• Title/Summary/Keyword: Pore-filled

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Fabrication and Mechanical Properties of the Hybrid Composites Filled with Waste Stone and Tire Powders (폐석분-폐타이어 분말 충전 혼성복합재료의 제조 및 기계적 특성)

  • 황택성;이승구;차기식
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.774-781
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    • 2001
  • In order to reuse the waste matters, the polyester hybrid composites were fabricated with the waste stone (WSP) and waste tire (WTC). Before mixing, the waste fillers were treated with the silane coupling agent [${\gamma}$-methacryloxy propyl trimethoxy silane(${\gamma}$-MPS)] for enhancing the dispersion of the fillers and interfacial bonding with polymer matrix. Mechanical properties and morphologies of the resulted hybrid composites were investigated with the filler content. The hybrid composites containing surface treated fillers have high initial thermal decomposition temperature and low weight loss compared to the untreated one. The highest mechanical properties of composites were obtained with the ${\gamma}$-MPS (2 wt%) treated fillers. The porosity of composite increased with the content of organic filler which can be reduced by the silane surface treatment of fillers. The pore size distribution of the composites varied with the waste filler content.

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Effect of pH in Hybrid Water Treatment Process of PVdF Nanofibers Spiral Wound Microfiltration and Granular Activated Carbon (PVdF 나노섬유 나권형 정밀여과와 입상 활성탄의 혼성 수처리 공정에서 pH의 영향)

  • Kyung, Kyu Myung;Park, Jin Yong
    • Membrane Journal
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    • v.25 no.4
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    • pp.358-366
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    • 2015
  • Flat membrane with $0.4{\mu}m$ pore size was prepared with PVdF (polyvinylidene fluoride) nanofiber, which has the advantages such as excellent strength, chemical resistance, nontoxic, non-combustibility. After that, spiral wound module was manufactured with it including a woven paper. Effect of pH was studied by comparing permeate fluxes and rejection rates of the spiral wound module using simulation solution including kaolin and humic acid. The recovery rate and filtration resistance were calculated after water back-washing at the end of filtration experiment. In addition, after the water filtrated by the spiral wound module was passed through a column filled with GAC (granular activated carbon), adsorption effect of GAC was investigated by measuring the turbidity and $UV_{254}$ absorbance.

Breakthrough behaviour of NBC canister against carbon tetrachloride: a simulant for chemical warfare agents

  • Srivastava, Avanish Kumar;Shah, D.;Mahato, T.H.;Singh, Beer;Saxena, A.;Verma, A.K.;Shrivastava, S.;Roy, A.;Yadav, S.S.;Shrivastava, A.R.
    • Carbon letters
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    • v.13 no.2
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    • pp.109-114
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    • 2012
  • A nuclear, biological, chemical (NBC) canister was indigenously developed using active carbon impregnated with ammoniacal salts of copper (II), chromium (VI) and silver (I), and high efficiency particulate aerosol filter media. The NBC canister was evaluated against carbon tetra chloride ($CCl_4$) vapours, which were used as a simulant for persistent chemical warfare agents under dynamic conditions for testing breakthrough times of canisters of gas masks in the National Approval Test of Respirators. The effects of $CCl_4$ concentration, test flow rate, temperature, and relative humidity (RH) on the breakthrough time of the NBC canister against $CCl_4$ vapour were also studied. The impregnated carbon that filled the NBC canister was characterized for surface area and pore volume by $N_2$ adsorption-desorption isotherm at liquid nitrogen temperature. The study clearly indicated that the NBC canister provides adequate protection against $CCl_4$ vapours. The breakthrough time decreased with the increase of the $CCl_4$ concentration and flow rate. The variation in temperature and RH did not significantly affect the breakthrough behaviour of the NBC canister at high vapour concentration of $CCl_4$, whereas the breakthrough time of the NBC canister was reduced by an increase of RH at low $CCl_4$ vapour concentration.

Development of Ceramic Body using Waste Celadon (청자 파도자기를 활용한 도자기 소지 개발)

  • Lee, Jea-Il;Park, Joo-Seok;Lee, Yong-Seok;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.602-608
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    • 2009
  • The yield is increasing as the manufacturing technology of ceramics progresses, however, there are many ceramics of poor quality due to variables upon producing ceramics. Some of those waste ceramics are recycled by sanitary ware or tile manufacturers, but most of them are filled in making environmental problem. Therefore, a research begins to recycle waste ceramic ware as alternative to some imported ceramic ware materials and to reduce environmental pollution. This study, succeeding last study which applied waste white ware as ceramic body material, aimed to solve problems of environment and materials by recycling waste ceradon generated in specially formed areas for ceramic in Gyeonggi-do such as Icheon, Yeoju and Gwangju as the ceramic body material. Consequently, the addition of waste ceramic ware into the ceramic body was judged to have limit up to 30% according to plasticity measurement. As we added shredded waste ceramic ware as much as 30% into basic ceramic body and checked its features, the pore rate and absorption rate were good to be average 4% and 3% respectively. In addition, it showed strength more than 720 kgf/$cm^2$ which is higher than existing ceradon body on the market with good sinter state; so it is judged to be available or developed as new ceramic body.

The Relevance of Soil N2O Emissions Measured by a Closed Chamber Technique on the Physico-chemical Soil Parameters (Closed chamber를 이용한 토양 N2O 배출량과 주요 토양 인자들과의 상관성)

  • Kim Deug-Soo;Oh Jin Man
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.749-758
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    • 2004
  • Nitrous oxide ($N_2$O) has been known as an important trace gas due to the greenhouse gas and the major source of stratospheric oxide of nitrogen (NO). Soil is the major source of $N_2$O in nature. The physicochemical characteristics of soils affect the emission of $N_2$O from soil. These physicochemical parameters are soil moisture, soil temperature, and soil N content. Since these parameters are correlated to the flux of $N_2$O from soil individually and compositely, there still remain many unknowns in the mechanism to produce $N_2$O in soil and the roles of such physicochemical parameters which affect the soil $N_2$O emission. Soil $N_2$O fluxes were measured at different levels in water filled pore space (WFPS), soil temperature and soil N contents from the same amounts of soils which were sampled from agriculturally managed upland field in a depth of ~30 cm at Kunsan. The soil $N_2$O flux measurements were conducted in a laboratory with a closed flux chamber system. The optimum soil moisture and soil temperature were observed at 60% of WFPS and ~13$^{\circ}C$. The soil $N_2$O flux increased as soil N contents increases during the whole experimental hours (up to 48 hours). However, average $N_2$O flux decreased after ~30 hours when organic carbon was mixed with nitrogen in the sample soils. It is suggested that organic carbon could be important for the emission of $N_2$O, and that the ratio of N to C needs to be identified in the process of $N_2$O soil emission.

A Study on the Surface Pre-treatment of Palladium Alloy Hydrogen Membrane (팔라듐 합금 수소 분리막의 전처리에 관한 연구)

  • Park, Dong-Gun;Kim, Hyung-Ju;Kim, Hyo Jin;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.45 no.6
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    • pp.248-256
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    • 2012
  • A Pd-based hydrogen membranes for hydrogen purification and separation need high hydrogen perm-selectivity. The surface roughness of the support is important to coat the pinholes free and thin-film membrane over it. Also, The pinholes drastically decreased the hydrogen perm-selectivity of the Pd-based composite membrane. In order to remove the pinholes, we introduced various surface pre-treatment such as alumina powder packing, nickel electro-plating and micro-polishing pre-treatment. Especially, the micro-polishing pretreatment was very effective in roughness leveling off the surface of the porous nickel support, and it almost completely plugged the pores. Fine Ni particles filled surface pinholes with could form open structure at the interface of Pd alloy coating and Ni support by their diffusion to the membrane and resintering. In this study, a $4{\mu}m$ surface pore-free Pd-Cu-Ni ternary alloy membrane on a porous nickel substrate was successfully prepared by micro-polishing, high temperature sputtering and Cu-reflow process. And $H_2$ permeation and $N_2$ leak tests showed that the Pd-Cu-Ni ternary alloy hydrogen membrane achieved both high permeability of $13.2ml{\cdot}cm^{-2}{\cdot}min^{-1}{\cdot}atm^{-1}$ permation flux and infinite selectivity.

A Case Study on the Cause and Reinforcement of Railroad Facilities Settlement According to the Ground Excavation (지반굴착에 따른 철도시설물의 침하 원인 및 보강 사례연구)

  • Oh, Beyung-Sam
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.10
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    • pp.85-94
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    • 2012
  • Recent development trend of construction projects in the urban area is the efficient use of insufficient land, however caused to difficult construction conditions because of many adjacent structures. This paper presents the case study that analyzed the ground settlement of railroad structure for the double track railway project of Gyeongui line, adjacent to the high rise building under ground excavating for substructure work, considering interaction of soft ground characteristics. Field survey and measurement works were carried out during construction of station and excavation of high rise building, and field data were analyzed to find the source of settlement of platform and railway. In addition, the soil reinforcement and foundation restoration were performed using in-situ injection method, i.e., D-ROG(Digitalized Restoring On Grout) method which filled the pore of bottom and around of foundation with micro-cement.

Morphological and Molecular Confirmation of Parvatrema duboisi Metacercariae in the Manila Clam Ruditapes philippinarum from Gochang-gun, Korea

  • Chang, Taehee;Jung, Bong-Kwang;Shin, Hyejoo;Hong, Sooji;Lee, Jeonggyu;Kim, Deok-Gyu;Patarwut, Laddawan;Sohn, Woon-Mok;Chai, Jong-Yil
    • Parasites, Hosts and Diseases
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    • v.58 no.1
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    • pp.87-91
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    • 2020
  • Gymnophallid metacercariae found in the Manila clam Ruditapes philippinarum ('Banjirak' in Korean) from Gochang-gun, Jeollabuk-do, Korea were morphologically and molecularly confirmed to be Parvatrema duboisi (Dollfus, 1923) Bartoli, 1974. The metacercariae were morphologically characterized by having a large oral sucker, small ventral sucker, genital pore some distance anterior to the ventral sucker, no ventral pit, and 1 compact or slightly lobed vitellarium, which were all compatible with P. duboisi. Some of the metacercariae were experimentally fed to mice, and adult flukes were recovered at day 7 post-infection. The morphology of the adult flukes was basically the same as that of the metacercariae except for the presence of uterine eggs; the uterus was filled with up to 40 eggs. The nucleotide sequences (1,193 bp) from ITS regions (ITS1, 5.8S rDNA, and ITS2) of the metacercariae showed 99.7% identity with P. duboisi and 75.7% identity with Gymnophalloides seoi deposited in GenBank. These results confirmed the presence of P. duboisi metacercariae in the Manila clam R. philippinarum in an estuary region of Gochang-gun, Korea.

An Experimental Study on Factors Affecting the Leachability of Cs-137 in Cement Matrix and Leaching Model with Backfill (시멘트 고화체내 Cs-137의 침출능에 영향을 미치는 인자에 대한 실험적 연구와 뒷채움재를 고려한 침출 모델)

  • Park, Jong-Kil;Lee, Kun-Jai
    • Nuclear Engineering and Technology
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    • v.23 no.4
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    • pp.374-386
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    • 1991
  • Various factors affecting the teachability of Cs-137 in cement matrix have been investigated. Factors investigated include such as pressure curing, vibration curing, pressure leaching, the effect of the clay addition, ion-exchange resin(IRN-77) addition, and $CO_2$or air injection. Leaching experiments were conducted by the method recommended by IAEA. To analyze the experimental results, pore structure analysis of cement matrices was carried out by BET method. Cement matrices may not contact directly with underground water in real repository, since the surroundings of disposed drums are filled with backfill. Thus, the effect of backfill to the teachability has been investigated. The well-known diffusion theory was utilized to predict long term leach rate and cumulative fraction leached of Cs-137 or non-radioactive species.

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Variations of NO Concentration Released from Fertilized Japanese Upland Soil Under Different Soil Moisture Conditions

  • Kim, Deug-Soo;Haruo Tsuruta;Kazuyuki Inubushi
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.E
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    • pp.9-17
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    • 1998
  • Oxides of nitrogen play important roles in atmospheric chemistry. Soil has been recognized as a major natural source of NO, and its emission depends on soil parameters such as soil nitrogen availability, soil moisture and temperature. It is necessary to understand effects of these controlling parameters on soil NO emission. In order to understand soil moisture effects on NO emission, variations of NO concentration and existence of its equilibrium concentration were observed from ammonium fertilized Japanese upland soil prepared for different soil moisture conditions. The closed chamber technique was employed for this study. The significant increases in NO with soil moisture were found. Maximum was occurred at sample ID4 (55% of water-filled pore space (WFPS)), but it decreased as soil moisture increased. No significant NO concentration was emitted from soil sample without fertilizer, but there was significant NO in fertilized soil samples. The magnitudes of NO from soil increased with time and reached at steady state within ten minutes approximately. These results suggest that nitrogen input from fertilizer takes charge in the first step of sharp increase in NO emission, and then soil moisture becomes important factor to control NO emission from the soils. NO concentrations from soil were compared to those one-day after the experiment. Results from the comparison analysis suggest that the soil NO flux might have been stimulated by soil disturbances like mixing, and this is much more effective in dry soils rather than in wet soils. It was found that much less NO came out from soils after a day; suggesting that most of NO was released from the soils within a day after fertilizer application during our experiment. The length of NO releasing time span may depend on the amounts of fertilizer applied, soil moisture condition, and other soil physical parameters.

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