• Title/Summary/Keyword: Pphotoisomerization

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A Large Trans/cis Conversion Ratio In Redox-Conjugated Single-Light Reversible Isomerization of a Cobalt Complex with meta-Bipyridylazobenzene Ligands

  • Kume, Shoko;Kurihara, Masato;Nishihara, Hiroshi
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.189-191
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    • 2002
  • Reversible trans-cis isomerization of meta-bipyridylazobenzene coordinated to cobalt was achieved by a combination of photoirradiation with a single UV light source and a Co(II)/Co(III) redox reaction. The trans/cis conversion performance was significantly improved in the meta-form compared with the meta-form ligated to cobalt.