• Korean Journal of Soil Science and Fertilizer
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• v.40 no.2
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• pp.151-155
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• 2007

The issue of acid precipitation and related environmental problems in East Asia have been emerging. To evaluate the acidity and chemical characteristics of rainwater in Korea, its chemical properties during crop cultivation season from April to October were investigated at Suwon, Korea. Also, to estimate the contribution of ions on its acidity, ion composition characteristics and neutralization effects by cation ions were determined. Ion balance and electrical conductivity balance between the measured and estimated values showed high correlation. Rainwater had distributed highly in the range of pH 4.5~5.6. The pH of rainwater was relatively high at June as compared with other monitoring periods. $Na^+$ was the main cation followed by $NH_4{^+}$, $Ca^{2+}$, $H^+$ > $K^+$ > $Mg^{2+}$. Among these, $Na^+$, $NH_4{^+}$, $Ca^{2+}$ and $H^+$ covered over 93% of total cations. About 86% of anion in rainwater was composed of $SO{_4}^{2-}$ and $NO_3{^-}$. In rainwater samples, $NH_4{^+}$ and $Ca^{2+}$ contributed greatly to neutralization of the rain acidity. Also, 88% of soluble sulfate in rainwater was nss-$SO{_4}^{2-}$(non-sea salt sulfate).

• Progress in Superconductivity and Cryogenics
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• v.18 no.1
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• pp.28-32
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• 2016

There are a few thousand abandoned metal mines in South Korea. The abandoned mines cause several environmental problems including releasing acid mine drainage (AMD), which contain a very high acidity and heavy metal ions such as Fe, Cu, Cd, Pb, and As. Iron oxides can be formed from the AMD by increasing the solution pH and inducing precipitation. Current study focused on the formation of iron oxide in an AMD and used the oxide for adsorption of heavy metals. The heavy metal adsorbed iron oxide was separated with a superconducting magnet. The duration of iron oxide formation affected on the type of mineral and the degree of magnetization. The removal rate of heavy metal by the adsorption process with the formed iron oxide was highly dependent on the type of iron oxide and the solution pH. A high gradient magnetic separation (HGMS) system successfully separated the iron oxide and harmful heavy metals.

• Journal of the Korean institute of surface engineering
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• v.50 no.4
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• pp.231-236
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• 2017

The present work addresses how to measure the amount of dissolved aluminum in phosphoric acid, based on volumetric and gravimetric measurements of the precipitates formed by reaction between the $H_3PO_4$ solution containing dissolved aluminum ions and 10 % KF solution. The volume of the precipitates increased with dilution of the dissolved aluminum-containing $H_3PO_4$ solution up to 1/4 dilution above which it decreased with further dilution. The lowered amounts of the precipitates at low dilution less than 1/4 and high dilution more than 1/4 are attributed to high acidity of the solution and decreased amount of dissolved aluminum in the solution, respectively. Volumetric measurement of the amount of precipitates was found not to be very reliable with the experiments, while weight measurement of the precipitates after drying for 80 min at $60^{\circ}C$ appeared to be very reproducible. In the present work, it is suggested that the amount of Al dissolved in 85 % $H_3PO_4$ solution can be calculated by multiplying 50 to the weight of precipitate obtained by reacting 8 ml of 1/4 diluted $H_3PO_4$ solution containing dissolved aluminum ions with 6 ml of 10 % KF solution.

• Journal of the Korean Ceramic Society
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• v.33 no.7
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• pp.823-831
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• 1996

Due to the intrinsic low surface activation of ${\gamma}$-alumina it has been used limitely in practice. Accordingly forward enhancing its utility ${\gamma}$-alumina surface was treated with slfuricf aicd nitric acid and chloric acid respec-tively. Subsequently the effects of surface activity on the surface electrical characteristics were investigated. The ${\gamma}$-alumina was prepared by the precipitation of aluminium nitrate [Al(NO3)3.9H2O] using ammonia water as a precipitator and it was chemically treated with such acids mentioned above. The surface and morphology of the acid-treated ${\gamma}$-alumina were analysed by XRD, BET and the surface activities were measured by the amine titration methods. The interfacial properties of the ${\gamma}$-alumina dispersed in electrolyte solution were esti-mated by the surface charge density measured using potentiometric tiration. Based on the relation between surface charge density and the acid amount the following results were drawn for the surface and interfacial electrical properties ; Acidic properties of surface-treated alumina increase with anion load on alumina surface. P. Z. C decreases with acid amount on alumina surface. The surface charge densities were apart from electrolyte ionic strength. The acidity of ${\gamma}$-alumina is linearly dependent on the P. Z,.C when the ${\gamma}$-alumina was dispersed in aqueous electrolyte solution.

• Journal of the Korean Wood Science and Technology
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• v.21 no.2
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• pp.9-14
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• 1993

Weathering of wood in a region of acid rain was performed by the test which thin veneers of Sitka spruce were exposed to outdoor weathering for a total of 18 weeks, with a daily soaking for 30 minutes in acidified water in the pH range 2~5.6. The weathering measured by weight loss and loss in maximum failure load in tension was accelerated by the increase in the acidity of acidified water and in the period of outdoor exposure. It was also shown that the weathering was accelerated even with low acidic conditions in the case of long exposure period, although the weathering was rapidly accelerated with high acidic conditions. When compared the degree of weight loss with that of loss in failure load by weathering, the latter was much greater. From the results of this research, it could be concluded that at pH 4.0 or below of precipitation, the acceleration of weathering of exterior wood would become serious problems, which would be caused deterioration in performance of exterior wood.

• Food Science and Preservation
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• v.6 no.4
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• pp.424-428
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• 1999

The performance of a 30K polysulfone membrane for clarification of depectinized peach juice was studied Ultrafiltration of peach juice could minimize to loss of flavor and many compounds and was expected to effectively remove precipitation and suspended solid. The results showed that permeate flux increased with the increase of operating pressure and temperature. The permeate flux declined continuously as the process time increased. The values of soluble solid and titratable acidity of permeate were decreased or were at the same level, the turbidity was largely decreased. Total resistance decreased with lower temperature and lower pressure.

• Journal of Korean Society of Forest Science
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• v.83 no.4
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• pp.460-472
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• 1994

This study has been conducted to give some ideas for reasonable ecological management of Taejon city and its adjacent forest ecosystem against the effect of acid rain. Rain monitoring points to analyse its components represented 1 point in industrial area, 4 points in commercial area, 4 points in residential area, and 5 points in suburban area and forest survey was done in 7 forest sites adjacent to rain monitoring points. Transformed vegetation index(TVI) based on Landsat TM data was analysed for forest area. Taejon area was seriously contaminated by air pollutants and average concentration of anions in precipitation were 20.16mg/l for $SO_4{^{2-}}$, 3.65mg/l for $NO_3{^-}$, and 3.09mg/l for $Cl^-$. Anion in precipitation were $1.09mg/m^2/month$ for $SO_4{^{2-}}$, $0.23mg/m^2/month$ for $NO_3{^-}$, and $0.20mg/m^2/month$ for $Cl^-$. Cation in precipitation were $0.14mg/m^2/month$ for $Ca^{2+}$, $0.10mg/m^2/month$ for $NH_4{^+}$, $0.08mg/m^2/month$ for $Na^+$, $0.07mg/m^2/month$ for $K^+$, and $0.08mg/m^2/month$ for $Mg^{2+}$. The region with the highest concentration of $SO_4{^{2-}}$, $NO_3{^-}$, and $Cl^-$ in rain was industrial area. $SO_4{^{2-}}$, $NO_3{^-}$, and $Cl^-$ concentrations in industrial area were 43.08, 3.88, and 3.64ppm, respectively. Forest soil showed strongly acidic ranging pH4.16-4.94. Transformed vegetation index(TVI) were 3.11 in Dangsan, 4.00 in Kyechoksan, 4.13 in Bomunsan, 4.18 in Kabhasan, 3.34 in Bongsan, 4.13 in Sikchangsan, and 4.20 in Seongchisan. Dangsan forest located near in industrial area showed the lowest TVI.

• Korean Journal of Remote Sensing
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• v.36 no.6_3
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• pp.1669-1679
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• 2020

This study examines the washing effect of precipitation on particulate matter (PM) and the rainwater quality (pH, electrical conductivity (EC), water-soluble ions concentration). Of six rain events in total, rainwater samples were continuously collected every 50 mL from the beginning of the precipitation using rainwater collecting devices at Pukyong National University, Busan, South Korea, from March 2020 to July 2020. The collected rainwater samples were analyzed for pH, EC, and water-soluble ions (cations: Na+, Mg2+, K+, Ca2+, NH4+, and anions: Cl-, NO3-, SO42-). The concentrations of particulate matter were continuously measured during precipitation events with a custom-built PM sensor node. For initial rainwater samples, the average pH and EC were approximately 4.3 and 81.9 μS/cm, and the major ionic components consisted of NO3- (5.4 mg/L), Ca2+ (4.2 mg/L), Cl- (4.1 mg/L). In all rainfall events, rainwater pH gradually increased with rainfall duration, whereas EC gradually decreased due to the washing effect. When the rainfall intensities were relatively weak (<5 mm/h), PM10 reduction efficiencies were less than 40%. When the rainfall intensities were enhanced to more than 7.5 mm/h, the reduction efficiencies reached more than 60%. For heavy rainfall events, the acidity and EC, as well as ions concentrations of initial rainwater samples, were higher than those in later samples. This appears to be related to the washing effect of precipitation on PM10 in the atmosphere.

• Korean Journal of Soil Science and Fertilizer
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• v.46 no.5
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• pp.386-390
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• 2013

Recently, special attention has been given to acid rain and its problem to environment such as acid precipitation and air pollution in East Asia. In the present study, rainwater samples were collected from Apr to Nov in 2012. The samples were chemically characterized for the assessment of emission sources. Suwon and Yeoju regions, typical agricultural areas in South Korea, were chosen for study sites. Ion composition and cation-affected neutralization were determined to evaluate the contribution of cations to the acidity of rainwater. Ion and electrical conductivity between the measured and the estimated showed high correlation. The cations observed in Suwon and Yeoju were $Na^+$ > $NH_4{^+}$ > $K^+$ > $Ca^{2+}$ > $Mg^{2+}$ > $H^+$ and $Na^+$ > $K^+$ > $NH_4{^+}$ > $Ca^{2+}$ > $Mg^{2+}=H^+$, respectively. The anions of all sites were $SO{_4}^{2-}$ > $NO_3{^-}$ > $Cl^-$. While the amounts of sulfate, one of the major dissolved components of rainwater, were 77.6 and 75.6 ueq $L^{-1}$ in Suwon and Yeoju, the ones of NSS-$SO{_4}^{2-}$ (Non-Sea Salt sulfate) were 83 and 82% in Suwon and Yeoju, respectively. The comparison of observed pH values ($pH_{obs}$) with the theoretical pH values ($pH_{the}$) showed that the neutralization of rain water considerably went along during the study periods. The highest amounts of rainfall throughout the year in Suwon and Yeoju were 572.3 and 484.6 mm in July, and its corresponding nitrogen loadings in Suwon and Yeoju were 5.28 and 3.50 kg $ha^{-1}$, respectively. The major ion contents for crop growth with $SO{_4}^{2-}$, $Ca^{2+}$, $K^+$ and $Mg^{2+}$ were 51.7, 5.2, 11.8 and 1.8 kg $ha^{-1}$ in Suwon and 34.2, 4.0, 4.2 and 1.1 kg $ha^{-1}$ in Yeoju.

• Applied Chemistry for Engineering
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• v.10 no.7
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• pp.963-968
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• 1999

The global environmental problems have been caused by the release of CFCs. Therefore, methods for safe destruction of recoverd CFCs will be eventually needed. The objective of this study was to develop and test a catalyst operating at a mild condition for the decomposition of CFC-113. In this work, catalytic oxidative decomposition of CFC-113 was carried out over aerosol $TiO_2/SiO_2(ATS)$ catalysts prepared by the sol-gel method. All ATS catalysts(Ti/Si mol ratio=1, 2, 2.33, 4) showed high initial activity. However, the deactivation of ATS catalysts was found that more remarkable due to an attack of fluorine and the destruction of ATS structure(Si-F reaction) from analyses of SEM-EDX, XRD than $TiO_2/SiO_2(ATS)$ catalyst prepared by the precipitation method. ATS catalysts prepared by more acidic prehydrolysis condition were found to have still more activity and longer life-time by increasing of acidity. The activity of ATS catalyst also depend on the content of $TiO_2$. There was reason that the acidity of the ATS catalyst was increased with the increased content of $TiO_2$ from 50 to 80 mol %. Solid superacid catalyst ($ATX/SO_4{^{2-}}$) modified with $H_2SO_4$ solution was prepared for high activity and lower deactivation. The reaction of $ATS/SO_4{^{2-}}$ catalyst also exhibited even higher activity and lower deactivation than the original ATS catalyst. It is suggested that the addition of the sulphate species clearly inhibit the deactivation.