• Title/Summary/Keyword: Porous Glass

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The Characteristics of 〈112〉-preferred Orientation for Photocatalytic TiO2 Fabricated by CVD (CVD법에 의해 제작된 광촉매 TiO2 〈112〉 우선배향의 특성)

  • Kang, Kyoung-tae;Jhin, Jung-geun;Kang, Pil-kyu;Ro, Dae-ho;Byun, Dong-jin
    • Korean Journal of Materials Research
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    • v.13 no.7
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    • pp.436-441
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    • 2003
  • The characteristics of <112> orientation were studied for the $TiO_2$thin films, which were prepared on the glass by CVD (chemical vapor deposition) at various substrate temperatures. It was confirmed that $TiO_2$ films exhibited <112>-preferred orientation in a specific temperature range. Although $TiO_2$polycrystalline film grown deposited at relatively low temperature showed the growth of random directions, the <112>-preferred orientation was gradually developed with increasing deposition temperature. According to exhibit higher degree of <112>-preferred orientation, $TiO_2$thin film showed porous surface morphology, well-developed columnar structure, and deeper voids resulted from non-aggregation of columns were observed. In addition, transmittance was enhanced. Therefore, the growth of $TiO_2$with <112>-preferred orientation is suitable for glass coating because of predominance of photocatalytic efficiency and transmittance.

Ion Exchange Capacity and Phase Separation of Alkali Borosilicate Glass by Substituting $Al_2O_3$ (산화알루미늄의 치환에 따른 붕규산 유리의 분상 미 이온교환성에 관한 연구)

  • 김병호;유영문
    • Journal of the Korean Ceramic Society
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    • v.21 no.1
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    • pp.41-50
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    • 1984
  • The ion-exchange porous glasses were prepared by heat treating and subsequently acid treating the (95-y) $SiO_2$.$yB_2O_3$.$5Na_2O+xAl_2O_3$ glasses with y=55, 45, 35, 25. mole% and x=0, 2, 5, 9 mole% It was then investigated how the cation exchange capacity was affected by the phase separation in these glasses. For that matter such quantities as alkali extraction amount pore volume and specific surface area of the glasses were measured. The phase separation in these glasses was in general suppressed by the addition of $Al_2O_3$ maximally around the composition of 5 mole% $Al_2O_3$ This may be because the micro-phase separation prevailed in the glass of that composition over the macro-phase separation increasing thereby the specific surface area as well as the residual amount Al of after acid-treatment and accordingly the cation exchange capacity. The maximum values of the cation exchange capacity was observed to be about 150meq/100g for the glasses of (40-50) $SiO_2$ (55~45)$yB_2O_3$. $5Na_2O+5Al_2O_3$.

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A Study on Bloating of Porous Ceramic (다공성 세라믹의 발포에 관한 연구)

  • Kim, Gui-Shik;Kim, Hyeon-Gwan;Jeong, Ji-Hyun
    • Journal of Power System Engineering
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    • v.17 no.2
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    • pp.108-113
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    • 2013
  • In this study, lightweight aggregate was made from basalt stone powder sludge. Clay and glass powder were respectively added from 0 to 20 wt% and from 0 to 100 wt%. The glass powder helped to form glassy phase which trapped generating gas in the materials. $CaCO_3$ helping bloating process was added from 0 to 10 wt%. It was possible to produce lightweight aggregate at range from $1150^{\circ}C$ to $1200^{\circ}C$. The specimen was heated in furnace at 1100, 1150 and $1200^{\circ}C$ for 15 min, respectively, to sinter aggregates. Chemical composition of materials were determined, and characteristics were analyzed, including specific gravity, water absorption. Lightweight aggregate which was heated at $1200^{\circ}C$ had specific gravity of $0.53g/cm^3$, water absorption of 3.08%, and this value satisfied KS L 8551 standard.

Fabrication of Single Layer Anti-reflection Thin Film by Sol-gel Method (Sol-gel법에 의한 단층 반사 방지막 제조)

  • Park, Jong-Guk;Jeon, Dae-Woo;Lee, Mi-Jai;Lim, Tea-Young;Hwang, Jonghee;Bae, Dong-Sik;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.821-825
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    • 2015
  • Anti-reflective (AR) thin film was fabricated on a glass substrate by sol-gel method. The coating solution was synthesized with TEOS (tetraethlyorthosilicate) and poly ethylene glycol (PEG, 4.0 wt%). As the withdrawal speed of coating was changed from 0.1 mm/sec to 0.3 mm/sec, the thickness and refractive index of prepared thin films were changed. The reflectance and transmittance of coating glass fabricated by the withdrawal speed of 0.1 mm/sec were 0.62% and 95.0% in visible light range. The refractive index and thickness of single layer thin film were n= 1.29 and ca. 99.0 nm.

Teflon coating of fabric filters for enhancement of high temperature durability (섬유상 여과필터의 고온 내구성 향상을 위한 테프론 코팅 연구)

  • Kim, Eun-Joo;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.232-239
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    • 2011
  • Fabric fibrous filter has been used in various industrial applications owing to the low cost and wide generality. However, the basic properties of fabric materials often limit the practical utilization including hot gas cleaning. This study attempts to find new coatings of porous fibrous filter media in order to overcome its insufficient thermal resistance and durability. Teflon was one of the plausible chemicals to supplement the vulnerability against frequent external thermal impacts. A foaming agent composed of Teflon and some organic additives was tentatively coated on the glass fiber mat. The present test Teflon foam coated filter was fount to be useful for hot gas cleaning, up to $250^{\circ}C$-$300^{\circ}C$. Close examination using XPS(X-ray Photoelectron Spectroscopy) and Contact angle proved the binding interactions between carbon and fluorine, which implies coating stability. The PTFE/Glass foam coated filter consisted of more than 95% (C-F)n bond, and showed super-hydrophobic with good-oleophobic characteristics. The contact angle of liquid droplets on the filter surface enabled to find the filter wet-ability against liquid water or oil.

Fabrication of CIGS Thin Film Solar Cell by Non-Vacuum Nanoparticle Deposition Technique (비진공 나노입자 코팅법을 이용한 CIGS 박막 태양전지 제조)

  • Ahn, Se-Jin;Kim, Ki-Hyun;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.222-224
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    • 2006
  • A non-vacuum process for $Cu(In,Ga)Se_2$ (CIGS) thin film solar cells from nanoparticle precursors was described in this work CIGS nanoparticle precursors was prepared by a low temperature colloidal route by reacting the starting materials $(CuI,\;InI_3,\;GaI_3\;and\;Na_2Se)$ in organic solvents, by which fine CIGS nanoparticles of about 20nm in diameter were obtained. The nanoparticle precursors were mixed with organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of CIGS with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents ud to burn the organic binder material. Subsequently, the resultant (porous) CIGS/Mo/glass simple was selenized in a two-zone Rapid Thermal Process (RTP) furnace in order to get a solar ceil applicable dense CIGS absorber layer. Complete solar cell structure was obtained by depositing. The other layers including CdS buffer layer, ZnO window layer and Al electrodes by conventional methods. The resultant solar cell showed a conversion efficiency of 0.5%.

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Measurements of Transmittances and Calculations of Fundamental Radiative Properties (투과율의 측정 및 이를 이용한 복사물성치의 계산)

  • Hwang, Yong-Ha;Park, Seung-Ho;Lee, Young-Soo
    • Solar Energy
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    • v.14 no.2
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    • pp.29-37
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    • 1994
  • Radiative charaacteristics of glass windows and porous absorbing media which can be used for a solar air heater are determined through the measurements of spectral transmittances. Those in the visible range are measured by the UV-IR spectrometer. Refractive index of glass are obtained by the comparison of the measured transmittances and the correlations derived from the electromagnetic theory and are compared to the theoretical ones calculated from the classical dispersion theory. Absorption and back-scattering coefficients of 15-mesh stainless wire screens are calcuated by the comparison of the measured transmittances and the correlations derived from the two flux model.

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Comparison of Kramers-Krönig Relation and High-Frequency Acoustic Measurements in Water-Saturated Glass Beads (다공성 입자 매질에서 고주파 영역 음향 측정 자료와 Kramers-Krönig 관계식의 비교)

  • Yang, Hae-Sang;Lee, Keun-Hwa;Seong, Woo-Jae
    • The Journal of the Acoustical Society of Korea
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    • v.30 no.7
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    • pp.402-407
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    • 2011
  • The necessary and sufficient condition for causality of a physical system can be expressed as Kramers-Kr$\ddot{o}$nig (K-K) relation. K-K relation for acoustic wave is a Hilbert transforms pair between dispersion equations of phase speed and attenuation. In this study, we quantitatively compare the acoustic measurements in water-saturated glass beads for the frequency ranges from 400 kHz to 1.1 MHz with the predictions of differential form of K-K relation obtained by Waters et al. For media with attenuation obeying an arbitrary frequency power law, acoustic measurements show good agreements with the predictions of Kramers-Kr$\ddot{o}$nig relation.

Effect of Alumina on the Ion-Exchange Capacity of Porous Glasses (다공질유리의 이온교환성에 미치는 알루미나의 영향)

  • 김병호;이덕열;김성길
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.251-260
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    • 1988
  • Ion-exchange porous glasses were prepared by heat treatment and subsequently hydro thermalor acid leaching treatment $10Li_2O$.$(90-x)B_2O_3$.$xSiO_2$ base glasses containing various amount of $Al_2O_3$ or $MoO_3$. It was investigated how the phase separation and the cation exchange capacity(CEC) were affected by the addition of $Al_2O_3$ or $MoO_3$. The optimum condition of phase separation in these glasses was about 48$0^{\circ}C$ for 10 hrs. The degree of phase separation was rapidly suppressed by the addition of $Al_2O_3$ up to 10 mol% and thereafter suppression effect was decreased. The maximum value of CEC, about 252meq/100g, was observed with the $1OLi_2O$.$45B_2O_3$.$45SiO_2+7.5Al_2O_3$ porous glass prepared by hydrothermal treatment and its mean pore radius was about 16.3A. The addition of $MoO_3$ accelerated phase separation and leaching rate. Looking at the remakable increment of pore diameter and pore volume of these porous glasses by the addition of $MoO_3$, the effect of $MoO_3$ may be ascribed to the lowering of silica concentration in the borate phase and to the forming of water-soluble complex with silica during the leaching treatment.

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Fabrication and characterization of 3-D porous scaffold by polycaprolactone (폴리카프로락톤을 이용한 3차원 다공성 지지체 제조 및 특성 분석)

  • Kim, Jin-Tae;Bang, Jung Wan;Hyun, Chang-Yong;Choi, Hyo Jeong;Kim, Tae-Hyung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.2
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    • pp.58-65
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    • 2016
  • This study was a preparatory experiment aimed the development of membrane scaffolds for tissue engineering. A PCL composite solution contained sodium chloride(NaCl). PCL porous membrane scaffolds were formed on a glass casting plate using a film applicator and immersed in distilled water to remove the NaCl reaching after drying. NaCl was used as a pore former for a 3 dimensional pore net-work. The dry condition parameters were $4^{\circ}C$, room temperature (RT) and $40^{\circ}C$ for each different temperatures in the drying experiment. SEM revealed the morphology of the pores in the membrane after drying and evaluated the in vitro cytotoxicity for basic bio-compatibility. The macro and micro pores existed together in the scaffold and showed a 3-dimensional pore net-working morphology at RT. The in vitro cytotoxicity test result was "grade 2" in accordance with the criterion for cytotoxicity by ISO 10993-5. The dry condition affected the formation of a 3 dimensional pore network and micro and macro pores. Therefore, these results are expected provide the basic process for the development of porous membrane scaffolds to control degradation and allow drug delivery.