• 제목/요약/키워드: Practical synthesis

검색결과 284건 처리시간 0.019초

Toward Industrial Applications of Graphene Electrodes

  • 홍병희
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
    • /
    • pp.39-39
    • /
    • 2010
  • There have been many efforts to utilize the outstanding properties of graphene for macroscopic applications such as transparent conducting films useful for flexible/stretchable electronics. However, the lack of efficient synthesis, transfer, and doping methods limited the scale and the quality needed for the practical production of graphene films. In this presentation, we introduce ultra-large scale (~30 inch) synthesis and roll-to-roll transfer of graphene films showing excellent electrical and physical properties suitable for practical applications. Considering the outstanding scalability/processibility of roll-to-roll and CVD methods and the extraordinary flexibility/conductivity of graphene films, we expect the commercial production and application electrodes replacing the use of ITO can be realized in near future.

  • PDF

Practical Synthesis of 1,1-Difluoro- or 1-Fluoroalkenes from 2,2,2-Trifluoroacetophenone Derivatives

  • Kang, Min-Hyuk;Lee, Sun-Ah;Kang, Na-Na;Moon, Bong-Jin
    • Bulletin of the Korean Chemical Society
    • /
    • 제32권spc8호
    • /
    • pp.3022-3030
    • /
    • 2011
  • Since the discovery of the fact that compounds bearing a vinylic fluoride moiety often exhibit remarkable biological activities such as enzyme inhibitors, many synthetic methods for fluorine-substituted vinylic compounds have been developed. The synthesis of selectively fluorinated building blocks, such as arylsubstituted fluoro-alkenes, also has become an area of interest in recent years. Herein we describe a novel and practical method for the synthesis of 1,1-difluoro- and 1-fluoroalkenes starting from easily accessible trifluoroacetophenone derivatives. Various 1,1-difluoro- and 1-fluoroalkenes were prepared by the reaction of the corresponding tosyl hydrazones that were derived from trifluoroacetophenone derivatives by treating with alkyl or aryllithium reagents via addition-elimination and single electron transfer (SET) mechanism.

Protection Process of the tert-Butyl Group as a Non-Polar Moiety of D-Serine: Unexpected Rearrangement

  • Choi, Bo-Eun;Jeong, Jin-Hyun
    • Archives of Pharmacal Research
    • /
    • 제23권6호
    • /
    • pp.564-567
    • /
    • 2000
  • The use of amino acid derivatives as building blocks in peptide synthesis is increasingly being recognized as a potential route for the development of pharmaceutical agents. Side chain protection of polyfunctional amino acids such as Ser, Thr, Tyr is viewed as being particularly important. Although these derivatives are commercially listed, they are expensive and not widely available. We describe here a practical large-scale synthesis of t-butyl introduced D-serine, one of the building blocks of zoladex, a peptide drug.

  • PDF

Facile One-Pot Synthesis of 1,3,5-Trisubstituted Pyrazoles from α,β-Enones

  • Yu, Jin;Kim, Ko Hoon;Moon, Hye Ran;Kim, Jae Nyoung
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권6호
    • /
    • pp.1692-1696
    • /
    • 2014
  • A practical and efficient one-pot synthesis of 1,3,5-trisubstituted pyrazoles from ${\alpha},{\beta}$-enones and arylhydrazine hydrochlorides has been developed. The pyrazoles were formed via a tandem formation of the corresponding pyrazolines and an acid-catalyzed aerobic oxidation process.

Guidance Synthesis to Control Impact Angle and Time

  • Shin, Hyo-Sang;Lee, Jin-Ik;Tahk, Min-Jea
    • International Journal of Aeronautical and Space Sciences
    • /
    • 제7권1호
    • /
    • pp.129-136
    • /
    • 2006
  • A new guidance synthesis for anti-ship missiles to control impact angle and impact time is proposed in this paper. The flight vehicle is assumed as a 1st order lag system to consider more practical system. The proposed guidance synthesis enhances the survivability of anti-ship missiles because multiple anti-ship missiles with the proposed synthesis can hit the target simultaneously. The control input to satisfy constraints of zero miss distance and impact angle, and the feedforward bias control input to control impact time constitute the guidance law. The former is from trajectory shaping guidance, the latter is from neural network. And particle swarm optimization method is introduced to furnish reference input and output for learning in neural network. The performance of the proposed synthesis in the accuracy of impact time and angle is validated by numerical examples.

수용액에서 폴리에틸렌 글리콜 촉매에 의한 1, 8-Dioxo-octahydroxanthene 유도체의 다용도적이며 실용적인 합성 (A Versatile and Practical Synthesis of 1, 8-Dioxo-octahydroxanthene Derivatives Catalyzed by Polyethylene Glycol (PEG) in Water)

  • Chavan, Abhijit P.
    • 대한화학회지
    • /
    • 제53권4호
    • /
    • pp.415-421
    • /
    • 2009
  • 수용액에서 다양한 알데히드 5, 5-dimethyl-1, 3-cyclohexanedione을 이용한 1, 8-Dioxo-octahydroxanthene 유도체의 편리하고 실용적인 합성이 촉매인 폴리에틸렌 글리콜(PEG)하에서 성공적으로 수행되었다. 간단한 work-up, 깨끗한 생성물, 높은 수율, 친환경적인 용매인 물의 사용은 이 방법의 특색이다.

Toward Industrial Applications of Graphene Electrodes

  • 홍병희
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2010년도 춘계학술발표대회
    • /
    • pp.3.2-3.2
    • /
    • 2010
  • There have been many efforts to utilize the outstanding properties of graphene for macroscopic applications such as transparent conducting films useful for flexible/stretchable electronics. However, the lack of efficient synthesis, transfer, and doping methods limited the scale and the quality needed for the practical production of graphene films. In this presentation, we introduce ultra-large scale (~30 inch) synthesis, roll-to-roll transfer, and chemical doping of graphene films showing excellent electrical and physical properties suitable for practical applications. Considering the outstanding scalability/processibility of roll-to-roll and CVD methods and the extraordinary flexibility/conductivity of graphene films, we expect the commercial production and application electrodes replacing the use of ITO can be realized in near future.

  • PDF