• Title/Summary/Keyword: Pozzolanic Reaction

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A Study on the Watertightness Improvement of Cementitious Material for Durability Improvement of Concrete (콘크리트 내구성 향상을 위한 시멘트 재료의 수밀성 개선에 관한 연구)

  • Kang, Hyun-Ju;Song, Myong-Shin;Jeong, Eui-Dam
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.5
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    • pp.17-25
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    • 2010
  • We studied on the watertightness improvement of cementitious material for durability enhancement of concrete. For improvement of watertightness of OPC and OPC with fly ash, we used various materials with watertightness properties to OPC and OPC with fly ash. The performance of watertightness improvement of cementitious materials closely related to formation of CSH by pozzolanic reaction and to reducing of size of contact angle in cement pore by using organic fatty acid. And volume of CSH formation at early hydration have an influence of watertightness improvement and reduction of long-term water absorption rate. In using of fly ash, improvement of workability by using the spherical fly ash caused to densify on the structures of cement material and CSH formation by pozzolanic reaction and cement using fly ash also caused watertightness improvement of cementitious materials. For improvement of concrete durability by watertightness, cementitious materials need using watertightness materials and at using fly ash, also it have to the effect of improvement of watertightness of cementitious materials by pozzolanic reaction.

A Small Scale Test using the Coal Ash Placement Equipment (고유동성 채움재 타설장비를 이용한 모형시험)

  • Kim, Ju-Hyong;Cho, Sam-Deok;Ham, Tae-Gyu;Do, Jong-Nam;Chun, Byung-Sik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.1452-1457
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    • 2010
  • Recently, coal ash is used as resources to make controlled low-strength material (CLSM) which a self-compacted, cementitious material used primarily as a backfill in lieu of compacted fill. Pozzolanic reaction is strongly related with self-cementation of coal ashes. However, this reaction depends on pozzolanic content in fill materials and is disappeared in 2-3 days after placement of coal ash fill. Therefore, state of coal ash fill is commonly very loose and not appropriate for foundations of structures without special treatments. In this study, a coal ash placement device was developed to place coal ashes effectively to improve density of coal ash fills. The device consists of a ribbon type mixer to obtain homogeneous materials mixture and a piston type pump for density control of fill materials. Based on several laboratory test results, more stable coal ash fill state can be obtained with controlling placement pressure.

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Experimental Study on the Properties of Concrete by the Kinds of Admixture and the Replacement Ratios of Activated Hwangtoh (혼화재 종류 및 활성황토 대체율별 콘크리트의 공학적 특성에 관한 실험적 연구)

  • 최희용;김무한;김문한;황혜주;최성우
    • Journal of the Korea Concrete Institute
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    • v.13 no.2
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    • pp.123-129
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    • 2001
  • Pozzolan is to improve the strength and the durability of concrete as a result of the pozzolanic reaction, Broadly speaking, pozzolanic materials can be artificial materials, such as slica fume and fly ash, and natural material, such as rice husk ash, clay, volcanic ash, clayish pozzolan. Hwangtoh is a mineral which belongs to a group of matakaolin, especially halloysite, and the main elements is SiO$_2$, Al$_2$O$_3$, Fe$_2$O$_3$. The purpose of this study is to examine the application of Hwangtoh for the concrete admixtures, the composition of this study is shown as follows. Chapter I is analysis for properties of concrete as the kinds of admixture, and Chapter H is analysis for properties of concrete as the replacement ratio of activated Hwangtoh. As a result of this study, Hwangtoh is found to have high practical use as pozzolanic material, and the pertinent range of replacement ratios of Hwangtoh on cement are 10∼20 %.

The Research on Possibility as Mineral Admixture of Agriculture by-product (농업부산물의 혼화재료로써 사용가능성에 관한 연구)

  • Jeong, Euy-Chang
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.178-179
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    • 2019
  • The purpose of this study was to investigate the possibility as mineral admixture of agriculture by-product. XRD and XRF analysis were performed on rice straw ashes at various combustion temperatures to identify chemical compositions. Also to evaluate properties of pozzolanic reaction, pH change method was tested.

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Expansion Properties of Mortar Using Waste Glass and Industrial By-Products

  • Park, Seung-Bum;Lee, Bong-Chun
    • International Journal of Concrete Structures and Materials
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    • v.18 no.2E
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    • pp.125-132
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    • 2006
  • Waste glass has been increasingly used in industrial applications. One shortcoming in the utilization of waste glass for concrete production is that it can cause the concrete to be weakened and cracked due to its expansion by alkali-silica reaction(ASR). This study analyzed the ASR expansion and strength properties of concrete in terms of waste glass color(amber and emerald-green), and industrial by-products(ground granulated blast-furnace slag, fly ash). Specifically, the role of industrial by-products content in reducing the ASR expansion caused by waste glass was analyzed in detail. In addition, the feasibility of using ground glass for its pozzolanic property was also analyzed. The research result revealed that the pessimum size for waste glass was $2.5{\sim}1.2mm$ regardless of the color of waste glass. Moreover, it was found that the smaller the waste glass is than the size of $2.5{\sim}1.2mm$, the less expansion of ASR was. Additionally, the use of waste glass in combination with industrial by-products had an effect of reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass. Finally, ground glass less than 0.075 mm was deemed to be applicable as a pozzolanic material.

A potential review on the influence of nanomaterials on the mechanical properties of high strength concrete

  • P. Jagadesh;Karthik Prabhu ;Moutassim Charai;Ibrahim Y. Hakeem;Emrah Madenci;Yasin Onuralp Ozkilic
    • Steel and Composite Structures
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    • v.48 no.6
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    • pp.649-666
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    • 2023
  • In the current scenario, conventional concrete faces a substantial challenge in the modern era of the construction industry. Today's structures are massive, featuring innovative designs and strict time constraints. Conventional concrete does not provide the required compressive strength, tensile strength, flexural strength, toughness, and cracking resistance. As a result, most of engineers and professionals prefer to use ultra-high-performance concrete (UHPC), based on its wide advantages. Several advantages like mechanical and durability properties of UHPC provides dominant properties than the traditional concrete. Mix proportions of UHPC consists of higher powder content which provides maximum hydration and pozzolanic reaction, thereby contributing to the enhancement of the UHPC properties. Apart from that the nanomaterials provides the filler behavior, which will further improve the density. Enhanced density and mechanical properties lead to improved durability properties against water absorption and other typical chemicals. Nanomaterials are the most adopted materials for various applications, ranging in size from 0.1 nanometers to 100 nanometers. This article explores the effects of nanomaterial application in UHPC as a replacement for cementitious material or as an additive in the UHPC mix. The physical and durability properties modifications and improvements of UHPC, as well as negative effects, limitations, and shortcomings, are also analyzed.

Engineering properties of expansive clayey soil stabilized with lime and perlite

  • Calik, Umit;Sadoglu, Erol
    • Geomechanics and Engineering
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    • v.6 no.4
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    • pp.403-418
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    • 2014
  • There are around 6700 millions tons of perlite reserves in the world. Although perlite possesses pozzolanic properties, it has not been so far used in soil stabilization. In this study, stabilization with perlite and lime of an expansive clayey soil containing smectite group clay minerals such as montmorillonite and nontronite was investigated experimentally. For this purpose, test mixtures were prepared with 8% of lime (optimum lime ratio of the soil) and without lime by adding 0%, 10%, 20%, 30%, 40% and 50% of perlite. Geotechnical properties such as compaction, Atterberg limits, swelling, unconfined compressive strength of the mixtures and changes of these properties depending on perlite ratio and time were determined. The test results show that stabilization of the soil with combination of perlite and lime improves the geotechnical properties better than those of perlite or lime alone. This experimental study unveils that the mixture containing 30% perlite and 8% lime is the optimum solution in stabilization of the soil with respect to strength.

Improved Durability Performances in Cement Mortar with Rice Husk Ash

  • Saraswathy, Velu;Karthick, Subbiah;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.66-73
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    • 2014
  • Currently many researches have been performed for enhancing durability of concrete. Rice husk ash has several advantages like early strength of concrete and dense pore structure. A calcium silicate hydrate (CSH) gel around the cement particles due to pozzolanic reaction of rice husk can increase the strength of concrete against cracking. Very limitedly a systematic and detailed investigation on the corrosion performance of rice husk ash and silica fume blended concrete is performed. A realistic approach has been made through compressive strength, bond strength, and split tensile strength etc. Corrosion performance was also evaluated rapid chloride ion penetration test (RCPT) and impressed voltage test, and the results were discussed in the paper.

The Possibility of Alkali-Aggregate Reaction of High Strength Concrete by Concrete Bar Test (콘크리트 시험체 시험법을 통한 고강도 콘크리트의 알칼리골재 반응성)

  • 권영진;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.137-140
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    • 1996
  • The deterioration of concrete due to alkali-aggregate reaction is dependent on the total alkali content per unit volume of concrete. It was reported that the expansion of high alkali concrete with the reactive aggregate increased easily due to high alkali of concrete with the reactive aggregate increased easily. And it has been confirmed that the addition of pozzolanic material prevents the concrete with reactive aggregate from deterioration caused by alkali-aggregate reaction. It is the aim of this study to provide the fundamental data on the possibility of alkali-aggregate reaction of high strength concrete and its preventing and repair technic.

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The Effect of Seawater on Hydration of Clinker Minerals (I) Effects of SO42- and Cl- ions (시멘트 클린커 광물의 수화에 미치는 해수성분의 영향 (I)SO42- 및 Cl-이온에 의한 영향)

  • 신도철;송태웅;한기성;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.77-85
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    • 1987
  • Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

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