• Journal of environmental and Sanitary engineering
• /
• v.20 no.4 s.58
• /
• pp.45-50
• /
• 2005

Titania gel formations were prepared by sol-gel method using titanium(IV) chloride $(TiCl_4)$, and its characteristics were analyzed by varying the $epoxide/TiCl_4$ ratio and the amount of water In the end, titania $(TiO_2)$ aerogel were prepared using supercritical drying process. VOCs such as benzene, toluene, and m-xylene (BTX) were oxidized using prepared titania aerogel and commercially available $TiO_2$, and its performance was compared. The surface area, pore volume, and average pore diameter of 1,2-epoxybutane are significantly smaller than the propylene oxide. And the titania aerogels with 6 moi of epoxides have high surface areas, pore volumes, and average pore diameters. As a result of photo-oxidation, conversion of benzene was reached about $70\%$, and other reactants were reached about $60\%$ similarly. The conversion of BTX was increased as inlet concentration decreased. The reactivity of titania calcined at $600^{\circ}C$ was greater than $400^{\circ}C$ and $800^{\circ}C$. Water is required as a reactants for the oxidation of VOCs, and the continuous consumption of hydroxyl radicals required replenishments to maintain catalyst activity. The activity ratio increased with increasing reaction time when enough amount of water was present in the reactor.

• Geomechanics and Engineering
• /
• v.20 no.5
• /
• pp.411-420
• /
• 2020

Numbers fitting-curve equations have been proposed to predict soil-water retention curve (SWRC) whose parameters have no definitude physical meaning. And these methods with precondition of measuring SWRC data is time-consuming. A simplified directly method to estimate SWRC without parameters obtained by fitting-curve is proposed. Firstly, the total SWRC can be discretized into linear segments respectively. Every segment can be represented by linear formulation and every turning point can be determined by the pore-size distribution (PSD) of Mercury Intrusion Porosimetry (MIP) tests. The pore diameters governing the air-entry condition (AEC) and residual condition (RC) can be determined by the PSDs of MIP test. The PSD changes significantly during drying in SWR test, so the determination of AEC and RC should use the PSD under corresponding suction conditions. Every parameter in proposed equations can be determined directly by PSD without curve-fitting procedure and has definitude physical meaning. The proposed equations give a good estimation of both unimodal and bimodal SWRCs.

• Geomechanics and Engineering
• /
• v.33 no.1
• /
• pp.113-120
• /
• 2023

Coastal and offshore structures such as ports and offshore wind farms will often need to be built on fine-grained sediments. Geotechnical properties associated with sediment compressibility are key parameters for marine construction designs especially on soft grounds, which involve clay-mineral dominated fines that can consolidate and settle significantly in response to engineered and environmental loads. We conduct liquid limit tests and 1D consolidation tests with fine-grained soils (silica silt, mica, kaolin and bentonite) and biogenic soils (diatom). The pore fluids for the liquid limit tests include deionized water and a series of brines with NaCl salt concentrations of 0.001 m, 0.01 m, 0.1 m, 0.6 m and 2.0 m, and the pore fluids for the consolidation tests deionized water, 0.01 m, 0.6 m, 2 m. The salt concentrations help the liquid limits of kaolin and bentonite decrease, but those of diatom slightly increase. The silica silt and mica show minimal changes in liquid limit due to salt concentrations. Accordingly, compression indices of soils follow the trend of the liquid limit as the liquid limit determined the initial void ratio of the consolidation test. Diatoms are more likely to be broken than clastic sediments during to loading, and diatom-rich sediment is therefore generally more compressible than clastic-rich sediment.

• Membrane and Water Treatment
• /
• v.1 no.2
• /
• pp.121-137
• /
• 2010

This work presents inexpensive inorganic precursor formulations to yield submicron range symmetric ceramic microfiltration (MF) membranes whose average pore sizes were between 0.1 and $0.4{\mu}m$. Incidentally, the sintering temperature used in this work was about 800 to $950^{\circ}C$ instead of higher sintering temperatures ($1100^{\circ}C$) that are usually deployed for membrane fabrication. Thermogravimetric (TGA) and X-Ray diffraction (XRD) analysis were carried out to evaluate the effect of temperature on various phase transformations during sintering process. The effect of sintering temperature on structural integrity of the membrane as well as pore size distribution and average pore size were evaluated using scanning electron microscopy (SEM) analysis. The average pore sizes of the membranes were increased from 0.185 to $0.332{\mu}m$ with an increase in sintering temperature from 800 to $950^{\circ}C$. However, a subsequent reduction in membrane porosity (from 34.4 to 19.6%) was observed for these membranes. Permeation experiments with both water and air were carried out to evaluate various membrane morphological parameters such as hydraulic pore diameter, hydraulic permeability, air permeance and effective porosity. Later, the membrane prepared with a sintering temperature of $950^{\circ}C$ was tested for the treatment of synthetic oily waste water to verify its real time applicability. The membrane exhibited 98.8% oil rejection efficiency and $5.36{\times}10^{-6}\;m^3/m^2.s$ permeate flux after 60 minutes of experimental run at 68.95 kPa trans-membrane pressure and 250 mg/L oil concentration. Based on retail and bulk prices of the inorganic precursors, the membrane cost was estimated to be $220 /$m^2$ and $1.53 /$m^2$, respectively.

• Journal of Pharmaceutical Investigation
• /
• v.40 no.4
• /
• pp.245-250
• /
• 2010

Porous poly(lactic-co-glycolic acid) microspheres (PLGA MS) have been utilized as an inhalation delivery system and a matrix scaffold system for tissue engineering. Here, gelatin (type A) is introduced as an extractable pH-responsive porogen, which is capable of controlling the porosity and pore size of PLGA microspheres. Porous PLGA microspheres were prepared by a water-in-oil-in-water ($w_1/o/w_2$) double emulsification/solvent evaporation method. The surface morphology of these microspheres was examined by varying pH (2.0~11.0) of water phases, using scanning electron microscopy (SEM). Also, their porosity and pore size were monitored by altering acidification time (1~5 h) using a phosphoric acid solution. Results showed that the pore-forming capability of gelatin was optimized at pH 5.0, and that the surface pore-formation was not significantly observed at pHs of < 4.0 or > 8.0. This was attributable to the balance between gel-formation by electrostatic repulsion and dissolution of gelatin. The appropriate time-selection between PLGA hardening and gelatin-washing out was considered as a second significant factor to control the porosity. Delaying the acidification time to ~5 h after emulsification was clearly effective to make pores in the microspheres. This finding suggests that the porosity and pore size of porous microspheres using gelatin can be significantly controlled depending on water phase pH and gelatin-removal time. The results obtained in this study would provide valuable pharmaceutical information to prepare porous PLGA MS, which is required to control the porosity.

• Journal of the Korean Geotechnical Society
• /
• v.33 no.11
• /
• pp.45-57
• /
• 2017

Temperature change affects consolidation behavior of soft clays. The increase of temperature in soft clays induces the increase of pore water pressure. The dissipation of the excess pore water pressure decreases volume and void ratio. Also, the consolidation rate is accelerated by high temperature which induces the decrease of viscosity of pore fluid. The effects of temperature on the consolidation behavior such as consolidation settlement, consolidation time, and pore water pressure were investigated in this study. A numerical analysis of hydro-mechanical (HM) and thermo-hydro-mechanical (THM) behavior was performed. The combination of heat injection and sand drain for consolidating the soft ground, with varying temperature (40 and $60^{\circ}C$) and sand drain diameter (40, 60, and 80 mm), was considered. The results show that the temperature inside soil specimen increases with the increase of the temperature of heating source and the diameter of sand drain. Moreover, the heat injection increases the excess pore water pressure and, accordingly, induces additional settlement in overconsolidated (OC) state and reduces the consolidation time in normally consolidated (NC) state.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.61 no.2
• /
• pp.13-23
• /
• 2019

In this study, an overtopping model experiments and three dimensional seepage characteristics at the deteriorated homogeneous reservoirs were performed to investigate the behavior of failure for embankment and spillway transitional zone due to overtopping. The failure pattern, pore water pressure, earth pressure and settlement by overtopping were compared and analyzed. The pattern of the failure by overtopping was gradually enlarged towards reservoirs crest from the spillway transition zone at initial stage. In the rapid stage and peak stage, the width and depth of failure gradually increased, and the pattern of the failure appeared irregular and several direction of the erosion. In the early stage, the pore water pressure at spillway transitional zone was more affected as its variation and failure width increased. In the peak stage, the pore water pressure was significantly increased in all locations due to the influence of seepage. The earth pressure increased gradually according to overtopping stage. The pore pressure by the numerical analysis was larger than the experimental value, and the analysis was more likely to increase steadily without any apparent variation. The horizontal and vertical displacements were the largest at the toe of slope and at the top of the dam crest, respectively. The results of this displacement distribution can be applied as a basis for determining the position of reinforcement at the downstream slope and the crest. The collapse in the overtopping stage began with erosion of the most vulnerable parts of the dam crest, and the embankment was completely collapsed as the overtopping stage increased.

• Membrane Journal
• /
• v.14 no.2
• /
• pp.108-116
• /
• 2004

In this study, the pore-filled ion-exchange membranes were prepared by using the asymmetric PVDF membrane as a nascent membrane. First, the solution of PVBCI having the chlorornethylate aryl ring of 80 percents and DABCO was made with the mixed solvent of THF and DU (8:2). These mixed solution was then, filled in the pores of PVDF membrane, and left for a day to complete the gelation. Finally the pore-filled anion-exchange membrane is obtained fallowed by the amination of the remaining chloromethyl groups with trimethylamine (TMA, 40 wt% in water) forming the positive ammonium ion sites. This 2 step procedure enabled us to produce the pore-filled membranes without change of size, and to control the properties of final membrane with various degree of cross-linking. The results of SEM and AFM showed the polyelectrolyte existed in the pores of nascent membrane as a certain configuration. From the investigation of the solvent affecting much to the permeability and rejection, it was found that the membranes using mixed solvent of THE and DMF (8:2) showed better performances than the membranes produced by THF only. The result of an investigation for the water permeability of the final membrane at low pressure (100 Kpa) showed a typical ultrafiltration membrane's permeability (8 ∼ 10 kg/$m^2$hr) and good values of rejection (55∼60 percent).

• Journal of Environmental Science International
• /
• v.2 no.1
• /
• pp.43-49
• /
• 1993

Concentrations of sulfate and 6-values of sulfate, $({\delta}^{34}SO_4_){pw}$, dissolved In pore waters were measured from the sediment cores of the two different marine environments : deep northeast Pacific (57-1) and coastal Kyunggi Bay of Yellow Sea (57-2) . Sulfate concentration in pore waters decreases with depth at both cores, reflecting sulfate reduction in the sediment columns. However, much higher gradient of pore water sulfate at 57-2 than 57-1 indicates more rapid sulfate reduction at 57-2, because of high sedimentation rate at the coastal area compared to the deep-sea. The measured 6-values, $({\delta}^{34}SO_4_){pw}$, follow extremely well the predicted trend of the Rayleigh fractionation equation. The range of 26.756 to 61.35% at the coastal core 57-2 is not so great as that of 32.4$\textperthousand$ to 97.8$\textperthousand$ at the deep-sea core 57-1. Despite greater graclient of pore water sulfate at 57-2, the 6-values become lower than those of the deep- sea core 57-1. This inverse relation between the 6-values and the gradients of pore water sulfate could be explained by the combination of the two subsequent factors : the kinetic effect by which the residual pore water sulfate becomes progressively enriched with respect to the heavy isotope of $^{34}S$ as sulfate reduction proceeds, and the intrinsic formulation effect of the Rayleigh fractionation equation in which the greater becomes the fractionation factor, the more diminished values of $({\delta}^{34}SO_4_){pw}$ are predicted.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2002.10a
• /
• pp.385-390
• /
• 2002

Autogenous shrinkage of concrete has been defined as decrease in volume due to hydration cement, not due to other causes such as evaporation, temperature change and external load and so on. For ordinary concretes, autogenous shrinkage is so little compared to the other deformations that it has been dignored. It has recently been proved, however, that autogenous shrinkage considerably increase with decrease in water to cement ratio. And it has been reported that cracking can be caused by autogenous shrinkage, when high- strength concretes were used. In this study, we propose an analytical system to represent autogenous shrinkage in cement paste in order to control crack due to autogenous shrinkage. The system is composed with the hydration model and pore structure model. Contrary to the usual assumption of uniform properties in the hydration progress, the hydration model to refine Tomosawa's represents the situation that inner and outer products are made in cement paste. The pore structure model is based upon the physical phenomenon of ion diffusion in cement paste and chemical phenomenon of hydration in cement particle. The proposed model can predict the pore volume ratio and the pore structure in cement paste under variable environmental conditions satisfactorily The autogenous shrinkage prdiction system with regard to pore structure development and hydration at early ages for different mix-proportions shows a reasonable agreement with the experimental data.