• 제목/요약/키워드: Porous Solid

검색결과 352건 처리시간 0.026초

Nanocomposite Ni-CGO Synthesized by the Citric Method as a Substrate for Thin-film IT-SOFC

  • Wang, Zhenwei;Liu, Yu;Hashimoto, Shin-ichi;Mori, Masashi
    • 한국세라믹학회지
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    • 제45권12호
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    • pp.782-787
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    • 2008
  • Ni-ceria cermets have been extensively investigated as candidates for the anode in intermediate-temperature solid oxide fuel cells. We have used the citric method to synthesize nanocomposite powders consisting of NiO (Ni metal content: $40{\sim}60%$ by volume) highly dispersed in $Ce_{0.9}Gd_{0.1}O_{1.95}$ (CGO). The microstructure characteristics and sintering behaviors of the nanocomposites were investigated. No impurity phases were observed and the shrinkage of these substrates matched well with that of a CGO electrolyte with a specific surface area of $11\;m^2/g$. Densification of the CGO electrolyte layer to $<5\;{\mu}m$ thickness was achieved by co-firing the laminated electrolyte with the porous NiO-CGO substrate at $1400^{\circ}C$ for 6 h.

LSGM 기반의 IT-SOFC를 위한 Infiltration 기법을 이용한 다공성의 LSGM 연료극 형성에 관한 연구 (Study on catalyst infiltration into the porous LSGM scaffold typed anode for LSGM electrolyte)

  • 윤병영;김정현;배중면
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.85.2-85.2
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    • 2011
  • 현재 중온의 고체산화물 연료전지를 위해 다양한 전해질에 대한 연구되었으며 1994년 Ishihara et al.에서 1074K의 온도에서 높은 이온전도도를 갖는 페록스카이 구조를 갖는 LSGM 물질을 발표하였다. Sr과 Mg을 도핑한 Lanthanum gallate는 이온전도도가 1073K에서 0.14S/cm로 YSZ의 5배로 높은 이온전도도를 갖고 있으며 산화환경에서부터 환원환경에서 화학적으로 안정한 특성을 갖고 있다. 또한 LSGM 전해질은 넓은 산소 농도범위에서 안정적인 특성을 갖는 장점을 갖고 있다. 그러나 LSGM은 가장 널리 사용되는 연료극의 Ni 촉매와 고온 소결시 상호확산현상에 의한 2차상을 생성시켜 성능 저감의 원인으로 그 해결방안이 요원한 실정이다. 이에 본 논문에서는 LSGM 전해질에 LSGM scaffold를 형성하고 형성된 scaffold에 연료극 촉매 solution을 infiltration 시켜 저온에서 anode를 형성하여 그 성능을 연구하였다.

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On the route towards Si-based full color LED microdisplays for NTE applications

  • Smirnov, A.;Labunov, V.;Lazarouk, S.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.727-731
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    • 2005
  • Design and manufacturing process of a full color LED microdislay fabricated by standard CMOS technology and containing an array of aluminum / nanostructured porous silicon reverse biased light emitting Schottky diodes will be discussed. Being of a solid state construction, this microdisplays are cost-effective, thin and light in weight due to very simple device architecture. Its benefits include also super high resolution, wide viewing angles, fast response time and wide operating temperature range. The advantages of full integration of an LED-array and driving circuitry onto a Si-chip will be also discussed.

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상압소결에 의하여 제조된 SiC-AlN 세라믹스의 상 및 미세구조 (Phase and Microstructure of SiC-AlN Ceramics Prepared by Pressureless Sintering)

  • 최웅;이종국;조덕호;김환
    • 한국세라믹학회지
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    • 제32권11호
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    • pp.1308-1314
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    • 1995
  • Changes in phase and microstructure were investigated in the SiC-AlN ceramics prepared by pressureless sintering using yttrium aluminum garnet (YAG) as a sintering aid at 200$0^{\circ}C$ and 210$0^{\circ}C$. The SiC/AlN ratio made a remarkable difference in densification, phase relations and the morphology of grains. In the AlN-rich composition, major phase was 2H and microstructure was composed of the densified equiaxed grains irrespective of the sintering temperatures. While those sintered at 200$0^{\circ}C$ were porous with major phase being 3C, the rod-like and the equiaxed grains were coexisted when sintered at 210$0^{\circ}C$ in the SiC-rich composition.

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전기화학증착법에 의한 $CeO_2$계 고체전해질 박막의 제조 (Preparation of $CeO_2$ Based Solid Electrolyte Thin Films by Electrochemical Vapor Deposition)

  • 박동원;김대룡
    • 한국세라믹학회지
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    • 제34권10호
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    • pp.1067-1073
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    • 1997
  • The yttria doped ceria (YDC) thin films were fabricated by electrochemical vapor deposition on the porous $\alpha$-Al2O3 substrate. The growth rates of the films obeyed a parabolic rate law, which constant was 259.0 $m^2$/hr at 120$0^{\circ}C$. As deposition temperature (above 110$0^{\circ}C$) increased, dense thin films were enhanced. Mole fraction of XYC13 had an effect upon surface morphologies. Electrical conductivity was increased with deposition temperature. The conductivity of YDC film prepared at XYC13=7.9$\times$10-2 was about 0.097 S/cm at 104$0^{\circ}C$ and the activation energy of conduction was calculated to be 26.6 kcal/mol.

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Modelling of the Electrochemical Performance of Functionally Graded Fuel Cell Electrodes by Discrete Simulations

  • Schneider, L.C.R.;Martin, C.L.;Bultel, Y.;Kapelski, G.;Bouvard, D.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.916-917
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    • 2006
  • Solid Oxide Fuel Cell technology uses powder processes to produce electrodes with residual porosity by partially sintering a mixture of electronically and ionically conducting particles. We model porous fuel cell electrodes with 3D packings of monosized spherical particles. These packings are created by numerical sintering. Each particle-particle contact is characteristic for an ionic, electronic or electrochemical resistance. The numerical packing is then discretized into a resistor network which is solved by using Kirchhoff's current law to evaluate the electrode's electrochemical performance. We investigate in particular percolation effects in functionally graded electrodes as compared to other types of electrodes.

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연속식 고정층 탑내에서의 휘발성 유기 화합물[VOCs]의 흡착 특성에 관한 연구

  • 최인호;최호석;이현재;구본탁;김인호
    • KSBB Journal
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    • 제15권6호
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    • pp.578-583
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    • 2000
  • Biofiltration has been identified as a promising method of odor, VOCs and air toxic removal from waste gas streams because of low capital and operating cost, low energy requirements and an absence of residual products requiring further treatment of disposal. Because biofiltration units are microbial systems in-corporationg microorganisms grown on a porous solid media like compost, peat, soil and mixtures of these materials, there is a need to study of the adsorptive behavior of these supports. The purpose of this study was to investigate the major parameters of adsorptive process. We adsorbed VOCs onto peats and bark, and examined the correlations between the interphase mass transfer coefficients and transfer units, at different stream flow rates, VOCs inlet concentrations and bed lengths.

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Simulation of brittle fracture of autoclaved aerated concrete

  • Kadashevich, I.;Stoyan, D.
    • Computers and Concrete
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    • 제7권1호
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    • pp.39-51
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    • 2010
  • The system of pores of autoclaved aerated concrete (AAC) is described by the so-called cherry-pit model, a random system of partially interpenetrating spheres. For the simulation of fracture processes, the solid phase is approximated by an irregular spatial network of beams obtained by means of the so-called radical tessellation with respect to the pore spheres. FE calculations using standard software (ANSYS) yield the strain energies of the beams. These energies are used as fracture criterion according to which highly loaded beams are considered as broken and are removed from the network. The paper investigates the relationship between mean fracture strength and microstructure for structures close to real AAC samples and virtual structures with particular geometrical properties.

다공성 물질이 충전된 정방형 밀폐용기 내에서 수용성 혼합용액의 동결거동에 관한 실험적 연구 (Experimental Study on the freezing of Aqueous Binary Solution Saturated Packed bed in a Square Cavity)

  • 최주열;김병철
    • 설비공학논문집
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    • 제4권3호
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    • pp.175-182
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    • 1992
  • Freezing of the binary solution ($H_2O-NaCl$) saturating a packed bed of spheres is investigated experimentally. The system is cooled through its top surface, and the bottom is maintained at a temperature above the liquidus. Experiments are performed on the hypolutectic side, and the cold wall temperature is lower than the eutectic point. The effects of initial mixture concentration, superheat and glass bead diameter on temperature and concentration distributions are investigated. Supercooling was observed only at early times of the freezing process for experiments with 5% initial salt concentration. Flow visualization experiments and mushy-liquid interface position observations revealed natural convection in the liquid region. Remelting phenomena was not observed at both the solid-mushy and mushy-liquid interfaces.

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반경방향 다중 채널 내 예혼합 화염의 안정화 특성과 맥동 불안정성에 관한 실험적 연구 (An Experimental Study on the Flame Localization Characteristics and Pulsating Instability in a Radial Multi-channel)

  • 이대근;고창복
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2013년도 제46회 KOSCO SYMPOSIUM 초록집
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    • pp.41-43
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    • 2013
  • In order to simulate and visually observe combustion phenomena in cylindrical radial-flow porous inert media, a radial multi-channel burner, made of transparent quartz plates, was fabricated. Flame stabilization characteristics and its pulsating instability in the burner were experimentally investigated with respect to various mixture flow rates and equivalence ratio. As a result, five different flame behaviors, such as stable flame, pulsating instability, sudden extinction, blowout and unstable extinction, were observed. Mean radial position of circularly arranged multi-flame and its averaged burning velocity were measured and then compared to the freely propagating flame. The multi-flame pulsation frequency is about several tens of Hz and it is supposed to be generated by the heat diffusion enhancement to cold pre-mixture by the intensive gas-solid interaction.

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