2016
  • Background: This study evaluated the atmospheric dispersion of radioactive material according to local weather conditions and emission conditions. Materials and Methods: Local weather conditions were defined as 8 patterns that frequently occur around the Kori Nuclear Power Plant and emission conditions were defined as 6 patterns from a combination of emission rates and the total number of particles of the $^{137}Cs$, using the WRF/HYSPLIT modeling system. Results and Discussion: The highest mean concentration of $^{137}Cs$ occurred at 0900 LST under the ME4_1 (main wind direction: SSW, daily average wind speed: $2.8ms^{-1}$), with a wide region of its high concentration due to the continuous wind changes between 0000 and 0900 LST; under the ME3 (NE, $4.1ms^{-1}$), the highest mean concentration of $^{137}Cs$ occurred at 1500 and 2100 LST with a narrow dispersion along a strong northeasterly wind. In the case of ME4_4 (S, $2.7ms^{-1}$), the highest mean concentration of $^{137}Cs$ occurred at 0300 LST because $^{137}Cs$ stayed around the KNPP under low wind speed and low boundary layer height. As for the emission conditions, EM1_3 and EM2_3 that had the maximum total number of particles showed the widest dispersion of $^{137}Cs$, while its highest mean concentration was estimated under the EM1_1 considering the relatively narrow dispersion and high emission rate. Conclusion: This study showed that even though an area may be located within the same radius around the Kori Nuclear Power Plant, the distribution and levels of $^{137}Cs$ concentration vary according to the change in time and space of weather conditions (the altitude of the atmospheric boundary layer, the horizontal and vertical distribution of the local winds, and the precipitation levels), the topography of the regions where $^{137}Cs$ is dispersed, the emission rate of $^{137}Cs$, and the number of emitted particles.

Synthesis of $TiO_2$Anchored on a Porous Clay Ceramic Support Using Dropping Precipitant Method (침전제 적하법을 이용한 $TiO_2$고정화 다공체 제조)

  • 신대용;한상목;김경남
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1097-1103
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    • 2001
  • TiO$_2$anchored on a porous clay ceramic support (PCS) for use in lightweight photocatalyst were synthesized by the dropping precipitant method. A PCS of macro and micro pore size of around several mm~${\mu}{\textrm}{m}$ in diameter were prepared by the rapid heat treatment at, 1,15$0^{\circ}C$ for 10 min from low grade of clay. The change in pH of reaction solution due to the different addition rate of NH$_4$HCO$_3$as a precipitant, the reaction temperature and the concentration of TiCl$_4$had a pronounced effect on the nature of precipitated TiO$_2$particles on the surface of a PCS and the crystal structure of precipitated TiO$_2$particles. At an addition rate of 0.8 ml/min of NH$_4$HCO$_3$and pH=6 of reaction solution, homogeneous precipitation of TiO$_2$particles on a PCS was achieved. TiO$_2$particles with anatase phase was precipitated on the surface of a PCS at the low concentration of TiCl$_4$, the high addition rate of NH$_4$HCO$_3$and the high reaction temperature.

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