• Title/Summary/Keyword: Precipitation Effect

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The Effect of Alloying Elements and Heat Treatment on the Intergranular Corrosion of 440A Martensitic Stainless Steel(II) (440A 강의 입계부식에 미치는 합금원소와 열처리의 영향(II))

  • Kim,, Y.C.;Jung, B.H.;Kang, C.Y.
    • Journal of Power System Engineering
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    • v.15 no.3
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    • pp.52-57
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    • 2011
  • 440A martensitic stainless steels which were modified with reduced carbon content(~0.5wt.%) and addition of small amount of vanadium, tungsten and molybdenum 0.4wt.%, 0.4wt.% and 0.68wt.% respectively were manufactured. Effects of alloying elements and tempering temperatures on the intergranular corrosion were investigated through the method of DL-EPR(Double-electrochemical potentiodynamic reactivation). It was thought that the highest DOS(Degree of sensitization) of specimens was obtained at the tempering temperature of $450^{\circ}C$ regardless of types of alloy because of the precipitation of Cr7C3. Addition of vanadium lowered DOS a little above the tempering temperature of $550^{\circ}C$. It was considered to be effected by precipitation of VC carbides. Intergranular corrosion was influenced more by tempering temperature than by alloying elements of V, W and Mo.

Hardness and Electrical Conductivity Changes according to Heat Treatment of Cu-1.6Co-0.38Si Alloy (Cu-1.6Co-0.38Si 합금의 열처리에 따른 경도 및 전기전도도의 변화)

  • Kwak, Wonshin;Lee, Sidam
    • Journal of the Korean Society for Heat Treatment
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    • v.33 no.5
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    • pp.226-231
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    • 2020
  • The Cu-Co-Si alloy shows high strength by forming precipitates by aging precipitation heat treatment of supersaturated solid solution treated with solution treatment such as Cu-Ni-Si alloy, and the Co2Si precipitated phase is dispersed in the copper matrix. The effect of aging treatment on the microstructure, mechanical and electrical properties of Cu-Co-Si alloys for electronic devices was investigated. As a results of SEM/EDS analysis, it was found that Co2Si precipitates of 30~300 nm size were distributed in grains. By performing the double aging treatment, it was possible to improve the strength and electrical conductivity by dispersing the fine precipitate evenly.

Correlation Analysis Using Precipitation Radar of TRMM Satellite and Ground Observed Value : YONG-DAM Watershed (TRMM/PR 관측치와 지상 관측치와의 상관분석 - 용담댐 유역을 대상으로 -)

  • Jang, Choul-Hee;Park, Guen-Ae;Kim, Seong-Joon
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2001.10a
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    • pp.335-339
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    • 2001
  • The Tropical Rainfall Measuring Mission(TRMM) Satellite was launched in November 1997, carrying into orbit the first space-borne Precipitation Radar(PR). The purpose of this study is to identify the relationship between TRMM/PR and AWS raingage data, and test the possibility to apply storm runoff prediction. Four TRMM/PR data in 1999 for Yongdam watershed was adopted and made a simple linear regression equation using AWS data. By using the equation, the storm runoff was estimated with the adjusted rainfall. TRMM/PR rainfall and runoff was overall underestimated by the carry-over effect of rainfall error and SCS-CN value selection.

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Molasses clarifying method used by lime-phosphate for yeast culture (효모배지용 당밀의 청징법에 관하여)

  • 임억규
    • Korean Journal of Microbiology
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    • v.19 no.3
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    • pp.121-127
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    • 1981
  • The constituents of molasses and effect of pH precipitate formation in molasses solution, vary according to its producing districts. The formation of precipitation is not so changeable in the range of buffering zone of molasses solution(pH4.3-6.3) in philippine molasses according to the change of pH value. On lower or higher than the range of buffering zone, the precipitation is increased from pH 4.3 to 2.8 and from 6.3 to 8.1, it is decreased when pH value is lower or higher than the pH value range. For molasses clarifying, it had better adjust the pH of molasses solution to neutral or weak alkali range out of the alkai side of the buffering zone, with lime solution. And then, add the calcium super phosphate solution to pH value of alkali side in buffering zone, as much as the pH of clarified molasses solution can reach to middle value in buffering zone. For the equilibrium of pH value on clarifying molasses, it takes plenty of time more than 6 hours.

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Morphology and Characteristic change of $LiMn_2O_4$ Powder Prepared by Precipitation-Evaporation Method (침전-증발법에 의해 제조된 $LiMn_2O_4$ 분말의 특성과 형태 변화)

  • Kim, Guk-Tae;Shim, Young-Jae
    • Korean Journal of Crystallography
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    • v.15 no.1
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    • pp.44-50
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    • 2004
  • Spinel structured lithium managanese oxide $(LiMn_2O_4)$ powder with well defined facetted morphology was prepared by precipitation-evaporation method. {111}, {110}, and {100} planes are mainly observed in the $LiMn_2O_4$ powder. And powder shape of tetradecahedron and octahedron was observed depending on the calcinations temperature. The observed powder morphology observed seemed to be related to the nonstoichiometry of the oxygen in the $LiMn_2O_4$ spinel structure. Oxygen nonstoichiometry might be responsible for the Jahn-teller effect and structure transition which in turn affects the surface energy of the {111}, {110}, and {100} planes. Powder shape transition from tetradecahedron to octahedron seemed to be related to the surface energy of the {111}, {110}, and {100} planes with oxygen nonstoichiometry.

Effect of Mo-doped LiFePO4 Positive Electrode Material for Lithium Batteries

  • Oh, Seung-Min;Sun, Yang-Kook
    • Journal of Electrochemical Science and Technology
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    • v.3 no.4
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    • pp.172-177
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    • 2012
  • Mo-doped $LiFePO_4$ was synthesized via co-precipitation method using sucrose as the carbon source. Structure, surface morphology, and the electrochemical properties of the synthesized olivine compounds were investigated using Rietveld refinement of X-ray diffraction data (XRD), scanning electron microscopy (SEM), and electrochemical charge-ischarge tests. Spherical morphology with the particle size of ${\sim}8{\mu}m$ authenticated the enhanced tap density and volumetric energy density of the synthesized materials. Charge-discharge behavior of $LiFePO_4$ and Mo-doped $LiFePO_4$ cells demonstrated a specific capacity of 130 and 145 mAh $g^{-1}$, respectively. Mo-doped $LiFePO_4$ cells exhibited an excellent discharge capacity at 96 mAh $g^{-1}$ at 7 C-rate.

Effect of Si Addition on the Microstructure of AI-Cu-Si Alloy for Thin Film Metallization (반도체 metallization용 Al-Cu 합금의 미세구조 천이에 미치는 Si 첨가영향)

  • Park, Min-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.237-241
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    • 2000
  • The effects of Si addition on the precipitation processes of in Al-Cu-Si alloy films were studied by the transmission electron microscopy. Deposition of an Al-1.5Cu-1.5Si (wt. %) film at $305^{\circ}C$ resulted in formation of fine, uniformly distributed spherical $\theta$-phase particles due to the precipitation of the $\theta$ and Si phase particles during deposition. For deposition at $435^{\circ}C$, fine $\theta$-phase particles precipitated during wafer cooldown, while coarse Si nodules formed at the sublayer interface during deposition. The film susceptibility to corrosion is discussed in relation to the film microstructure and deposition temperature.

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Effect of pH and Reaction Temperature on Mechanical Properties of Hydroxyapatite for Dental prosthesis (치관보철용 Hydroxyapatite의 기계적 물성에 미치는 pH 및 반응온도의 영향)

  • Chung, In-Sung;Her, Ho-Young
    • Journal of Technologic Dentistry
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    • v.26 no.1
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    • pp.89-96
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    • 2004
  • Hydroxyapatite powder were synthesized by precipitation method, varying pH, and reaction temperature. The powders were heated at 1,200$^{\circ}{\cdots}$ and 1,300$^{\circ}{\cdots}$ for fabrication of dental prosthesis. The results are as follows: Synthesized powder showed the smallest particle in size, under the conditions of pH 11 and reaction temperature 37$^{\circ}{\cdots}$. The hydroxyapatite was partially converted to $\alpha,\;\beta$-TCP at 1,200$^{\circ}{\cdots}$ and 1,300$^{\circ}{\cdots}$. Mechanical strength of sample was affected by such powder preparation conditions as pH and reaction temperature and sintering temperature. The mechanical strength of sample prepared under the same conditions was increased with increasing pH, reaction temperature and sintering temperature.

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GIS-based Meteorological Data Processing Technology for Forest Fire Danger Rating Forecast System of China

  • Zhao, Yinghui;Zhen, Zhen;Li, Fengri
    • Journal of Korean Society of Forest Science
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    • v.99 no.2
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    • pp.197-203
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    • 2010
  • The data of average temperature, average relative humidity, precipitation and average wind speed were collected from 674 meteorological stations in China. A specific procedure that processes original data into a new data format needed in forest fire danger rating forecast system of China was introduced systematically, and the feasibility of this method was validated in this paper. In addition, a set of meteorological data processing software was constructed by the secondary development of GIS in order to realize automation of processing data for the system. Results showed that the approach preformed well in handling temperature, average relative humidity and average wind speed, and the processing effect of precipitation was acceptable. Moreover, the automated procedure could be achieved by GIS and the working efficiency was about 3 times as much as that of manual handling. The informationization level of processing meteorological data was greatly enhanced.

Precipitation Behavior of α-Cr Particle in B2-type Intermetallic Compounds β-NiAl (B2형 금속간화합물 β-NiAl중에 α-Cr입자의 석출거동)

  • Han, Chang-Suck;Kim, Youn-Che
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.2
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    • pp.91-102
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    • 1996
  • Microstructural control to produce multiphase structure has received much attention to improve the high temperature strength as well as low temperature ductility of intermetallics. Transmission electron microscopic investigation has been carried out concerning the effect of Cr-precipitation on the mechanical properties of B2-ordered NiAl containing 4 to 8 mol% of Cr. By aging at temperatures around 973 K after solution annealing, fine spherical precipitates took place homogeneously in the NiAl matrix and the alloys hardened appreciably. Selected area electron diffraction (SAED) patterns have not revealed any additional extra-spots during aging, because the Cr-particles show cube-cube orientation relationship and keep a perfect coherency with the ordered matrix lattice. Dislocations were confirmed to bypass the particles during deformation. Although the dispersion of Cr-particles increased the yield strength of NiAl at intermediate temperature, the strength decreased appreciably at higher temperatures.

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