• Title/Summary/Keyword: Porous Solid

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Variation of Oxygen Nonstoichiometry of Porous $La_{0.6}Ca_{0.4}MnO_{3-{\delta}}$ SOFC-Cathode under Polarization

  • Mizusaki, Junichiro;Harita, Hideki;Mori, Naoya;Dokiya, Masayuki;Tagawa, Hiroaki
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.177-182
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    • 2000
  • At the porous $La_{0.6}Ca_{0.4}MnO_{3-{\delta}}$(LCM)/YSZ electrodes of solid oxide fuel cells (SOFC), the electrochemical redox reaction of oxygen proceeds via the triple boundary (TPB) of gas/LCM/YSZ. The surface diffusion of adsorbed oxygen on LCM has been proposed as the rate determining process, assuming the gradient of oxygen chemical potential from the outer surface of porous layer to TPB. Along with the formation of this gradient, oxygen nonstoichiometry in the bulk of LCM may varies. In this paper, an electrochemical technique was described precisely to determine the variation of oxygen content in LCM of porous LCM/YSZ under polarization. It was shown that the oxygen potential in LCM layer under large cathodic polarization is much lower than that in the gas phase, being determined from the electrode potential and Nernst equation.

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Vibration analysis of double-bonded micro sandwich cylindrical shells under multi-physical loadings

  • Yazdani, Raziye;Mohammadimehr, Mehdi;Zenkour, Ashraf M.
    • Steel and Composite Structures
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    • v.33 no.1
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    • pp.93-109
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    • 2019
  • In the present study, vibration analysis of double bonded micro sandwich cylindrical shells with saturated porous core and carbon/boron nitride nanotubes (CNT/BNNT) reinforced composite face sheets under multi-physical loadings based on Cooper-Naghdi theory is investigated. The material properties of the micro structure are assumed to be temperature dependent, and each of the micro-tubes is placed on the Pasternak elastic foundations, and mechanical, moisture, thermal, electrical, and magnetic forces are effective on the structural behavior. The distributions of porous materials in three distributions such as non-linear non-symmetric, nonlinear-symmetric, and uniform are considered. The relationship including electro-magneto-hydro-thermo-mechanical loadings based on modified couple stress theory is obtained and moreover the governing equations of motion using the energy method and the Hamilton's principle are derived. Also, Navier's type solution is also used to solve the governing equations of motion. The effects of various parameters such as material length scale parameter, temperature change, various distributions of nanotube, volume fraction of nanotubes, porosity and Skempton coefficients, and geometric parameters on the natural frequency of double bonded micro sandwich cylindrical shells are investigated. Increasing the porosity and the Skempton coefficients of the core in micro sandwich cylindrical shell lead to increase the natural frequency of the structure. Cylindrical shells and porous materials in the industry of filters and separators, heat exchangers and coolers are widely used and are generally accepted today.

The Simulation about the Air Flow and Pressure Drop inside the Metal Foam (발포 금속 내 공기 유동 및 압력강하에 관한 시뮬레이션)

  • Kim, Pil-Hwan;Jin, Mei-Hua;Jang, Seok-Jun;Chung, Han-Shik;Jeong, Hyo-Min
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1053-1058
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    • 2008
  • Porous medium was considered in the present study for the heat transfer enhancement. This was attributed to its high surface area to volume ratio as well as intensive flow mixing by tortuous flow passages. But when the air or water flow through in the porous medium, it is occurred the pressure drop between inlet and outlet. So in the present study investigated simulation result about the pressure drop in the porous medium before apply to heat exchanger. In this simulation, the thickness of the solid inside the porous medium region was varied 0.2 mm to 0.4 mm. And then the simulation result were compared the pressure drop in the same unit cell ($0.5\;mm{\times}0.5\;mm{\times}0.5\;mm$). To make the analysis model, it was assumed the 14-sided tetrakaidecahedron cell which has long been considered the optimal packing cell first proposed by the Lord Kelvin in 1887. And then the simulation is carried out using by STAR-CCM+ which is commercial software. The simulation result can be showed quantified pressure drop by solid effect in the porous medium.

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Forced vibration of a sandwich Timoshenko beam made of GPLRC and porous core

  • Mohammad Safari;Mehdi Mohammadimehr;Hossein Ashrafi
    • Structural Engineering and Mechanics
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    • v.88 no.1
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    • pp.1-12
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    • 2023
  • In this study, forced vibration behavior of a piezo magneto electric sandwich Timoshenko beam is investigated. It is assumed a sandwich beam with porous core and graphene platelet reinforced composite (GPLRC) in facesheets subjected to magneto-electro-elastic and temperature-dependent material properties. The magneto electro platelets are under linear function along with the thickness that includes a cosine function and magnetic and electric constant potentials. The governing equations of motion are derived using modified strain gradient theory for microstructures. The effects of material length scale parameters, temperature change, different distributions of porous, various patterns of graphene platelets, and the core to face sheets thickness ratio on the natural frequency and excited frequency of a sandwich Timoshenko beam are scrutinized. Various size-dependent methods effects such as MSGT, MCST, and CT on the natural frequency is considered. Moreover, the final results affirm that the increase in porosity coefficient and volume fractions lead to an increase in the amount of natural frequency; while vice versa for the increment in the aspect ratio. From forced vibration analysis, it is understood that by increasing the values of volume fraction and the length thickness of GPL, the maximum deflection of a sandwich beam decreases. Also, it is concluded that increasing the temperature, the thickness of GPL, and the initial force leads to a decrease in the maximum deflection of GPL. It is also shown that resonance phenomenon occurs when the natural and excitation frequencies become equal to each other. Outcomes also reveal that the third natural frequency owns the minimum value of both deflection and frequency ratio and the first natural frequency has the maximum.

Analysis of Heat Transfer Characteristics in the Thermally Developing Region of a Porous Channel by LTNE Model (LTNE 모델을 이용한 다공성 채널 입구영역에서의 열전달 특성 해석)

  • Lee, Sang-Tae;Lee, Kwan-Soo;Kim, Seo-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.7
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    • pp.983-990
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    • 2002
  • A numerical analysis has been carried out on forced convection heat transfer in the developing region of a porous channel. The channel is filled with an isotropic porous medium. At the channel walls, a uniform heat flux is given. Comprehensive numerical solutions are acquired to the Brinkman-Forchheimer extended Darcy equation and the LTNE model which does not employ the assumption of local thermal equilibrium between solid and fluid phases. Details of thermal fields in the developing region are examined over wide ranges of the thermal parameters. The numerical solutions at the fully developed region are compared with the previous analytical solutions. The correlation for predicting local Nusselt number in a porous channel is proposed.

Limit-current type zirconia oxygen sensor with porous diffusion layer (다공성 확산층을 이용한 한계전류형 지르코니아 산소센서)

  • Oh, Young-Jei;Lee, Chil-Hyoung
    • Journal of Sensor Science and Technology
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    • v.17 no.5
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    • pp.329-337
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    • 2008
  • Simple, small and portable oxygen sensors were fabricated by tape casting technique. Yttria stabilized zirconia containing cordierite ceramics (YSZC) were used as a porous diffused layer of oxygen in pumping cell. Yttria stabilized zirconia (YSZ) solid electrolyte, YSZC porous diffusion layer and heater-patterned ceramic sheets were prepared by co- firing method. Limit current characteristics and the linear relationship of current to oxygen concentration were observed. Viscosity variation of the slurries both YSZ and YSZC showed a similar behavior, but micro pores in the fired sheet were increased with increasing of the cordierite amount. Molecular diffusion was dominated due to the formation of large pores in porous diffusion layer. The plateau range of limit current in porous-type oxygen sensor was narrow than the one of aperture-type oxygen sensor. However limit current curve was appeared in porous-type oxygen sensor even at the lower applied voltage. The plateau range of limit-current was widen as increasing the thickness of porous diffusion layer of the YSZ containing cordierite. Measuring temperature of $600{\sim}650^{\circ}C$ was recommended for limit-current oxygen sensor. Porous diffusion layer-type oxygen sensor showed faster response than the aperture-type one and was stable up to 30 days running without any crack at interface between the layers.

Enhanced Production of Epothilone by Immobilized Sorangium cellulosum in Porous Ceramics

  • Gong, Guo-Li;Huang, Yu-Ying;Liu, Li-Li;Chen, Xue-Feng;Liu, Huan
    • Journal of Microbiology and Biotechnology
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    • v.25 no.10
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    • pp.1653-1659
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    • 2015
  • Epothilone, which is produced by the myxobacterium Sorangium cellulosum, contributes significant value in medicinal development. However, under submerged culture conditions, S. cellulosum will accumulate to form bacterial clumps, which hinder nutrient and metabolite transportation. Therefore, the production of epothilone by liquid fermentation is limited. In this study, diatomite-based porous ceramics were made from diatomite, paraffin, and poremaking agent (saw dust). Appropriate methods to modify the porous ceramics were also identified. After optimizing the preparation and modification conditions, we determined the optimal prescription to prepare high-performance porous ceramics. The structure of porous ceramics can provide a solid surface area where S. cellulosum can grow and metabolize to prevent the formation of bacterial clumps. S. cellulosum cells that do not form clumps will change their erratic metabolic behavior under submerged culture conditions. As a result, the unstable production of epothilone by this strain can be changed in the fermentation process, and the purpose of increasing epothilone production can be achieved. After 8 days of fermentation under optimized conditions, the epothilone yield reached 90.2 mg/l, which was increased four times compared with the fermentation without porous ceramics.

Application of sensitivity analyses in premixed combustion within a porous ceramic burner (다공 세라믹 연소기 속에서의 예혼합연소에 대한 민감도 해석의 적용)

  • Im, In-Gwon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.2
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    • pp.162-172
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    • 1998
  • A numerical study of premixed combustion within a porous ceramic burner (PCB) is performed to understand flame behavior with respect to various model parameters. Basic flame structure within the porous ceramic burner and species profiles such as NO and CO are examined. Sensitivity analysis of flame speed, gas and solid temperature, NO and CO emission from the burner with respect to reaction steps and various physical properties of the ceramic material is applied to find the most significant parameters in selection of porous materials for the porous ceramic burner. Effects of thermal conductivity, extinction coefficient and scattering albedo on the burner characteristics are studied through the sensitivity analysis. The results of sensitivity study reveal the order of importance in ceramic material properties to get suitable burner performance. Scattering albedo, which governs the ratio of absorbed energy by the ceramic material to total radiative energy transferred, is one of the most important parameters in the material properties since it affects the actual absorbed radiation rate and thus it largely affects the flame structure. Through the study, it is found that the sensitivity study can be used to estimate the flame behavior within the porous ceramic burner more effectively.

Wave Propagation Characteristics in Saturated Porous Media I. Theoretical Solution (포화된 다공성매체에서 파동의 전파특성 I. 이론해의 유도)

  • Kim, Sun-Hoon;Kim, Kwang-Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.20 no.2
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    • pp.95-103
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    • 2007
  • An analytical closed-form solution for wave propagation velocity and damping in saturated porous media is presented in this paper The fully coupled field model with compressible solid Brains and pore water were used to derive this solution. An engineering approach for the analysis of fully saturated porous media was adopted and closed-form solutions for one dimensional wave propagation in a homogeneous domain were derived. The solution is highly versatile in that it considers compression of the solid grains, compression of the pore water, deformation of the porous skeleton, and spatial damping and can be used to compute wavespeeds of first and second kind and damping coefficients in various geologic materials. This solution provides a means of analyzing the influence of material property variations on wavespeed and attenuation. In Part 2 of this work the theoretical solution is incorporated into the numerical code and the code is used in a parametric study on wave propagation velocity and damping.

Characterization of electrochemical behaviour for supercapacitor based on porous activated carbon composite with various contents of metal-organic framework(MOF) (금속유기골격체(Metal-organic Framework)의 함량에 따른 다공성 활성탄소 복합재료 기반 슈퍼커패시터의 전기화학적 거동 분석)

  • Jeong, Hyeon Taek;Kim, Yong Ryeol
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.5
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    • pp.1200-1207
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    • 2020
  • We have fabricated the supercapacitor composed of porous activated carbon, metal-organic framework (MOF) with polymer based solid state electrolyte as a "ion gel" and characterized its electrochemical behaviour as a function of the MOF contents. The electrochemical properties of the supercapacitor were analyzed via cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge test. As a results, the supercapacitor based on porous activated carbon/MOF composite showed the highest capacitance value at 0.5 wt% of MOF contents and decreased capacitance with increase MOF contents over the 0.5 wt%. Consequently, the porous activated carbon/MOF composite based supercapacitor is applicable to various aspect for energy storage device.