• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.06a
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• pp.1281-1284
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• 2005

In the micro electrochemical machining (ECM), unfavorable oxide/passive layer formation and overall corrosion of electrodes must be prevented. Generally, the stainless steel electrode corrodes, passivates or dissolves in the electrochemical cell according to the electrode potential. Therefore, the electrode must maintain stable potential. The stable electrode potentials of tool and workpiece were determined with the potentiodynamic polarization test and verified experimentally from the point of machining stability and machined surface quality.

• Korean Journal of Materials Research
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• v.27 no.11
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• pp.624-630
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• 2017

In this study, we investigated the overpotential of precipitation related to the catalytic activity of electrodes on the initial process of electrodeposition of Co and Co-Ni alloys on polycrystalline Cu substrates. In the case of Co electrodeposition, the surface morphology and the magnetic property change depending on the film thickness, and the relationship with the electrode potential fluctuation was shown. Initially, the deposition potential(-170 mV) of the Cu electrode as a substrate was shown, the electrode potential($E_{dep}$) at the $T_{on}$ of electrodeposition and the deposition potential(-600 mV) of the surface of the electrodeposited Co film after $T_{off}$ and when the pulse current was completed were shown. No significant change in the electrode potential value was observed when the pulse current was energized. However, in a range of number of pulses up to 5, there was a small fluctuation in the values of $E_{dep}$ and $E_{imm}$. In addition, in the Co-Ni alloy electrodeposition, the deposition potential(-280 mV) of the Cu electrode as the substrate exhibited the deposition potential(-615 mV) of the electrodeposited Co-Ni alloy after pulsed current application, the $E_{dep}$ of electrodeposition at the $T_{on}$ of each pulse and the $E_{imm}$ at the $T_{off}$ varied greatly each time the pulse current was applied. From 20 % to less than 90 % of the Co content of the thin film was continuously changed, and the value was constant at a pulse number of 100 or more. In any case, it was found that the shape of the substrate had a great influence.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.22 no.2
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• pp.57-62
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• 2008

This paper deals with a comparison of individual and connecting grounding electrode for potential rise. When a test current flowed through grounding electrode, potential rise was measured and analyzed for grounding method using a electrolytic tank in real time. In order to analyze the potential rise of grounding systems, a hemispherical water tank experimental apparatus was studied. Potential rise was measured and analyzed regarding the grounding method and distance by using this apparatus. The apparatus was composed of a hemispherical water tank, AC power supply, a movable potentiometer, and test grounding electrodes. The potential rise was measured by the horizontal moving probe of the potentiometer. The grounding electrodes were designed and fabricated with ground rods on a scale of one-eightieth. Potential rises of individual grounding electrode were higher than those of connecting grounding electrode. The distributions of surface potential are dependent on the distance from grounding electrode.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.54 no.8
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• pp.371-377
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• 2005

This paper Presents the Potential gradient characteristics of structure grounding electrode when a test current flows through grounding electrode. In order to analyze the potential gradient of ground surface on structure grounding electrode, the reduced scale model has been used. The potential gradient has been measured and analyzed for types of structure using the hemispherical grounding simulation system in real time. The structures were designed through reducing real buildings and fabricated with four types on a scale of one-one hundred sixty. The supporter was made to put up with weight of structure and could move into vertical, horizontal, rotary direction. When a test current flowed through structure grounding electrodes, ground potential rise was the lowest value at electric cage type(type B). According to resistivity and absorption percentage In concrete attached to structure, the potential distribution of ground surface appeared differently.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2004.11a
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• pp.111-114
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• 2004

There are many electricity, electronics, and communication equipment which need to Grounding in the building. When electric current flows into a certain Grounding system in the same building, the potential of other Grounding system rises. This potential interference repuire surface potential of electrods by electrode shape. In this paper basic formula is deduced on the basis of both electrodes surface potential of Grounding electrode as a source of the potential interference and Grounding electrode which receive the potential interference. The degree of potential interference as multiple Grounding electrode is verified the simulated results by means of the simple model in advance.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2005.05a
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• pp.349-354
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• 2005

Recently, there are many equipment of electricity, electronics, and communication which need to grounding in the building. When the electric current flows into a certain grounding system in the same building, the potential rise of other grounding system is possible to be affected by its potential rise. This potential interference was affected by the surface potential, it is deeply related whit the electrode shape. In this paper, basic formula is deduced on the basis of both electrodes surface potential of grounding electrode in a source of the potential interference and groundidng electrode which receive the potential interference. Therefore the degree of potential interference as multiple groundidng electrode can be verified the simulated results by means of the simple model in advance. This is for investigating the grounding resistance of grounding electrodes, the experiment was performed with model-scale of the grounding system and the scaled model grounding system was to this experiment using a water tank of a stainless steel-hemisphere shape. since mesh electrodes have been widely in the general building, we're tried to analyze that this water tank model and it's simulation as well.

• Korean Chemical Engineering Research
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• v.45 no.5
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• pp.433-441
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• 2007

This work investigated the stability of a Sn-modified Pt electrode, which was used for reduction of nitrate, fabricated by an adsorption or electro-deposition of Sn on Pt. In order to find the causes for instability of the electrode, the effects of the solutions in which the electrode was used and the potential applied to the electrode on the electrochemical and metallurgical behaviors of Sn on Pt were studied. The Sn of freshly- prepared modified-Sn Pt electrode existed as Sn hydroxide form, which brought about an easy loss of the electro-activity of the electrode even staying in water, especially in acid solution. When the Sn-modified Pt electrode was used for the reduction of nitrate, the electro-activity of the electrode was affected depending on the potential applied to the electrode. When a more negative potential than the redox equilibrium potential between $Sn(OH)_2$ and Sn was applied to the electrode, the Sn hydroxide was converted to Sn that could diffused into Pt, which leaded to the loss of electro-activity of the electrode as well. The solid diffusion of Sn increased linearly with the applied potential. The Sn-electrodeposited Pt electrode which had more Sn on the electrode was more favorable to maintaining the integrity of the electrode during the reduction of nitrate than the Sn-adsorbed Pt electrode prepared in the under-potential deposition way.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.27 no.2
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• pp.95-101
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• 2013

This paper presents the comparison of the earth resistivity obtained from the measurements made with the three-electrode and four-electrode fall-of-potential techniques. The ${\rho}-a$ curve obtained from Wenner four-electrode method in undisturbed earth is in good agreement with the ${\rho}-l$ curve obtained from the three-electrode method based on the fall-of- potential method. However, The ${\rho}-a$ curve in disturbed earth with moisture and freezing is significantly different with the ${\rho}-l$ curve. The ${\rho}-a$ curve is considerably sensitive to the freezing and the moisture present in the earth surface compared to the ${\rho}-l$ curve. Thus to determine the actual earth resistivity, it is necessary to take into account the earth surface conditions when measuring the earth resistivity.

• Bulletin of the Korean Chemical Society
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• v.11 no.6
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• pp.487-493
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• 1990

A complete potential profile of an electrical double layer is calculated from a distribution function of charged particles based upon a model where the effect of a charged electrode and the finite size of ion are explicitly included. Electrons which are distributed on the electrode surface are assumed not to penetrate the electrode/electrolyte boundary. Formation of the constant density regions and their effects on potential and the electrical double layer capacitances are studied in great detail. The distribution of surface electrons as well as the constant density regions are found to be essential in characterizing the electrical double layer. The introduction of the ion size into the prior electrical double layer model of an ideally polarizable electrode/point charged electrolyte system, shows a great improvement in its characteristics mostly at negative potential region.

• Bulletin of the Korean Chemical Society
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• v.10 no.6
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• pp.585-591
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• 1989

The effects of the charged metal on the overall electrostatic potential profiles and the capacitances of the electrical double layer are brought out. A model with a simplified jellium and a point-charged electrolyte is utilized in the present calculations. Electrons are assumed not to penetrate electrode surface due to a strong screening of electrolyte at the interface. Electron density functions and ion density functions are obtained, which are also based upon the Poisson equation and Boltzmann equation on either side of the interface. A complete potential profile starting from bulk electrode and ending at bulk electrolyte is obtained by connecting the two potential profiles (one inside the metal electrode, the other inside the electrolyte) with proper boundary conditions. In spite of the simplicity of the model, the present model reveals the importance of the effect of the charged metal on the electrostatic potential profile and the electrical double layer capacitances. The results are discussed and compared with the predictions by Gouy Chapman theory.