• Title/Summary/Keyword: Pore geometry

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Analysis of Contaminant Transport in the Ground using the Lattice-Boltzmann Method (격자 볼츠만 방법에 의한 지반 내 오염물질의 거동 분석)

  • Kang, Dong Hun;Yun, Tae Sup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.6C
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    • pp.267-274
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    • 2012
  • The conventional approach to evaluate the contaminant transport in soils adopts the macro-scale implementation while the pore configuration and network is a dominant factor to determine the fate of contaminant. However, the observation of fate and transport at pore scale may not be readily approachable because of the computational expenses to solve Navier-Stokes equation. We herein present the 2D Lattice-Boltzmann method that enables to assess the local fluid velocity and density efficiently for the case of single phase and multi-components. The solute fate spatio-temperal space is explicitly determined by the advection of fluid flow. Two different types of idealized pore space provides the path of fluid. Also, solute transport, the velocity field and average concentration of solute are computed in steady state. Results show that the pore geometry such as tortuosity mainly affect the solute fate. It highlights the significance of the pore configuration and shape in granular soils and rock discontinuity in spite of the equivalent porosity.

Application of the Electrical Impedance of Rocks in Characterizing Pore Geometry (암석 내 공극구조의 평가를 위한 전기임피던스의 적용)

  • Choo, Min-Kyoung;Song, In-Sun;Lee, Hi-Kweon;Kim, Tae-Hee;Chang, Chan-Dong
    • The Journal of Engineering Geology
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    • v.21 no.4
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    • pp.323-336
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    • 2011
  • The hydro-mechanical behavior of the Earth's crust is strongly dependent on the fractional volume and geometrical structure of effective pore spaces. This study aims to understand the characteristics of pores using electrical impedance. We measured the electric impedance of core samples (diameter, 38-50 mm; length, 70-100 mm) of three types of granite (Hwangdeung, Pocheon, and Yangsan) and two types of sandstone (Boryung and Berea) with different porosities and pore structures, after saturation with saline water of varying salinities. The results show that resistance decreases but capacitance increases with increasing salinity of the pore fluid. For a given salinity, the resistivity and formation factor are reduced with increasing porosity of the rocks, and the capacitance increases. Berea sandstone shows anisotropy in resistance, tortuosity, and cementation factor, with these factors being highest normal to bedding planes. This result indicates that the connectivity of pores is weakest normal to bedding. In conclusion, the electrical characteristics of the tested samples are related not only to their porosity but also to the pore geometry.

Analytical solution for undrained plane strain expansion of a cylindrical cavity in modified cam clay

  • Silvestri, Vincenzo;Abou-Samra, Ghassan
    • Geomechanics and Engineering
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    • v.4 no.1
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    • pp.19-37
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    • 2012
  • This paper presents the results of analytical and numerical analyses of the effects of performing a pressuremeter test or driving a pile in clay. The geometry of the problem has been simplified by the assumptions of plane strain and axial symmetry. Pressuremeter testing or installation of driven piles has been modelled as an undrained expansion of a cylindrical cavity. Stresses, pore water pressures, and deformations are found by assuming that the clay behaves like normally consolidated modified Cam clay. Closed-form solutions are obtained which allow the determination of the principal effective stresses and the strains around the cavity. The analysis which indicates that the intermediate principal stress at critical state is not equal to the mean of the other two principal stresses, except when the clay is initially isotropically consolidated, also permits finding the limit expansion and excess pore water pressures by means of the Almansi finite strain approach. Results are compared with published data which were determined using finite element and finite difference methods.

Effect of Oil on Pool Boiling of Refrigerant on Enhanced Tubes having Different Pore Sizes (다공도가 다른 전열촉진관의 냉매 풀비등에 미치는 오일의 영향)

  • Kim Nae-Huyn;Lee Eung-Ryul;Min Chang-Keun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.3
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    • pp.254-261
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    • 2006
  • The effect of enhanced geometry (pore diameter, gap width) is investigated on the pool boiling of R-123/oil mixture for the enhanced tubes having pores with connecting gaps. Tubes with different pore diameters (and corresponding gap widths) are specially made. Significant heat transfer degradation by oil is observed for the present enhanced tubes. At 5% oil concentration, the degradation is 26 to 49% for $T_{sat}=4.4^{\circ}C$. The degradation increases 50 to 67% for $T_{sat}=26.7^{\circ}C$. The heat transfer degradation is significant even with small amount of oil (20 to 38% degradation at 1% oil concentration for $T_{sat}=4.4^{\circ}C$), probably due to the accumulation of oil in sub-tunnels. The pore size (or gap width) has a significant effect on the heat transfer degradation. The maximum degradation is observed for $d_p$ = 0.20 mm tube at $T_{sat}=4.4^{\circ}C$, and for $d_p$=0.23 mm tube at $T_{sat}=26.7^{\circ}C$. The minimum degradation is observed for $d_p$=0.27 mm tube for both saturation temperatures. It appears that the oil removal is facilitated for the larger pore diameter (along with larger gap) tube. The highest heat transfer coefficient with oil is obtained for $d_p$ =0.23 mm tube, which yielded the highest heat transfer coefficient for pure R-123. The heat transfer degradation increases as the heat flux decreases.

Preparation and Pore-Characteristics Control of Nano-Porous Materials using Organometallic Building Blocks

  • Oh, Gyu-Hwan;Park, Chong-Rae
    • Carbon letters
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    • v.4 no.1
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    • pp.1-9
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    • 2003
  • Recently, the control of pore-characteristics of nano-porous materials has been studied extensively because of their unique applications, which includes size-selective separation, gas adsorption/storage, heterogeneous catalysis, etc. The most widely adopted techniques for controlling pore characteristics include the utilization of pillar effect by metal oxide and of templates such as zeolites. More recently, coordination polymers constructed by transition metal ions and bridging organic ligands have afforded new types of nano-porous materials, porous metal-organic framework(porous MOF), with high degree and uniformity of porosity. The pore characteristics of these porous MOFs can be designed by controlling the coordination number and geometry of selected metal, e.g transition metal and rare-earth metal, and the size, rigidity, and coordination site of ligand. The synthesis of porous MOF by the assembly of metal ions with di-, tri-, and poly-topic N-bound organic linkers such as 4,4'-bipyridine(BPY) or multidentate linkers such as carboxylates, which allow for the formation of more rigid frameworks due to their ability to aggregate metal ions into M-O-C cluster, have been reported. Other porous MOF from co-ligand system or the ligand with both C-O and C-N type linkage can afford to control the shape and size of pores. Furthermore, for the rigidity and thermal stability of porous MOF, ring-type ligand such as porphyrin derivatives and ligands with ability of secondary bonding such as hydrogen and ionic bonding have been studied.

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Pixel-Structured Scintillator with Polymeric Microstructures for X-Ray Image Sensors

  • Jung, Im-Deok;Cho, Min-Kook;Bae, Kong-Myeong;Lee, Sang-Min;Jung, Phill-Gu;Kim, Ho-Kyung;Kim, Sung-Sik;Ko, Jong-Soo
    • ETRI Journal
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    • v.30 no.5
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    • pp.747-749
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    • 2008
  • We introduce a pixel-structured scintillator realized on a flexible polymeric substrate and demonstrate its feasibility as an X-ray converter when it is coupled to photosensitive elements. The sample was prepared by filling $Gd_2O_2S:Tb$ scintillation material into a square-pore-shape cavity array fabricated with polyethylene. For comparison, a sample with the conventional continuous geometry was also prepared. Although the pixelated geometry showed X-ray sensitivity of about 58% compared with the conventional geometry, the resolving power was improved by about 70% above a spatial frequency of 3 $mm^{-1}$. The spatial frequency at 10% of the modulation-transfer function was about 6 $mm^{-1}$.

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Three-dimensional numerical analysis of nonlinear phenomena of the tensile resistance of suction caissons

  • Azam, Arefi;Pooria, Ahad;Mehdi, Bayat;Mohammad, Silani
    • Geomechanics and Engineering
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    • v.32 no.3
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    • pp.255-270
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    • 2023
  • One of the main parameters that affect the design of suction caisson-supported offshore structures is uplift behavior. Pull-out of suction caissons is profoundly utilized as the offshore wind turbine foundations accompany by a tensile resistance that is a function of a complex interaction between the caisson dimensions, geometry, wall roughness, soil type, load history, pull-out rate, and many other parameters. In this paper, a parametric study using a 3-D finite element model (FEM) of a single offshore suction caisson (SOSC) surrounded by saturated soil is performed to examine the effect of some key factors on the tensile resistance of the suction bucket foundation. Among the aforementioned parameters, caisson geometry and uplift loading as well as the difference between the tensile resistance and suction pressure on the behavior of the soil-foundation system including tensile capacity are investigated. For this purpose, a full model including 3-D suction caisson, soil, and soil-structure interaction (SSI) is developed in Abaqus based on the u-p formulation accounting for soil displacement (u) and pore pressure, P.The dynamic responses of foundations are compared and validated with the known results from the literature. The paper has focused on the effect of geometry change of 3-D SOSC to present the soil-structure interaction and the tensile capacity. Different 3-D caisson models such as triangular, pentagonal, hexagonal, and octagonal are employed. It is observed that regardless of the caisson geometry, by increasing the uplift loading rate, the tensile resistance increases. More specifically, it is found that the resistance to pull-out of the cylinder is higher than the other geometries and this geometry is the optimum one for designing caissons.

First-Order Mass Transfer in a Diffusion-Dominated (Immobile) Zone of an Axisymmetric Pore: Semi-Analytic Solution and Its Limitations (대칭형 다공성 매질의 확산주도 영역에 관한 1차 물질이동 방정식)

  • Kim, Young-Woo;Kang, Ki-jun;Cho, Jung-ho;Kabala, Zbigniew
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4664-4670
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    • 2010
  • Comparison of the classical mobile-immobile zone (MIM) model to the derived model led to several conclusions. If the MIM model is to be applied, the initial concentration in the immobile zone has to be down-scaled by a correction factor that is a function of pore geometry. The MIM model was valid only after sufficiently long time has passed, i.e., only after the diffusion front reaches the deepest pore wall in the immobile zone. The MIM mass-transfer coefficient $\alpha$, was inversely proportional to the square of the pore depth. Also it did not depend on the mobile-zone flow velocity, contrary to the number of laboratory and field observations. The classical MIM model displayed a rapid exponential decay of immobile-zone concentration. Meanwhile at large times, the newly derived model displayed similar exponential decay. This was contrary to the mounting evidence of power-law BTC tails observed in laboratory and field settings.

Understanding and predicting physical properties of rocks through pore-scale numerical simulations (공극스케일에서의 시뮬레이션을 통한 암석물성의 이해와 예측)

  • Keehm, Young-Seuk;Nur, Amos
    • 한국지구물리탐사학회:학술대회논문집
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    • 2006.06a
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    • pp.201-206
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    • 2006
  • Earth sciences is undergoing a gradual but massive shift from description of the earth and earth systems, toward process modeling, simulation, and process visualization. This shift is very challenging because the underlying physical and chemical processes are often nonlinear and coupled. In addition, we are especially challenged when the processes take place in strongly heterogeneous systems. An example is two-phase fluid flow in rocks, which is a nonlinear, coupled and time-dependent problem and occurs in complex porous media. To understand and simulate these complex processes, the knowledge of underlying pore-scale processes is essential. This paper presents a new attempt to use pore-scale simulations for understanding physical properties of rocks. A rigorous pore-scale simulator requires three important traits: reliability, efficiency, and ability to handle complex microstructures. We use the Lattice-Boltzmann (LB) method for singleand two-phase flow properties, finite-element methods (FEM) for elastic and electrical properties of rocks. These rigorous pore-scale simulators can significantly complement the physical laboratory, with several distinct advantages: (1) rigorous prediction of the physical properties, (2) interrelations among the different rock properties in a given pore geometry, and (3) simulation of dynamic problems, which describe coupled, nonlinear, transient and complex behavior of Earth systems.

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Iron(III) removal from aqueous solution using MCM-41 ceramic composite membrane

  • Basumatary, Ashim Kumar;Kumar, R. Vinoth;Pakshirajan, Kannan;Pugazhenthi, G.
    • Membrane and Water Treatment
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    • v.7 no.6
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    • pp.495-505
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    • 2016
  • Mesoporous MCM-41 was deposited on an inexpensive disk shaped ceramic support through hydrothermal technique for ultrafiltration of $Fe^{3+}$ from aqueous solution. The ceramic support was fabricated using uni-axial compaction technique followed by sintering at $950^{\circ}C$. The characteristics of MCM-41 powder as well as the composite membrane were examined by X-ray diffraction (XRD), thermogravimetric analysis (TGA), field emission scanning electron microscope (FESEM), porosity and pure water permeation test. The XRD result revealed the good crystallinity and well-resolved hexagonally arranged pore geometry of MCM-41. TGA profile of synthesized MCM-41 zeolite displayed the three different stepwise mechanisms for the removal of organic template. The formation of MCM-41 on the porous support was verified by FESEM analysis. The characterization results clearly indicated that the accumulation of MCM-41 by repeated coating on the ceramic disk directs to reduce the porosity and pore size from 47% to 23% and 1.0 to $0.173{\mu}m$, respectively. Moreover, the potential of the fabricated MCM-41 membrane was investigated by ultrafiltration of $Fe^{3+}$ from aqueous stream at various influencing parameters such as applied pressure, initial feed concentration and pH of solution. The maximum rejection 85% was obtained at applied pressure of 276 kPa and the initial feed concentration of 250 ppm at pH 2.