• 제목/요약/키워드: Pore characteristics

검색결과 1,258건 처리시간 0.03초

Surface Characteristics of Hydroxyapatite Coated Surface on Nano/Micro Pore Structured Ti-35Ta-xNb Alloys

  • Jo, Chae-Ik;Choe, Han-Choel
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2014년도 추계학술대회 논문집
    • /
    • pp.185-185
    • /
    • 2014
  • In this study, we investigated surface characteristics of hydroxyapatite coated surface on nano/micro pore structured Ti-35Ta-xNb alloys. This paper was focus on morphology and corrosion resistance of Anodic oxidation. To prepare the samples, Ti-35Ta-xNb (x= 0, 10 wt. %) alloys were manufactured by arc melting and heat-treated for 12 h at $1050^{\circ}C$ in Ar atmosphere at $0^{\circ}C$ water quenching. Micro-pore structured surface was performed using anodization with a DC power supply at 280 V for 3 min, nanotube formed on Ti-35Ta-xNb alloys was performed using DC power supply at 30 V in 60 min at room temperature. Surface morphology and structure were examined by field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction.

  • PDF

콘크리트 기공 솔루션에서의 열간 압연 및 열 기계 처리 철근의 부식 특성 (Corrosion Characteristics of hot rolled and thermo-mechanically treated steel rebar in concrete pore solution)

  • 이한승;싱 지텐드라 쿠마르
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2018년도 춘계 학술논문 발표대회
    • /
    • pp.202-203
    • /
    • 2018
  • Chemistry and microstructure of steel reinforcement bars play an important role to control the corrosion in concrete environments. In present study, we have chosen two different microstructure of steel rebars produced from companies and assessed their corrosion characteristics in simulated concrete pore (SCP) solution with prolonged exposure periods. Hot rolled steel rebar showed more corrosion resistance compare to thermo-mechanically treated (TMT) one. The growth of passive is greater in hot rolled (A) than TMT (B) due to orientation of microstructure. TMT steel rebar exhibit distorted microstructure with many micro cells which enhances the galvanic coupling and induce the deterioration while on the other hand hot rolled rebars exhibit fine grain boundary which responsible in growth of uniform, adherent and protective passive film resultant improved impedance was observed.

  • PDF

버즘나무의 해부학적 성질과 종압축강도와의 관계 (The Relationship Between Anatomical Characteristics and Compression Strength Parallel to Grain of Platanus orientalis L.)

  • 오승원
    • 한국가구학회지
    • /
    • 제12권1호
    • /
    • pp.21-26
    • /
    • 2001
  • This study was carried out to get some basic information on mechanical properties of Platanus orientalis L. for the rational utilization of this wood. Relationship of anatomical characteristics with compression strength parallel to grain was analyzed using stepwise regression technique. All possible combination of 8 independent variables were regressed on compression strength parallel to grain. The summarized results in this study were as follows: 1. The compression strength parallel to grain increased with the increase of wood fiber length and wood fiber width. The strength, however, decreased with increase of number of pore per $\textrm{mm}^2$ and tangential diameter of pore. 2. The major factors affecting compression strength parallel to grain in heartwood were length of wood fiber and number of pore $per{\;}{\textrm{mm}^2}$ but width of wood fiber and length of vessel element were the important factors in sapwood.

  • PDF

Permeation Characteristics of Wastewater Containing Si Fine Particles through Ultrafiltration

  • Park, Ho-Sang;Park, Young-Tae;Lee, Seok-Ki
    • Korean Membrane Journal
    • /
    • 제5권1호
    • /
    • pp.31-35
    • /
    • 2003
  • The permeation characteristics of the wastewater containing Si fine particles were examined by ultrafiltration using the polyolefin tubular membrane module. Flux with time was due to the growth of Si cake deposited on the membrane surface and the pore plugging by fine particles. The rate of flux decline in the initial stage increased with the trans-membrane pressure. The pore blocking resistance was the dominant resistance at the initial period of filtration and the cake resistance began to dominate with the initial pore blocking resistance. The larger pores compared with the fine particles, the more the membrane pores could be blocked by the fine particles. Before and after treatment, the distribution of particle size was shifted toward to the left. Then, the average size of fine particles in the permeate was 20 nm.

Preparation of MgO with High Surface Area, and Modification of Its Pore Characteristics

  • Lee, Moon-Hee;Park, Dong-Gon
    • Bulletin of the Korean Chemical Society
    • /
    • 제24권10호
    • /
    • pp.1437-1443
    • /
    • 2003
  • Thermal decomposition of hydrated surface layer of $Mg(OH)_2$ at $500^{\circ}C$ in vacuum turned non-porous MgO into porous one with high surface area of around $270 m^2$/g. Most of its surface area, 74 %, was from micropores, and rest of it was from mesopores in wedge-shaped slits, exhibiting bimodal size distribution centered around 30 and 90${\AA}$. Rehydration followed by subsequent dehydration at $300 ^{\circ}C$ in dynamic vacuum further raised the surface area to 340 $m^2$/g. Fraction of microporous surface area was increased to 93%, and the shape of the mesopores was modified into parallel slits with a specific dimension of 32 ${\AA}$. Application of $Fe_2O_3$ over MgO via iron complex formation did not alter the pore characteristics of MgO core, except slightly increased pore dimension. Over the course of the modification, $Fe_2O_3$ stayed on the surface possibly via spill-over reaction.

MSP 기법을 적용한 고분자 전해질 연료전지 가스확산층의 포로시메트리 연구 (Porometric Study on the Gas Diffusion Layer in PEMFCs Using Method of Standard Porosimetry)

  • 이용택
    • 설비공학논문집
    • /
    • 제25권2호
    • /
    • pp.64-69
    • /
    • 2013
  • The structure of pore network of gas diffusion layers (GDLs) in PEMFCs plays a critical role in determining the transport phenomena of reaction gas as well as generated water. In addition, the interactive characteristics between water and surface of pore are no less important than the structural characteristics of pore network. In this study, porometric investigation is conducted for two kinds of GDL using method of standard porosimetry which enable to distinguish hydrophobic pores from hydrophilic pores of GDLs. The porosity of TGPH-120 decreases by 6% by adding 30 wt.% of PTFE, but the porosity of hydrophilic pores decreases by 12%. The relation of $p_c-S_{nw}$ varies with the addition of PTFE, especially at low $p_c$.

수화된 규산소다의 팽창 특성 (Expansion Characteristics of the Hydrated Sodium Silicate)

  • 공양표;조호연;서동수
    • 한국세라믹학회지
    • /
    • 제45권1호
    • /
    • pp.54-59
    • /
    • 2008
  • Hydrated sodium silicate with 25 wt% water contents was synthesized by hydrothermal reaction using anhydrous sodium silicate. The hydrated sodium silicate was expanded at $370^{\circ}C$ for 30 min. and then pulverized, classified (- 200 mesh) and press-formed. The samples were heat treated at $400{\sim}900^{\circ}C$ for 30 min. in order to study the expansion characteristics depending on heat treatment temperature. A porous body with closed pore was formed above $600^{\circ}C$. The volume expansion ratio and the pore size were increased and the specific gravity was decreased with increasing heat treatment temperature. However, the volume expansion ratio was decreased and the specific gravity was increased above $850^{\circ}C$ due to the softening of the sodium silicate.

Thermal Debinding Behavior of PIM Components Produced with Different Powder Sizes and Shapes

  • Shu, Guo-Jiun;Hwang, Kuen-Shyang
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
    • /
    • pp.219-220
    • /
    • 2006
  • To understand the effect of powder characteristics on the thermal debinding behavior, PIM parts produced with powders with different particle sizes and particle shapes were examined to determine their weight losses during thermal debinding. The results show that the average diameter of the pore channel in the compact increased when the temperature increased and when coarse powders were used. However, the weight loss rates did not increase proportionally with the pore size. This suggests that the different powders that are frequently used in PIM parts do not affect the thermal debinding rate significantly. This is because the pore size is much larger than the mean free path of the decomposed gas molecules. Thus, the diffusion rates of the gases are not rate-controlling in thermal debinding. The controlling mechanism of the thermal debinding rate is the decomposition of the backbone binder in the PIM parts.

  • PDF

동결건조 공정에서 동결제의 응고조건이 기공특성에 미치는 영향 (Effect of Solidification Condition of Sublimable Vehicles on the Pore Characteristics in Freeze Drying Process)

  • 석명진;김지순;오승탁
    • 한국분말재료학회지
    • /
    • 제21권5호
    • /
    • pp.366-370
    • /
    • 2014
  • The present study demonstrates the effect of solidification condition on the pore structure in freeze drying process using the slurries of CuO/sublimable vehicles. Camphene and Camphor-45 wt% naphthalene based slurries with 14 vol% CuO powder were frozen into a mold at $-25^{\circ}C$, followed by sublimation at room temperature. The green bodies were hydrogen-reduced and sintered at $500^{\circ}C$ for 1 h. The porous Cu specimen, frozen the CuO/camphene slurry into the heated mold of the upper part, showed large pores with unidirectional pore channels and small pores in their internal wall. Also, it was observed that the size of large pores was decreasing near the bottom part of specimen. The change of pore structure depending on the freezing condition was explained by the nucleation behavior of camphene crystals and rearrangement of solid powders during solidification. In case of porous Cu prepared from CuO/Camphor-naphthalene system, the pore structure exhibited plate shape as a replica of the original structure of crystallized vehicles with hypereutectic composition.

Simulating the influence of pore shape on the Brazilian tensile strength of concrete specimens using PFC2D

  • Haeri, Hadi;Sarfarazi, Vahab;Zhu, Zheming;Marji, Mohammad Fatehi
    • Computers and Concrete
    • /
    • 제22권5호
    • /
    • pp.469-479
    • /
    • 2018
  • The Brazilian tensile strength of concrete samples is a key parameter in fracture mechanics since it may significantly change the quality of concrete materials and their mechanical behaviors. It is well known that porosity is one of the most often used physical indices to predict concrete mechanical properties. In the present work the influence of porosity shape on concrete tensile strength characteristics is studied, using a bonded particle model. Firstly numerical model was calibrated by Brazilian experimental results and uniaxial test out puts. Secondly, Brazilian models consisting various pore shapes were simulated and numerically tested at a constant speed of 0.016 mm/s. The results show that pore shape has important effects on the failure pattern. It is shown that the pore shape may play an important role in the cracks initiation and propagation during the loading process which in turn influence on the tensile strength of the concrete samples. It has also been shown that the pore size mainly affects the ratio of uniaxial compressive strength to that of the tensile one in the simulated material samples.