• Title/Summary/Keyword: Pore flow

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Impact of Air Convection on H3PO4-Activated Biomass for Sequestration of Cu (II) and Cd (II) Ions

  • Girgis, Badie S.;Elkady, Ahmed A.;Attia, Amina A.;Fathy, Nady A.;Abdel Wahhab, M. A.
    • Carbon letters
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    • v.10 no.2
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    • pp.114-122
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    • 2009
  • Crushed, depitted peach stones were impregnated activated with 50% $H_3PO_4$ followed by pyrolysis at $500^{\circ}C$. Two activated carbons were produced, one under its own evolved gases during pyrolysis, and the second conducted with air flow throughout the carbonization stage. Physicochemical properties were investigated by several procedures; carbon yield, ash content, elemental chemical analysis, TG/DTG and FTIR spectra. Porosity characteristics were determined by the conventional $N_2$ adsorption at 77 K, and data analyzed to get the major texture parameters of surface area and pore volume. Highly developed activated carbons were obtained, essentially microporous, with slight effect of air on the porous structure. Oxygen was observed to be markedly incorporated in the carbon matrix during the air treatment process. Cation exchange capacity towards Cu (II) and Cd (II) was tested in batch single ion experimental mode, which proved to be slow and a function of carbon dose, time and initial ion concentration. Copper was up taken more favorably than cadmium, under same conditions, and adsorption of both cations was remarkably enhanced as a consequence of the air treatment procedure. Sequestration of the metal ions was explained on basis of the combined effect of the oxygen functional groups and the phosphorous-containing compounds; both contributing to the total surface acidity character.

Effect of the Conducting Agent on Characteristics of Cathode for Zn/Air Batteries (도전재 종류 및 함량에 따른 아연공기전지의 cathode특성연구)

  • Kim, Jee-Hoon;Eom, Seung-Wook;Moon, Seong-In;Yun, Mun-Soo;Kim, Ju-Yong;Yug, Gyeong-Chang;Park, Jeong-Hoo
    • Journal of the Korean Electrochemical Society
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    • v.5 no.2
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    • pp.74-78
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    • 2002
  • Zinc Air battery obtain their energy density advantage over the other batteries by utilizing ambient oxygen as the cathode materials, and reusing cathode as recycled form. And specific capacity of zinc powder is as high as 820 mAh/g. However, if the pore size in cathode is small then the flow rate of air decreased, and as a result of that discharge voltage of batteries becomes low. We focused on resistance and porosity of cathode. So we studied the effects of conducting agents to zinc air batteries performance, capacity, power density, average discharge voltage, resistance. And we also measured porosity of cathode by the ASTM. So we have got optimum contents of conducting agent.

Filtration-induced pressure evolution in permeation grouting

  • Zhou, Zilong;Zang, Haizhi;Wang, Shanyong;Cai, Xin;Du, Xueming
    • Structural Engineering and Mechanics
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    • v.75 no.5
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    • pp.571-583
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    • 2020
  • Permeation grouting is of great significance for consolidating geo-materials without disturbing the original geo-structure. To dip into the filtration-induced pressure increment that dominates the grout penetration in permeation grouting, nonlinear filtration coefficients embedded in a convection-filtration model were proposed, in which the volume of cement particles in grout and the deposited particles of skeleton were considered. An experiment was designed to determine the filtration coefficients and verify the model. The filtration coefficients deduced from experimental data were used in simulation, and the modelling results matched well with the experimental ones. The pressure drop revealed in experiments and captured in modelling demonstrated that the surge of inflow pressure lagged behind the stoppage of flow channels. In addition, both the consideration of the particles loss in liquid grout and the number of filtrated particles on pore walls presented an ideal trend in filtration rate, in which the filtration rate first rose rapidly and then reached to a steady plateau. Finally, this observed pressure drop was extended to the grouting design which alters the water to cement (W/C) ratio so as to alleviate the filtration effect. This study offers a novel insight into the filtration behaviour and has a practical meaning to extend penetration distance.

Effects of Spraying Conditions on the Porosity and Hardness of Plasma Sprayed MgO Stabilized Zirconic Thermal Barrier Coatings (Plasma 용사된 MgO 안정화 지르코니아 단열피복의 기공도와 경도에 미치는 용사조건의 영향)

  • Park, Yeong-Gyu;Choe, Guk-Seon;Lee, Dong-Hui
    • Korean Journal of Materials Research
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    • v.2 no.2
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    • pp.85-94
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    • 1992
  • The size, morphology and distribution of pores which affect on the physical properties of thermal barrier coatings were investigated to find the relationship with spraying parameters. The plasma-sprayed zirconia coatings contained numerous micropores as well as macropores which were appeared as spherical and irregular pores, and cracks. The pore formation process and its characteristics were varied with spraying distance. Porosity itself was varied with spraying parameters such as spray gun current, gas flow rate and the gas used(Ar or $N_2). The Porosity of coatings was ranged from 10 to 18% with the variation of spraying conditions. The relative hardness measured by the scratch test, showed strong dependence on the porosity of coatings rather than spraying parameters.

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Growth Characteristics and Hydrocarbon Patterns of Flammable Liquid on a Vinyl Layer (비닐장판 위에서 연소된 인화성 액체의 성장 특성과 탄화 패턴)

  • Joe, Hi-Su;Choi, Chung-Seog
    • Fire Science and Engineering
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    • v.32 no.5
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    • pp.15-21
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    • 2018
  • This study examined the growth characteristics and carbonization pattern when a fire occurs due to a flammable liquid sprinkled on a vinyl floor. When acetone was sprinkled on a floor, the flame reached its peak in approximately 0.2 s after it was ignited. The lower part of the flame showed a laminar pattern while the upper part showed a turbulent pattern. The pattern showed a turbulent pattern and generated white smoke. The combustion completed floor surface showed carbonization of a dim pore pattern. In the case of benzene, an intense flame was formed in approximately 0.6 s after ignition. The flame length was measured to be approximately 50 mm. When the flame became weak, a significant amount of black smoke was generated due to incomplete combustion. The combustion completed floor surface showed carbonization of a pour pattern and splash pattern. In the case of alcohol, an intense flame was formed in approximately 1.1 s after ignition. In addition, the depth of carbonization was significant where the flammable liquid was collected and a trace of carbonization was observed at the boundary of the flow path of the flammable liquid.

Numerical Analysis of Light-weight Air Foamed Soils using Dredged Marine Clay for Soft Ground Improvement Method (준설점토 활용 경량혼합토의 연약지반개량공법 수치해석)

  • Yoon, Gillim;Kim, Sunbin
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.3
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    • pp.5-13
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    • 2014
  • This paper presents the results of a numerical investigation on applicability of Light-weighted Foam Soils (LWFS) consisted of dredged soils for soft ground improvement. The engineering properties of LWFS were comprehensively investigated based on the previous experimental tests. And three dimensional numerical models which reflect soft ground conditions were adopted to evaluate the applicability of LWFS compared to SCP and DCM. A number of cases were analyzed using a stress-pore pressure coupled model. The results indicated that LWFS method enables to reduce more settlement, lateral flow and heaving than SCP method and enable to reduce more residual settlement than DCM method. Also it was revealed that such effect depends on the properties of LWFS such as unit weight, unconfined compressive strength, deformation modulus and Poisson's ratio.

A Study on the Numerical Analysis for Soil Contamination Prediction in Incheon Area (인천지역 토양오염 조사 및 해석을 통한 장래 예측 연구)

  • Shin, Eun-Chul;Lee, Myung-Shin;Park, Jeong-Jun
    • Journal of the Korean Geosynthetics Society
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    • v.11 no.2
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    • pp.21-30
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    • 2012
  • This paper analyzes the map of soil contamination in years of 2009 by actual survey in Incheon. South-east national industrial complex and the US Army base in Bu-Pyung are turned out to be high polluted area because spilling of oil storage facilities, vehicle and glass industries. So, the soil contamination in Incheon Metropolitan area will be getting more attention. To solve this problem, the soil contamination has been predicted by using the visual Sufer and visual Modflow which are analysis program in geotechnique and water flow. The result of analysis is that F and TPH will be retarded after 5 years. However, the contamination diffusion will be increased if there is no proper management of soil contamination.

Smear Effect on Consolidation Behaviors of SCP-improved Ground (SCP 개량지만의 압밀거동에 대한 스미어 효과)

  • Kim, Yun-Tae
    • Journal of the Korean Geotechnical Society
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    • v.20 no.2
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    • pp.59-66
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    • 2004
  • Sand compaction pile (SCP)-improved ground is composite soil which consists of the SCP and the surrounding soft soil. When a surcharge load is applied to composite ground, time-dependent behaviors occur in the composite soil due to consolidation according to radial flow toward the SCP. In addition, stress transfer also takes place between the SCP and the soft soil. This paper presents the numerical results of cylindrical composite ground that was conducted to investigate smear effect on consolidation behaviors of SCP-improved ground. The results showed that the smeared zone of soft clay had a significant effect on effective stress-pore water pressure response, stress transfer mechanism and stress concentration ratio of composite ground. Amount of stress transfer between the clay and the SCP was maximum in depth of z/H=0.25, and decreased with depth. Stress concentration ratio of composite ground was not constant, but depended on consolidation process. It was also found that the value of stress concentration ratio in soft clay with smeared zone was larger than that in soft clay without smeared zone.

An Experimental Study on the Availability of Underground Air Energy Source in Non-Activity Volcanic Island (비활성 화산지역의 지중공기열원 에너지 이용에 관한 실험적 연구)

  • Kim, Yong-Hwan;Park, Sung-Seek;Kim, Woo-Jung;Kim, Nam-Jin;Hyun, Myung-Taek
    • Journal of the Korean Solar Energy Society
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    • v.34 no.5
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    • pp.73-80
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    • 2014
  • This study introduces and analyzes the geothermal energy availability in Non-active volcanic region. Jeju island in Korea is situated in non-active volcanic region. The island is composed of rock with high pore and clinker, scoria geological layer formed by volcanic activity about two million ago. Volcanic geological layers with porous characteristics have air, vapor, water and a underground structure through which air or water can move easily. For this reason, it is probable that the mechanism of energy acquisition is by convective heat transfer. For this presumption, the availability of underground air as energy source has been studied here through theoretical analysis and experimental data. The energy output of our system ranged from 2,485,076 kJ/day to 4,060,978 kJ/day monitored using variable velocity air flow controller. Our system has capability to be a reliable energy source irrespective of environmental changes. Consequently, underground air can be utilized for energy source and provide the optimal design of heating/cooling system.

A Numerical Analysis of Direct Contact Membrane Distillation for Hollow Fiber Membrane (중공사형 분리막에 대한 직접접촉식 막분리 공정의 수치해석)

  • Shin, Ho-Chul;Chung, Kun-Yong
    • Membrane Journal
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    • v.20 no.4
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    • pp.342-350
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    • 2010
  • Membrane distillation (MD) is a separation process which higher vapor pressure components are evaporated in mixed liquid solution through hydrophobic membrane with 0.1 or $0.5{\mu}m$ pore size. In this study, direct contact membrane distillation process for hollow fiber module were interpreted numerically using the "COMSOL Multiphysics" software. The variables for the system were temperatures and flow rates of lumen and shell side solutions. The permeate flux increased from 1.0 to $3.8L/m^2{\cdot}hr$ as temperature of the feed solution for lumen increased from 30 to $50^{\circ}C$. However the effect of shell solution temperature on permeate flux was relatively low. Also, the optimum velocity of lumen feed was obtained at 0.15 m/s ($Re_L=135$) by considering MD permeate flux as well as operating pressure loss.