• 제목/요약/키워드: Pore characteristics

검색결과 1,249건 처리시간 0.026초

Pore structure evolution characteristics of sandstone uranium ore during acid leaching

  • Zeng, Sheng;Shen, Yuan;Sun, Bing;Zhang, Ni;Zhang, Shuwen;Feng, Song
    • Nuclear Engineering and Technology
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    • 제53권12호
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    • pp.4033-4041
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    • 2021
  • To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased.

Effect of the Pore Structure of Concrete on the Compressive Strength of Concrete and Chloride Ions Diffusivity into the Concrete

  • Kim, Jin-Cheol;Paeng, Woo-Seon;Moon, Han-Young
    • 콘크리트학회논문집
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    • 제15권2호
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    • pp.345-351
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    • 2003
  • The transport characteristics of deleterious ions such as chlorides depend on the pore structures of concrete and are the major factors in the durability of concrete structures in subjected to chloride attack such as in marine environments. In this paper, the effect of the pore structure on compressive strength and chloride diffusivity of concrete was investigated. Six types of concretes were tested. The pore volume of concrete containing mineral admixtures increased in the range of 3∼30nm due to micro filling effect of hydrates of the mineral admixtures. There was a good correlation between the median pore diameter, the pore volume above 50nm and compressive strength of concrete, but there was not a significant correlation between the total pore volume and compressive strength. The relationship between compressive strength and chloride diffusivity were not well correlated, however, pore volume above 50nm were closely related to the chloride diffusion coefficient.

파랑-구조물-지반 상호작용에 의한 혼성제 주변 해저지반의 3차원 동적응답 특성 (3-D Dynamic Response Characteristics of Seabed around Composite Breakwater in Relation to Wave-Structure-Soil Interaction)

  • 허동수;박종률;이우동
    • 한국해양공학회지
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    • 제30권6호
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    • pp.505-519
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    • 2016
  • If the seabed is exposed to high waves for a long period, the pore water pressure may be excessive, making the seabed subject to liquefaction. As the water pressure change due to wave action is transmitted to the pore water pressure of the seabed, a phase difference will occur because of the fluid resistance from water permeability. Thus, the effective stress of the seabed will be decreased. If a composite breakwater or other structure with large wave reflection is installed over the seabed, a partial standing wave field is formed, and thus larger wave loading is directly transmitted to the seabed, which considerably influences its stability. To analyze the 3-D dynamic response characteristics of the seabed around a composite breakwater, this study performed a numerical simulation by applying LES-WASS-3D to directly analyze the wave-structure-soil interaction. First, the waveform around the composite breakwater and the pore water pressure in the seabed and rubble mound were compared and verified using the results of existing experiments. In addition, the characteristics of the wave field were analyzed around the composite breakwater, where there was an opening under different incident wave conditions. To analyze the effect of the changed wave field on the 3-D dynamic response of the seabed, the correlation between the wave height distribution and pore water pressure distribution of the seabed was investigated. Finally, the numerical results for the perpendicular phase difference of the pore water pressure were aggregated to understand the characteristics of the 3-D dynamic response of the seabed around the composite breakwater in relation to the water-structure-soil interaction.

액체유출법에 의한 폴리에스테르 직물의 기공 크기 및 분포 측정 (Pore Size and Distribution of Polyester Fabrics Determined by Liquid Extraction Method)

  • 이동화;여숙영;김은애
    • 한국의류학회지
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    • 제21권1호
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    • pp.206-216
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    • 1997
  • The purpose of this study was to determine the pore size distributions (PSDs) of polyester woven fabrics by using liquid extraction method. Three types of PSDs-percent PSD, PSD per unit area of sample and PSD per unit weight of sample-were evaluated. Plain, twill and satin polyester fabrics with various fabric counts were used as specimens. Results showed that the interyarn PSDs reflected the fabric characteristics such as the fabric count and the weave type and the intrayarn PSDs reflected the thread characteristics such as the number of fibers, the fiber diameter, the thread diameter and the thread twist. Of three types of PSDs, the PSD per unit area of sample best reflect fabric and thread characteritics. As the fabric count decreased, rc increased and interyarn pore volume increased. The PSDs were skewed to the small pore sizes and the pore volumes decreased in the order of plain> twill> satin. As the number of fibers, the fiber diameter and the thread twist decreased, the intrayarn pore volumes were increased.

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Nano-engineering of Hybrid Titanium Oxide Structure (TiO2) using Pore-widening Concentration for Enhanced Superhydrophilicity

  • Yeji Choi;Chanyoung Jeong
    • Corrosion Science and Technology
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    • 제23권1호
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    • pp.41-53
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    • 2024
  • Titanium alloy is gaining attention in the medical industry due to its excellent biocompatibility and osteoconductivity. However, the natural oxide film on the titanium surface is insoluble, resulting in inadequate bone adhesion. Therefore, it is necessary to optimize the contact between biological tissues and implant surfaces, and alter the chemical composition and morphological characteristics of the implant surface. In this study, the anodization method was applied to titanium surface treatment to form a uniform and robust oxide film. Subsequently, a chemical process, pore-widening, was employed to change the morphological characteristics of the oxide film. The concentration of the pore-widening solution was varied at 2, 4, 6, and 8 wt% and the process time was set at 30 and 60 minutes. As the concentration of the pore-widening solution increased the pore diameter of the oxide film increased. Notably, at 6 wt% for 60 minutes, the oxide film exhibited a coexistence of pillars and pores. Based on this, it was determined that surface roughness increased with higher concentration and longer process time. Additionally, the presence of pillars and pores structures maximized hydrophilicity. This study provides insights into enhancing the surface properties of titanium for improved performance in medical implants.

수증기 활성화법으로 제조된 활성탄의 탄화온도에 따른 세공구조 고찰 (Characteristics of pore structure of steam activated carbon with carbonization temperature)

  • 이송우;나영수;김도한;최동훈;류동춘;송승구
    • 한국환경과학회지
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    • 제9권4호
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    • pp.345-349
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    • 2000
  • Activated carbons were prepared from Korean coal by steam activation in this study. The variation of pore structure of the activated carbons were investigated according to different carbonization temperatures. Yield, surface area, pore volume and pore structure of this activated carbon were compared with those of activated carbon prepared without carbonization. The investigated carbonization temperature ranged from 700${\circ}C$ to 1,000${\circ}C$. Carbonization was carried out in nitrogen atmosphere for 70 minutes and activation was performed by steam at 950${\circ}C$ for 210 minutes. Surface area and pore volume of the resulting activated carbons increased with carbonization temperature. Also pore volume increased by 20% compared to the activated carbon without carbonization. Especially, in mesopore region, the activated carbon carbonized at 900${\circ}C$ had more pores by 60% than that of activated carbon carbonized at other temperature.

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담배용 흡착제들의 동공 특성에 관한 연구 (Studies on Pore Characteristics of Several Adsorbents)

  • 임광수;정용순;이영택
    • 한국연초학회지
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    • 제16권2호
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    • pp.181-190
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    • 1994
  • Various active carbons were made from plant sources of coconut shell, pine tree, oak tree and lignite coal. Pore characteristics of these adsorbents were investigated. 1, With increasing activation time, specific surface area and pore volume increased, but the development of micropores was limited at a certain level. The average pore diameter, by BET, of coconut active carbon was 15.5-21.8$\AA$ and that of lignite carbon was 15.6-31.3$\AA$. The pore diameters of silica-gel, sepiolite and zeolite was 30.9$\AA$, 58.6$\AA$ and 55.7$\AA$, respectively. 2. The Horvath - Kawazoe micropore diameter of coconut shell active carbon was under 10.5$\AA$ and that of the other active carbon was under 20.9$\AA$ but silica-gel 33$\AA$, sepiolite 103 $\AA$ and zeolite was unexpectedly large to be 175$\AA$. From the difference between BET micropore diameter and Howath - Kawazoe diameter, it could be said that silica - gel has comparatively uniform pore diameter but sepiolite and zeolite have very uneven diameter. 3. Total pore volume of coconut shell active carbon was 0.27-1.04 cm3/g but that of the other active carbon, 0.23-0.62 cm3/g, was much lower than that of coconut shell active carbon. Hydrophilic adsorbent silica - gel and sepiolite showed big difference in specific surface area, but pore volumes of these were 0.47 and 0.56 cm3/g showing similar value and micropore volumes of these were, respectively, 0.06 cm3/g and 0.04 cm3/g. Total pore volume of zeolite was 0.1 cm3/g and that of micropore was only 0.02 cm3/g.

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종이의 기공 특성 측정 기법의 비교 (Comparison of Characterization Techniques of the Pore in Paper Sheet)

  • 원종명;남기영;정순기
    • 펄프종이기술
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    • 제39권4호
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    • pp.1-6
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    • 2007
  • Paper is a composite consisted of various solid materials including pulp, filler and other additives. The pore is also one of components consisting the paper structure. Thus the characterization of pore structure of paper is very helpful in the understanding the structural properties of paper. Mercury intrusion technique is frequently used for the characterization of the porous paper, giving access to parameters such as pore size and pore distribution. But some researchers pointed out the problem that the distortion of the pore structure can be occurred by the application of high pressure during mercury intrusion. Thus in this study, we tried to evaluate the potential of SEM and image analysis method as means for analyzing pore structure of the paper. The new pore analysis technique with SEM and image analysis does not require the application of high pressure, and gave better relation between the measured pore characteristics and the bulk of sheet than mercury intrusion method.

흡착제 세공 특성이 담배연기성분 제거에 미치는 영향 (Effect of Adsorbent Pore Characteristics on the Removal Efficiency of Smoke Components.)

  • 이영택;김영호;신창호;임광수
    • 한국연초학회지
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    • 제14권1호
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    • pp.87-93
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    • 1992
  • The adsorption efficiency of some adsorbents for the organic solvents and gas phase of smoke was investigated. 1. Specific surface area of activated carbon increased to 1900 mfg with increased activation time. 2. Adsorption efficiency of benzene and acetone increased with increasing total surface area. Adsorption capacity for gas phase such as hydrogen cyanide, aldehyde was proportional to the micro pore surface area under 20A. 3. The removal efficiency of particulate matter of smoke was higher with the adsorbents of relatively higher pore size compared to that of micro pore.

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섬유혼합 점토의 비배수 강도 특성에 대한 연구 (Study on the Undrained Strength Characteristics of Fiber Mixed Clay)

  • 박영곤;장병욱
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 1998년도 학술발표회 발표논문집
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    • pp.382-387
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    • 1998
  • Triaxial compression tests were run to study on the undrained strength characteristics of fiber mixed kaolin clay(Hadong). The influence of various test parameters such as amount and aspect ratio(ratio of length to diameter) of fiber, confining stress was also investigated. Test results showed that the increase in aspect ratio was increased in deviator stress at failure, but no effect on pore water pressure at failure. Deviator stress at failure was also increased at 0.5% mixing ratio(weight fraction of fiber to that of soil solid) of fiber but it was, thereafter, decreased and wits reached to constant after 2% mixing ratio. On the contrary, Pore water pressure at failure was increased as mixing ratio of fiber was greater than 1%. Deviator stress and pore water pressure of both clay and fiber mixed clay(FMC) at failure were increased as confining stress was increased. Deviator stress of FMC at failure was about 10% larger than that of clay, but pore water pressure of FMC at failure was almost similar to that of clay.

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