• 한국대기환경학회지
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• 제20권3호
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• pp.371-380
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• 2004

In the dust separation by using porous filter media, the structure of dust layer deposited on the filter surface of filter medium directly affects the effective filtration. The present study has investigated the specific resistance (K$_2$') of the dust layer and its porosity ($\varepsilon$$_{c}$) for three different filters; FA composite filter, metal fiber filter and stainless filter. The specific resistance (K$_2$') increased and at the same time the cake porosity ($\varepsilon$$_{c}$) decreased with the increase of filtration velocity, possibly due to the compressible effect of dust layer. However, under the low dust concentration, subsequent dust particles would block the open channels through the layer resulting in high specific resistance of the layer. The FA composite filter among three filters was shown to be the most effective filter for dust cake filtration at low filtration velocities less than 0.1 m/s for an approximate dust concentration of 5 g/㎥.

• 한국표면공학회지
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• 제43권5호
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• pp.248-254
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• 2010

Porous $Al_2O_3$ film can be utilized as template for fabrication of nano-structured materials. Porous anodic alumina layer as template was prepared by anodization of aluminum in oxalic acid, and the pore diameter and barrier-type alumina layer can be controlled for proper anodizing parameter by widening process in $H_3PO_4$ solution. The $SiO_2$ nanodot and Ni nanowire was fabricated using anodic alumina template and their characteristics were investigated using SEM and TEM with EDS. Especially the growth mechanism of $SiO_2$ nanodot in alumina membrane compared with thinning of the alumina barrier layer during anodization was also investigated.

• Bulletin of the Korean Chemical Society
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• 제26권7호
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• pp.1075-1078
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• 2005

Hydrogen adsorption on various porous materials have been studied with a volumetric method at low temperature in the pressure of 0-760 torr. Their hydrogen uptakes depend at least partly on microporosity rather than total porosity. However, it is also necessary to consider other parameters such as pore size and pore architecture to explain the adsorption capacity. The heat of adsorption and adsorption-desorption-readsorption experiments show that the hydrogen adsorption over the porous materials are composed of physisorption with negligible contribution of chemisorption. Among the porous materials studied in this work, SAPO-34 has the highest adsorption capacity of 160 mL/g at 77 K and 1 atm probably due to high micropore surface area, micropore volume and narrow pore diameter.

• 한국세라믹학회지
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• 제40권9호
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• pp.837-841
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• 2003

Duplex microstructure of zirconia and alumina has been achieved via an organic-inorganic solution technique. Zirconium 2,4-pentanedionate, aluminum nitrate and polyethylene glycol were dissolved in ethyl alcohol without any precipitation. The organicinorganic precursor gels were turned to porous powders having volume expansion through explosive, exothermic reaction during drying process. The volume expansion was caused by abrupt decomposition of the organic groups in the gels during the vigorous exothermic reaction. The volume expanded, porous powders were crystallized and densified at 1500$^{\circ}C$ for 1 h. At the optimum amount of the PEG polymer, the metal cations were well dispersed in the solution and a homogeneous polymeric network was formed. The polymer content also affected on the specific surface area of the synthesized powder and the grain size of the sintered composite.

• 한국정밀공학회지
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• 제16권11호
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• pp.62-67
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• 1999

The RP&M(Rapid Prototyping and Manufacturing) is the most appropriate technology for the small-lot production system, in which the production cycle is getting shorter owing to various needs from consumers. Recently RP products which are made of plastics, wax, and paper are used to verify the design of samples. But these products cannot be applied to the real mold because the strength enough to be a mold cannot be given by soft materials such as plastics. So RP products are copied to AFR(Al powder Filled Resin) molds or metal molds, which is called the RP&M. In this paper, RP&M is applied to a casting process. A porous casting mold, which is made from ceramic powder and binder, is used for rapid tooling of aluminum shoes molds.

• 분석과학
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• 제33권3호
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• pp.159-166
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• 2020

진공금속증착법(vacuum metal deposition, 이하 VMD)는 비다공성과 반다공성 표면의 잠재지문을 현출하는데 효과적이다. VMD는 일반적인 기법으로 현출할 수 없거나 어려운 표면에 유류된 지문을 현출하는 경우에서 활용할 수 있다. VMD 기법이 권장되는 표면은 비닐, 폴리머 지폐, 마그네틱 코팅 처리가 된 티켓 등이 있다. 본 연구에서는 택배 봉투로 주로 사용되는 분홍색 고밀도 폴리에틸렌 봉투(HDPE)와 저밀도 폴리에틸렌 봉투(LDPE)에 지문을 유류한 뒤 최소 12시간부터 최대 28일이 경과한 지문을 현출하기 위한 금의 최소 투입량을 탐색하였다. 그리고 그 결과를 흑색분말, 형광분말의 효과와 비교하였다. 또한, 실제로 배송에 사용된 택배 봉투를 수거한 다음 HDPE와 LDPE로 분류하고 pseudo-operation test를 시행하였다. 그 결과, VMD는 HDPE와 LDPE 표면에서 비교적 일관된 지문 현출 결과를 보여주었다.

• 한국수처리학회지
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• 제26권6호
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• pp.13-26
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• 2018

This research was conducted to elucidate the removal mechanism of heavy metals and sulfate ion from acid mine drainage(AMD) by porous zeolite-slag ceramics (ZS ceramics) packed in a column reactor system. The average removal efficiencies of heavy metals and sulfate ion from AMD by the 1:3(Z:S) porous ZS ceramics in the column reactor under the HRT condition of 24 hours were Al 97.5%, As 98.8%, Cd 86.1%, Cu 96.2%, Fe 99.7%, Mn 64.1%, Pb 97.2%, Zn 66.7%, and $SO_4{^{2-}}$ 76.0% during 121 days of operation time. The XRD analysis showed that the ferric iron from AMD could be removed by adsorption and/or ion-exchange on the porous ZS ceramics. In addition it was known that Al, As, Cu, Mn, and Zn could adsorb or coprecipitate on the surface of Fe precipitates such as schwertmannite, ferrihydrite, or goethite. The EDS analysis revealed that Al, Fe, and Mn, which were of relatively high concentration in the AMD, would be adsorbed and/or ion-exchanged on the porous ZS ceramics and also exhibited that Al, Cu, Fe, Mn, and Zn could be precipitated as the form of metal hydroxide or sulfate and adsorbed or coprecipitated on the surface of Fe precipitates. The microscopic results on the porous ZS ceramics and precipitated sludge in a column reactor system suggested that the heavy metals and sulfate ion from AMD would be eliminated by the multiple mechanisms of coprecipitation, adsorption, ion-exchange as well as precipitation.

• Carbon letters
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• 제4권2호
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• pp.86-92
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• 2003

A series of micro- and mesoporous activated carbons were prepared from two kinds of phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than 973 $m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides ($CuCl_2$). Pore evolvement depends on the amount of additional metal chloride and precursors used. From the SEM and EDX data, copper contents were shown to be most effected by the incremental addition of metal chloride.

• 한국대기환경학회지
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• 제20권3호
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• pp.361-369
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• 2004

A metal fiber bed has seldom been applied to the practical filtration process despite its excellent mechanical and chemical stability. The filter-bed used in this work was highly porous with open structure, of which apparent porosity was 80 ∼ 90%. Although pressure loss across the filter-bed was very low, separation efficiency was found to be quite high. This paper focuses on the basic filtration mechanisms of a metal filter-bed and a thin ceramic filter from fly ash for reference. The experimental parameters were face velocity, dust loading and porosity of filter-bed. Pressure drop increased with increasing face velocity and dust feeding load for both filters. It also showed that dust particles deposited in the deep flow path, finally resulting in clogging the pore channels. It thereby indicates that the dominating mechanism of the metal filter-bed would be depth filtration. Meanwhile, the thin fly ash composite filters trapped the aerated dust mainly on the surface of the filter medium, so that the instantaneously formed dust layer might cause a steep increase of pressure drop across the filtration system.

• 한국세라믹학회지
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• 제42권11호
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• pp.703-717
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• 2005

The infiltration of ceramics by liquid metals to fabricate ceramic-metal composites is discussed. In particular, the complexity of infiltrating ceramics by liquid metals at high temperatures due to interfacial reactions, metal oxidation, pore modulation and closure, and transient capillary forces has been highlighted. The role of these factors is discussed in the context of reactive infiltration with examples from ceramic/metal composites of practical interest. In addition to flow through porous ceramics, reactive penetration of dense ceramics via chemical dissolution and reaction is also discussed.