• 자원환경지질
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• 제32권3호
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• pp.293-306
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• 1999

The lower Permian jungseong Formation, Taebaegsan basin (Baegunsan Syncline), represents a coal-bearing siliciclastic succession which was later modified by the Songrim or Dabo orogeny. Sandstone perography and clay mineralogy were studied to understand the thermal history of the Jangseong Formation during basin evolution. Petrographic study indicates the Jangseong sandstones are composed of quartz, feldspar, lithic fragments (metamorphic and sedimetary), and varying proportions of matrix and cement. The dominance of quartz(<97%) over feldspar (<1%) and lithic fragments (<2%) classifies most Jangseong sandstones as quartz arenotes or quartzwackes, but lithic graywackes and sublithic arenite locally occur. The diagentic features of these sandstones include mechanical compaction, cemenation by quartz and clay minerals indentified in the Jangseong Formation by X-ray diffraction analysis are late-stage clay pore-filling. Clay minerals isdentified in the Jangseong Formation by X-ray diffaction analysis are illite, kaolinte, and pyrophyllite with a minor amount of chlorite and micas. The illite, kaolinite, and pyrophyllite appear to be largely autjigenic based on their well-crystallinity forms. There authigenic clay minerals form clay minerals form clay coats/rims and late-stage pore-filling cements, Illitecrystallinity shows that the Jangseong formation has been in late-diagenetic zone to early-epizone, which ranges in temperature from $200^{\circ}C$ to $300^{\circ}C$. In assition, kaolinite-pyrophyllite transition suggests that paleotemperature of the formation has reached at least $265^{\circ}C$. Such temperatureis likely to be consistent with homogenixation temperatures of fluid inclusions in quartz veins in the formation. Thus, the Jangseong Formation has been subjected to paleotemperature of about $265^{\circ}C$. The major heat source responsible for paleotemperature may be hydrothermal solutions. The passage of hydrothermal solutions was probably assisted by fractures created during the basin-modifying tectonism of the taebaegsan basin.

• 한국해양학회지
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• 제28권3호
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• pp.229-240
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• 1993

조간대 퇴적물 내에서 황화물의 형성과 그 행동을 고찰하기 위해 황해 경기만에 위치한 반월조간 대에서 1990년부터 1992년에 걸쳐 총 7번의 주상시료를 채취하여, 황 상염, 암모늄, 인산염, 황화수소, 철이온 등의 공극수 용존성분과 AVS, 원소황, pyrite sulfur 등의 퇴적물 내 황화물을 분석하였다. 공극수에서 황화수소, 암모늄, 인산염 등의 농도가 활발한 황산염환원의 결과로 이인해 깊이에 따라 증가하는 경향이 나타났다. 한편 철이온의 농도는 표 아래에서 급격히 감소했는데, 황화수소의 농도를 고려할 때 이는 황화물의 형성을 지시하는 것으로 생각된다. 퇴적물 내의 황화물을 분 석한 결과 총황화물의 양은 최고 7.9 mg/g 이었다. 황화물 중 가장 우세한 형태는 AVS 로 언제나 전체 황화물의 50%를 넘었으며, 가장 안정한 형태의 황화물로 알려진 pyrite sulfur가 element sulfuur보다 약간 많았다. 이 지역에서 퇴적물 내 황화물 중 ASV는 언제나 활발하게 만들 어지지만, ASV와 element sulfur의 반응으로 형성되는 pyrite sulfur 는 그 형성이 제한되기 때문으로 생각된다. 그리고 가장 중요한 제한 요소는 element sulfur의 양으로 생각된다.

• 한국식품조리과학회지
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• 제13권1호
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• pp.64-69
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• 1997

벼 8품종의 현미와 백미로 쌀빵을 제조하여 쌀빵가공성에 대한 벼 품종간 및 현 백미간 비교를 실시하고 관련특성간 상관관계를 살펴 보았다. 벼 품종간에는 제빵성의 차이가 있으나 현미와 백미간에는 유의한 차이가 없었다. 그러나 품종에 따라서는 현미와 백미간에 쌀빵특성의 현저한 차이를 나타내었다. 찰벼 품종인 한강찰벼는 백미로는 쌀빵의 제조가 불가능하였으나 현미로는 다른 어떤 품종 보다도 제빵성이 우수한 결과를 얻었다. 메벼 품종들 중에서는 AC 27, IR 44, 수원조가 백미의 제빵성이 우수하였고, 이 세 품종을 제외하고는 모두 백미보다 현미로 쌀빵을 만들 경우 가공특성이 좋은 경향이 있었다. 쌀의 일반성분 및 쌀빵의 제 특성 간의 상관성을 현미와 백미에 대해 별도로 살펴보면, 현미의 경우에는 부피 증가율이 큰 쌀빵 반죽일수록 푹신한 감이 있는 쌀빵 제조가 가능하였고, 촉촉한 쌀빵일수록 부드럽고 응집성이 높은 경향이었다. 백미의 경우에는 단백질 함량이 낮을수록 촉촉한 느낌의 쌀빵이 되는 경향이었으며, 지질함량이 높을수록 기공의 크기가 작고 균일하며 탄력성이 적은 쌀빵이 제조되는 경향이 있었다 또한 쌀빵 성형이 양호할수록 경도 및 씹힘성이 낮은 부드러운 빵이되는 경향이었으며, 기공의 크기가 균일할수록 기공의 크기가 작으면서 푹신한 감이나 탄력성이 낮은 빵이 되는 경향이었다.

• 한국세라믹학회지
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• 제40권12호
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• pp.1213-1219
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• 2003

비정질알루미나에 기공형성제를 첨가하여 성형하고 수열반응, 열처리 및 수세를 통해 pellet 형태의 다공성 세라믹 담체를 제조하였다. 기공형성제는 64, 222, 405 $\mu\textrm{m}$의 평균 입경을 가지는 활성탄, 폴리머와 무기염의 변화를 두었으며, 20$0^{\circ}C$에서 24시간동안 수열반응 한 다음 $650^{\circ}C$에서 5시간동안 열처리 및 8$0^{\circ}C$에서 48시간 동안 수세하고, 결정의 생성 및 변화, 기공률, 기공의 분포 및 압축 강도를 측정하였다. 수열반응 이후 활성탄이 첨가된 시편은 boehmite로의 상전이가 이루어졌으나, 기공형성제로 폴리머 및 무기염이 첨가된 시편은 수열 반응 시 비정질알루미나의 aquohydroxy complex gel의 형성을 방해하여 boehmite 결정성장 억제를 가져왔다 활성탄을 기공형성제로 첨가하여 제조한 시편의 경우, 70% 이상의 기공률과 40kgf/$\textrm{cm}^2$ 이상의 강도를 갖는 ${\gamma}$-알루미나의 담체를 제조할 수 있었다.

• Journal of Pharmaceutical Investigation
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• 제40권4호
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• pp.245-250
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• 2010

Porous poly(lactic-co-glycolic acid) microspheres (PLGA MS) have been utilized as an inhalation delivery system and a matrix scaffold system for tissue engineering. Here, gelatin (type A) is introduced as an extractable pH-responsive porogen, which is capable of controlling the porosity and pore size of PLGA microspheres. Porous PLGA microspheres were prepared by a water-in-oil-in-water ($w_1/o/w_2$) double emulsification/solvent evaporation method. The surface morphology of these microspheres was examined by varying pH (2.0~11.0) of water phases, using scanning electron microscopy (SEM). Also, their porosity and pore size were monitored by altering acidification time (1~5 h) using a phosphoric acid solution. Results showed that the pore-forming capability of gelatin was optimized at pH 5.0, and that the surface pore-formation was not significantly observed at pHs of < 4.0 or > 8.0. This was attributable to the balance between gel-formation by electrostatic repulsion and dissolution of gelatin. The appropriate time-selection between PLGA hardening and gelatin-washing out was considered as a second significant factor to control the porosity. Delaying the acidification time to ~5 h after emulsification was clearly effective to make pores in the microspheres. This finding suggests that the porosity and pore size of porous microspheres using gelatin can be significantly controlled depending on water phase pH and gelatin-removal time. The results obtained in this study would provide valuable pharmaceutical information to prepare porous PLGA MS, which is required to control the porosity.

• 한국건축시공학회지
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• 제18권3호
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• pp.305-312
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• 2018

This study is about the development of a non-sintered binder (NSB) which does not require a sintering process by using the industrial by-products Phosphogypsum (PG), Waste Lime (WL) and Granulated Blast Furnace Slag (GBFS). In this report, through SEM analysis of the NSB paste hardening body, micropore analysis of paste using the mercury press-in method and microstructure observation were executed to consider the influence of the formation of the pore structure and the distribution of pore volume on strength, and the following conclusions were reached. 1) Pore structure of NSB paste of early age is influenced by hydrate generation amount by GBFS and activator. 2) Through observing the internal microstructure of NSB binder paste, it was found that the strength expression at early age due to hydration reaction was achieved with a large amount of ettringite serving as the frame with C-S-H gel generated at the same time. It was confirmed that C-S-H gel wrapped around ettringite, and as time passed, the amount generated continually increased, and C-S-H gel tightly filled the pores of hardened paste, forming a dense network-type web structure. 3) For NSB-type cement, the degree of formation of gel pores below $10{\mu}m$ had a greater influence on strength improvement than simple pore reduction by charging capillary pores, and the pore size that had the greatest effect on strength was micropores with diameter below $10{\mu}m$.

• 멤브레인
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• 제15권1호
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• pp.22-33
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• 2005

비대칭 폴리비닐리덴플루오라이드(PVDF) 막을 상전환법으로 제조하였다. 도포용액은 PVDF를 용매인 N-ethyl-2-pyrrolidone (NMP)와 비용매인 1,4-dioxane, diethyleneglycol dimethyl ether (DGDE), acetone, (equation omitted)-butyrolactone(GBL)의 혼합용매에 녹여서 제조한다. 여러 첨가제가 도포용액 특성, 투과특성과 막 구조에 미치는 영향을 조사하였다. 응고제인 물과 1,4-dioxane, DGDE, acetone과의 상용성이 NMP보다 낮아서 기공크기가 작아진다. 첨가제의 양을 조절하여 기공크기를 변화시켰다. 혼합용매(수계 및 비수계)가 막의 투과성능에 미치는 영향을 살펴보았다. 용액점도뿐만 아니라 표면장력도 용매 투과특성에 영향을 끼침을 알 수 있었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.107-110
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• 1999

The objective of this study is to obtain characteristics of early age pore-structure and carbonation of concrete using ground granulated blast furnace slag (GGBFS). The durability of GGBFS concrete should be evaluated for wide use of the GGBFS. As for that evaluation, an analysis on early age pore-structure characteristics of GGBFS concrete are very important, Carbonation depths of GGBFS concrete, which are known to be larger than that of OPC, are different according to replacement ratios and fineness of slag. Because sea sand as fine aggregate is much used recently, it is also necessary to analyze characteristics of carbonation of GGBFS concrete. In this study, The micro-pore structure formation characteristics of GGBFS concrete are obtained through the test of GGBFS mortars with different fineness and replacement ratio of GGBFS. The carbonation of GGBFS concrete is also investigated by acclerated carbonation test for early age GGBFS concrete.

• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.372-378
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• 2010

Membrane disruption by an antimicrobial peptide, protegrin-1 (PG-1), was investigated by measuring the $^2H$ solid-state nuclear magnetic resonance (SSNMR) spectra of 1-palmitoyl-$d_{31}$-2-oleoyl-sn-glycero-3-phosphatidylcholine (POPC_$d_{31}$) in the mixture of PG-1 and POPC_$d_{31}$ lipids deposited on thin cover-glass plates. The experimental line shapes of anisotropic $^2H$ SSNMR spectra measured at various peptide-to-lipid (P/L) ratios were simulated reasonably by assuming the mosaic spread of bilayers containing pore structures or the coexistence of the mosaic spread of bilayers and a fast-tumbling isotropic phase. Within a few days of incubation in the hydration chamber, the pores were formed by the peptide in the POPC_$d_{31}$ and POPC_$d_{31}$/cholesterol membranes. However, the formation of the pores was not clear in the POPC_$d_{31}$/1-palmitoyl-2-oleoyl-sn-glycero-3-phosphatidylglycerol (POPG) membrane. Over a hundred days after hydration, a rapidly rotating isotropic phase increased in the POPC_$d_{31}$ and the POPC_$d_{31}$/cholesterol membranes with the higher P/L ratios, but no isotropic phase appeared in the POPC_$d_{31}$/POPG membrane. Cholesterol added in the POPC bilayer acted as a stabilizer of the pore structure and suppressed the formation of a fast-tumbling isotropic phase.

• Journal of Advanced Marine Engineering and Technology
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• 제39권8호
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• pp.838-842
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• 2015

The Li-air battery is a promising candidate for the most energy-dense electrochemical power source because it has 5 to 10 times greater energy storage capacity than that of Li-ion batteries. However, the Li-air cell performance falls short of the theoretical estimate, primarily because the discharge terminates well before the pore volume of the air electrode is completely filled with lithium oxides. Therefore, the structure of carbon used in the air electrode is a critical factor that affects the performance of Li-air batteries. In a previous study, we reported a new class of carbon nanomaterial, named carbon nanoballs (CNBs), consisting of highly mesoporous spheres. Structural characterization revealed that the synthesized CNBs have excellent a meso-macro hierarchical pore structure, with an average diameter greater than 10 nm and a total pore volume more than $1.00cm^3g^{-1}$. In this study, CNBs are applied in an actual Li-air battery to evaluate the electrochemical performance. The formation mechanism and electrochemical performance of the CNBs are discussed in detail.