• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.817-820
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• 2006

This study investigated on the differentiation of microstructure of blast furnace slag concrete(BBSC) using Mercury Intrusion Porosimetry(MIP). From the test result, it was found that the BBSC did not show shortcomings of high temperature curing. The BBSC gives more fineness microstructure than that of plain concrete when it is cured same curing condition. The curing age making stable structure to poor surroundings was 28, 14, 7 days for blast furnace concrete cured at 5, 20, $30^{\circ}C$, respectively.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.20-21
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• 2017

In this study, fundamental properties by pore structure and heat of microhydration test were determined. As a result of pore structure analysis, BS(AA) specimen showed showed the maximum peak value of significantly lower incremental intrusion than the maximum peak value of incremental intrusion at smaller pore size than that of BS. As a result of heat of microhydration test, the maximum heating value was in the order of OPC > BS > BS(AA), and initial drying shrinkage and compressive strength of BS(AA) were expected to be improved.

• Computers and Concrete
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• v.11 no.4
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• pp.317-336
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• 2013

In this study, the pore structure of Portland cement paste is experimentally characterized by MIP (mercury intrusion porosimetry) and nitrogen adsorption, and simulated by a newly developed status-oriented computer model. Cement pastes with w/c=0.3, 0.4 and 0.5 at ages from 1 day to 120 days are comprehensively investigated. It is found that MIP cannot generate valid pore size distribution curves for cement paste. Nevertheless, nitrogen adsorption can give much more realistic pore size distribution curves of small capillary pores, and these curves follow the same distribution mode. While, large capillary pores can be effectively characterized by the newly developed computer model, and the validity of this model has been proved by BSE imaging plus image analysis. Based on the experimental findings and numerical simulation, a hypothesis is proposed to explain the formation mechanism of the capillary pore system, and the realistic representation of the pore structure of hydrated cement paste is established.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.34 no.5
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• pp.86-92
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• 2002

The benefits of high performance retention systems have been long recognized by the paper maker. The inter-relation between chemical retention and drainage and their effect on paper production efficiency and paper quality is significant. The subject of this paper is a summary of recent studies comparing three microparticle programs made under highly controlled pilot and commercial paper machine conditions. The results presented in this paper suggest that, in addition to improvements in machine operation, the retention, drainage and formation program can have a marked influence on the paper quality. Improvement of the topographical characteristics of the base paper was observed when the microparticle was a colloidal borosilicate inorganic oxide.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.42 no.1
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• pp.1-7
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• 2016

Highly porous polymethyl methacrylate (PMMA) microspheres impregnated by $TiO_2$ powder were prepared by spray drying method. The particle size and the porosity were controlled by optimizing the co-solvent ratio and the polymer concentration. $TiO_2$ powder was impregnated into the microspheres upto 74.6 wt% content based on the weight of the resultant $PMMA/TiO_2$ microspheres. SEM images showed that $TiO_2$ powder was well distributed throughout the inside of the microsphere. EDX mapping showed that the Ti signal was well detected from every part of the microspheres, which was the evidence of the formation of the $PMMA/TiO_2$ composite. Hg porosimetry result showed that the porosity was found to be over 50% regardless of the $TiO_2$ contents. The final product was found to have high oil-absorbing capacity and great hiding power, both of which are key properties in designing the microsphere materials for make-up cosmetics application.

• Journal of the Korea Concrete Institute
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• v.29 no.3
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• pp.275-281
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• 2017

This study examined the effect of water-to-binder ratio (W/B) and phosphate-to-binder ratio (P/B) on the flow, setting time, compressive strength development, and pH variation of magnesium-potassium phosphate composites, MKPC mortars. Ten mortars mixtures were prepared with the W/B varying from 20% to 40% at each P/B of 0.3 or 0.5. The hydration products and microstructural pore distribution of the MKPC pastes were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). The initial flow and setting time of MKPC mortars tended to decrease with an increase of P/B, indicating that the final setting time was shortened by approximately 24% when P/B increased from 0.3 to 0.5. The slope of the early-strength development measured in the MKPC mortars was considerably higher than that of cement concrete specified in code provisions. For obtaining a relatively good 28-day strength (above 30 MPa) and a near neutral pH (below 9.0) in MKPC mortars, the P/B and W/B need to be selected as 0.5 and 30%, respectively. The strubite-K crystal increased with the increases of P/B and W/B, which leads to the decrease of the macro-capillary pores.

• Journal of the Korea Concrete Institute
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• v.19 no.4
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• pp.499-506
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• 2007

According to the high demand of concrete structures with high performance, various studies have examined on the high performance concrete, especially high strength concrete. Various admixtures are required to produce high strength concrete and silica fume has been the most popular admixture. Recently, however, metakaolin, which is similar to silica fume in properties but cheaper, has been introduced to high strength concrete. In this study, high-strength concrete using metakaolin were studied of capillary pore structure by mercury intrusion porosimetry technique and the accelerated chloride diffusivity by electrical difference. In result, it was found that the pore structure improved and compressive strength increased and chloride diffusivity reduced as more metakaolin content was added. In addition, a regression analysis of $5{\sim}2,000nm$ pore volume and both compression strength and chloride diffusivity revealed that each these had a high correlation of about 0.76 and 0.68.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.185-190
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• 2008

In order to increase the surface area of electrodes for electrosorption, porous carbon electrodes were fabricated by a wet phase inversion method. A carbon slurry consisting of a mixture of activated carbon powder (ACP), polyvinylidene fluoride (PVdF), and N-methyl-2-pyrrolidone (NMP) as a solvent was cast directly on a graphite sheet. The cast film was then immersed in pure water for phase inversion. The physical and electrochemical properties of the electrodes were investigated using scanning electron microscopy (SEM), porosimetry, and cyclic voltammetry. The SEM images verified that the pores of various sizes were formed uniformly on the electrode surface. The average pore sizes determined for the electrodes fabricated with various NMP contents ranged from 64.2 to 82.4 nm and the size increased as the NMP content increased. All of the voltammograms showed a typical behavior of charging and discharging characteristic at the electric double layer. The electrical capacitance ranged from 3.88 to $5.87F/cm^2$ depending on the NMP contents, and the electrical capacitance increased as the solvent content decreased. The experimental results showed that the solvent content is an important variable controlling pore size and ultimately the capacitance of the electrode.

• Clean Technology
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• v.24 no.3
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• pp.239-248
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• 2018

In this study, pervaporation experiments of water, ethanol and IPA (Isopropyl alcohol) single components and water/ethanol, water/IPA mixtures were carried out using zeolite 4A membranes developed by Fine Tech Co. Ltd. Those membranes were fabricated by hydrothermal synthesis (growth in hydrothermal condition) after uniformly dispersing the zeolite seeds on the tubular alumina supports. They have a pore size of about $4{\AA}$ by ion exchange of $Na^+$ to the LTA structure with Si/Al ratio of 1.0, and shows strong hydrophilic property. Physical characteristics of prepared membranes were evaluated by using SEM (surface morphology), porosimetry (macro- or meso- pore analysis), BET (micropore analysis), and load tester (compressive strength). Pervaporation experiments with various temperature and concentration conditions confirmed that the zeolite 4A membrane can selectively separate water from ethanol and IPA. Water/ethanol separation factor was over 3,000 and water/IPA separation factor was over 1,500 (50 : 50 wt%, initial feed concentration). Pervaporation behaviors of single components and binary mixtures were predicted using ACM (activity coefficient model), GMS (generalized Maxwell Stefan) model and DGM (Dusty Gas Model). The adsorption and diffusion coefficients of the zeolite top layer were obtained by parameter estimation using GA (Genetic Algorithm, stochastic optimization method). All the calculations were carried out using MATLAB 2018a version.

• Journal of the Korea Concrete Institute
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• v.29 no.1
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• pp.101-107
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• 2017

This study aimed to conduct the basic analysis on the fractal characteristics of cementitious materials. The pore structure of cement paste incorporating ground granulated blast furnace slag (GGBFS) was measured using mercury intrusion porosimetry (MIP) and the fractal characteristics were investigated using different models. Because the pore structure of GGBFS-blended cement paste is an irregular system in the various range from nanometer to millimeter, the characteristics of pore region in the different scale may not be adequately described when the fractal dimension was calculated over the whole scale range. While Zhang and Li model enabled analyzing the fraction dimension of pore structure over the three divided scale ranges of micro, small capillary and macro regions, Ji el al. model refined analysis on the fractal characteristics of micro pore region consisting of micro I region corresponding to gel pores and micro II region corresponding to small capillary pores. As the pore size decreased, both models suggested that the pore surface of micro region became more irregular than macro region and the complexity of pores increased.