• 제목/요약/키워드: Pre-impregnation

검색결과 33건 처리시간 0.02초

Surface Impregnation of Glycine to Activated Carbon Adsorbents for Dry Capture of Carbon Dioxide

  • Lim, Yun Hui;Adelodun, Adedeji A.;Kim, Dong Woo;Jo, Young Min
    • Asian Journal of Atmospheric Environment
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    • 제10권2호
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    • pp.99-113
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    • 2016
  • In order to improve the portability of basic absorbents monoethanolamine (MEA) and glycine (Gly), both were supported on microporous activated carbon (AC). Chemical modification by alkali-metal ion exchange (of Li, Na, K) was carried out on Gly-based absorbents. All supported absorbents were subjected to $CO_2$ absorption capacity (pure $CO_2$) and selectivity (indoor level) tests. Textural and chemical characterizations were carried out on test sorbents. All impregnation brought about significant reduction of specific surface area and microporosity of the adsorbent Depreciation in the textural properties was found to result to reduction in pure $CO_2$ sorption. Contrarily, low-level $CO_2$ removal capacity was enhanced as the absorbent dosage increases, resulting in supported 5 molar MEA in methanol solution. Adsorption capacities were improved from 0.016 and 0.8 in raw ACs to 1.065 mmol/g for MEA's. Surface chemistry via X-ray photoelectron spectroscopy (XPS) of the supported sorbents showed the presence of amine, pyrrole and quaternary-N. In reducing sequence of potency, pyridine, amine and pyrrolic-N were noticed to contribute significantly to $CO_2$ selective adsorption. Furthermore, the adsorption isotherm study confirms the presence of various SNGs heterogeneously distributed on AC. The adsorption mechanism of the present AC adsorbents favored Freundlich and Langmuir isotherm at lower and higher $CO_2$ concentrations respectively.

창녕 비봉리 출토 신석기시대 나무배 편의 조습건조 (Humidity Controlled Drying for the Fragments of an Wooden Boat in the Neolithic Age, Excavated from Bibong-ri, Changnyeong, Korea)

  • 김수철;이광희
    • 박물관보존과학
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    • 제14권
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    • pp.7-12
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    • 2013
  • 창녕 비봉리에서 출토된 신석기 시대 나무배 편을 대상으로 PEG 함침처리 후 조습건조를 진행하였다. 칠기나 목기와 같은 소형 수침고목재 유물의 경우에는 진공동결건조법이 가장 많이 적용되고 있으나, 소형 유물에만 적용할 수 있다는 단점이 있다. 따라서 선박과 같은 대형유물의 경우에는 대부분 PEG 처리 후 자연건조를 하고 있으나 장시간의 약제함침이 요구되며, 건조결함이 발생할 위험이 있다. 따라서 본 처리에서는 비봉리 출토 나무배 편 4점을 대상으로 PEG 수용액으로 10%에서 80%까지 단계적으로 함침처리 후 조습건조법을 적용하였다. 또한 조습건조 후 배편의 습도조건별 중량변화를 측정하여 유물의 치수안정성을 확인하였다.

Low Temperature Catalytic Activity of Cobalt Oxide for the Emergency Escape Mask Cartridge

  • Park, Jae-Man;Kim, Deog-Ki;Shin, Chang-Sub
    • International Journal of Safety
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    • 제1권1호
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    • pp.58-61
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    • 2002
  • A preparation method of cobalt supported alumina catalyst for a emergency escape mask cartridge has been studied. Catalysts were prepared by incipient wetness impregnation method using pre-shaped $\gamma$=alumina powders of 70-100 mesh. The catalyst was tested in a continuous-flow reactor system and characterized by elemental analysis, BET and TGA-DTA techniques. Cobalt shows higher activity than platinum or nickel for carbon monoxide oxidation at room temperature. Optimum loading amount of cobalt was 10 wt.% for CO oxidation and the reaction activity increases gradually with the increase of calcination temperature up to $450^{\circ}C.

Fiber-Reinforcements of Composite Restorations

  • Cho, Kyung-Mo
    • 대한치과보존학회:학술대회논문집
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    • 대한치과보존학회 2001년도 춘계학술대회
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    • pp.258-258
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    • 2001
  • Fiber-reinforced materials have highly favorable mechanical properties. and their strength-to-weight ratios are superior to those of most alloys. When compared to metals they offer many other advantages as well. including non-corrosiveness. translucency. good bonding properties. and ease ofrepair. Fiber-reinforced materials can be categorized to pre-impregnated. impregnation required. dental laboratory products. chairside products and prefabricated posts. so it is not suprising that fiber-reinforced composites have potential for use in many applications in dentistry. Fiber-reinforced materials can be utilized in frameworks for crowns. anterior or posterior fixed prostheses. chairs ide tooth replacements. periodontal splints. customized posts. prefabricated posts. orthodontic retention. denture reinforcements and in implants dentistry. To realize the full potential of using fiber-reinforced composite restorations. it is essential that the clinician and laboratory technician understand concepts of tooth preparation and framework design. Also practitioner may appreciate the background information and other details about the materials themselves so that identify the rationale for their use in various clinical situations. select well-suited materials. and carry out related procedures. Understanding the material properties and take many attentions. fiber-reinforced materials will give more esthetic. more easy. more strong and more reliable restorations.ations.

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멜라민수지 함침지 적층에 의한 소나무재의 표면 강화 (Surface Hardening of Pine Wood by Laminating of Melamine Resin Sheet)

  • 한규성
    • 한국가구학회지
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    • 제17권1호
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    • pp.83-89
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    • 2006
  • Because the surface of pine wood is very soft, there have been many attempts, like as surface coating, resin impregnation, and densificationt, to harden the surface of wood for its interior use. This study was carried out for surface hardening of pine wood by laminating of melamine resin sheet. The effect of laminating method on the characteristics of melamine resin sheet-laminated wood(MLW) was investigated. Flat-sawn softwoods were suitable for MLW making. And the pre-drying of wood at $105^{\circ}C$ for 30min, before laminating, was effective for preparing of defect-free MLW. The abrasion resistance of pine wood was greatly improved by laminating of melamine resin sheet on its surface. Consequently, the laminating of melamine resin sheet was proved to be a favorable method for improvement of surface abrasiveness of pine wood.

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시흥군(始興郡) 서면일대(西面一帶)의 광화구제구조(鑛化規制構造)와 항공사진해석결과(航空寫眞解析結果)와의 비교연구(比較硏究) (The Study of Structural Control and Relative Photogeological Interpretation on Shiheung Mine Region)

  • 지정만;류병화
    • 자원환경지질
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    • 제3권4호
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    • pp.199-222
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    • 1970
  • One of the biggest sulfide metallic (Cu, Pb, Zn) ore deposits of South Korea is located in the area of Seo-myeon, Shiheung-gun, Gyeonggi-do. Geology of the region is mostly composed of metasediments of biotite schist, graphite schist, injection gneiss, sericite schist, limesilicate and quartzite from bottom, those are applicable to so-called Yeoncheon System of Pre-Cambrian, and granodiorite, quartz porphyry, basic dykes are outcroped in a small scope as intrusives. The origin of the ore deposit is pyrometasomatic contact deposits due to hydrothermal replacement and the ore bodies are imbedded in lower bed of limesilicate formation as impregnation and ore minerals are galena, sphalerite, marmatite, chalcopyrite, bornite, chalcocite, covellite, and the later two minerals are both hypogene and supergene. Gangue minerals are mostly skarn minerals those hornblende, diopside, epidote, hedenbergite, chlorite, garnet and quartz except primary calcite and quartz. Boundary plane (NS strike) between schists and limesilicate seemed to be primary opening of ore solution and fractures bearing $N50^{\circ}{\sim}80^{\circ}W$ are secondary structural control for localization of ore minerals and the third structural controls are both irregular gashes and schistosity in small scale. Photogeological study was carried with vertical aerial photo scaled 1: 38,000 and enlarged 1 : 10,000 under stereoscope. The study on the area convinced the fact that the geologic boundaries between rocks, limesilicates and quartzites, are traced easily by their typical topographic feature and drainage, and the main fracture patterns which derived from the result of fracture traces, that photogeologic lineament observed under stereoscope, are those bearing (1) $N20^{\circ}W$, (2) $N58^{\circ}W$, (3) $N76^{\circ}W$, (4) EW, (5) $N20^{\circ}W$, (6) $N62^{\circ}W$, (7) $N77^{\circ}W$. Among the written fractures, (5) (not schistosity, in case of fault) (6) (7) are post-mineral faults and others are pre-mineral faults and others are pre-mineral structures, and (2) (3) (6) (7) are coincided with statistical figure of 208 fractures surveyed in underground. By the result of the study, mineralized zone, are presumed to extend north and southward, total length about 4km.

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산처리 홍삼과 추출물의 특성 (Characteristics of Acid Pre-treated Red Ginseng and Its Decoction)

  • 김미현;이영철;최상윤;조장원;노정해
    • Journal of Ginseng Research
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    • 제33권4호
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    • pp.343-348
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    • 2009
  • 본 연구에서는 새로운 전처리를 통한 홍삼을 제조하여 홍삼의 향취미의 변화를 살펴보았으며 이로써 맛과 향이 개선 된 홍삼제품을 개발하고자 하였다. Acid(ascorbic acid, citric acid) 감압침투 방법으로 산처리 홍삼을 제조하였으며, 반 건조 산처리 홍삼과 반건조 홍삼의 색, 유리당, ginsenoside 함량, 관능검사를 실시하였다. 홍삼분말 색은 산을 처리하면 밝기 (L)와 황색도 (b)도는 감소하며, 적색도 (a)는 증가하는 것으로 나타났다. Fructose, glucose는 산을 처리하지 않은 홍삼이 가장 높았으나 sucrose, maltose는 citric acid 처리한 홍삼이 높게 나타나는 것을 알 수 있었다. Ginsenoside 함량은 산을 처리한 홍삼에서 $Rg_2+Rh_1$, $Rg_3$의 함량이 증가 되는 것을 알 수 있었다. 산을 처리한 반건조 홍삼과 일반 반건조 홍삼 관능검사에서는 색과 단맛에서만 유의적 차이가 나타났다. 그러나 건조 홍삼 추출물을 관능 검사한 결과 쓴맛과 떫은맛, 신맛, 향취, 색의 강도에서는 유의적 차이가 나타났다. 특히 산 처리한 홍삼 추출물은 쓴맛과 떫은맛이 감소되어 산으로 전 처리한 홍삼은 인삼에 대한 거부감을 줄일 수 있는 제품으로 사용 가능성을 보여 주었다.

수소 분리용 팔라듐계 분리막의 세라믹 코팅 영향 (Ceramic barrier coated Pd hydrogen membrane on a porous nickel support)

  • 이춘부;이성욱;박진우;김광호;황경란;박종수;김성현
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.114.1-114.1
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    • 2010
  • A highly performed Pd-based hydrogen membrane has prepared successfully on a modified porous nickel support. The porous nickel support modified by impregnation method of $Al(NO_3)_3{\cdot}9H_2O$ (Aldrich Co.) over the nickel powder showed a strong resistance to hydrogen embrittlement and thermal stability. Plasma surface modification treatment was introduced as a pre-treatment process instead of conventional HCl wet activation. Ceramic barrier was coated on the external surface of the prepared nickel supports to prevent intermetallic diffusion and to enhance the affinity between the support and membrane. Palladium and copper were deposited at thicknesses of $4\mu}m$ and $0.5{\mu}m$, respectively, on a barrier-coated support by DC sputtering process. The permeation measurement was performed in pure hydrogen at $400^{\circ}C$. The single gas permeation of our membrane was two times higher than that of the previous membrane which do not have ceramic barrier.

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콜타르 핏치를 이용하여 제조된 탄소/탄소 복합재의 관성제동 마찰특성 (The Inertia Friction properties of the Carbon/Carbon Composites Manufactured Using a Coal-tar Pitch)

  • 이진용;서동수;임연수;이승구;박종규
    • 한국세라믹학회지
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    • 제35권7호
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    • pp.740-748
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    • 1998
  • The inertia friction properties of C/C composites manufactured by the processes of pressure and at-mospheric carbonizaton with a commerciallized and two kinds of modified coal-tar pitch as a matrix pre-cursor were investigated. The modifications of a pitch such as the introduction of mesophase and the ad-dition of sulphur into a raw pitch were not effective for a impregnation efficiency conducted in a vacuum and at the same time in a pressure of 5kg/cm2 due to the increase of the pitch viscosity. There was not a difference in the densification increment between the pitch modifications however it was revealed that a pressure carbonization was more advantageous than an atmospheric in the densification and the formation of anisotropic carbon matrix. The friction and wear propertis of C/C having higher degree of matrix cry-stallization higher density and hardness of friction surface showed superiority. As the braking energy was increased the friction coefficients were decreased and reached almost same level at the high kinetic energy of 99.6kJ. The wear trends at 99.6kJ were different from the behaviors of friction ceofficient under the same energy in which an oxidation wear is being considered along with a mechnical wear although the wear rates were almost similar to the friction coefficient at the low energy.

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Preparation of Fe-ACF/TiO2 Composites and their Photocatalytic Degradation of Waste Water

  • Oh, Won-Chun;Bae, Jang-Soon
    • 한국세라믹학회지
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    • 제45권11호
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    • pp.667-674
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    • 2008
  • In this study, we prepared Fe-activated carbon fiber(ACF)/$TiO_2$ composites with titanium (VI) n-butoxide (TNB) as the titanium source for ACF pre-treated with iron compounds through the impregnation method. In terms of textural surface properties, the composites demonstrate a slight decrease in the BET surface area of the samples and an increase in the amount of iron compounds treated. The surface morphology of the Fe-ACF/$TiO_2$ composites was characterized by means of SEM. The composites have a porous texture with homogenous compositions of Fe and titanium dioxide distributed on the sample surfaces. The phase formation and structural transition of the iron compounds and titanium dioxide were observed in X-ray diffraction patterns of the Fe-ACF/$TiO_2$ composites. The chemical composition of the Fe-ACF/$TiO_2$ composites, which was investigated with EDX shows strong peaks for the C, O, Fe and Ti elements. The photo degradation results confirm that the Fe-ACF/$TiO_2$ composites show excellent removal activity for the COD in piggery waste due to photocatalysis of the supported $TiO_2$, radical reaction by Fe species, and the adsorptivity and absorptivity of ACF.