• 제목/요약/키워드: Pore Volume

검색결과 830건 처리시간 0.029초

철근 부식속도 예측식을 이용한 철근 피복 파괴 시간 추정 (Estimation of Concrete Cover Failure Time Considering the Corrosion Rate in Reinforced Concrete Structures)

  • 장봉석
    • 콘크리트학회논문집
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    • 제18권2호
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    • pp.233-238
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    • 2006
  • 본 연구에서는 염해환경에 노출되어 있는 철근콘크리트 구조물의 수명예측에 있어서 철근덮개 파괴시간 예측을 위하여, 유한요소해석을 통한 방법을 제시하였다. 또한 본 연구에서는 인공세공용액중의 철근 부식속도로부터 콘크리트 중의 철근 부식속도를 유도하는 방법을 제시하였으며, 철근 부식의 분포에 따른 철근덮개의 파괴시간을 비교하여, 철근덮개 파괴시간을 합리적으로 예측하기 위한 방법을 제시하였다. 국부부식을 고려한 경우 균일한 부식을 가정한 경우보다 최대 약 40%정도 철근덮개 파괴시간이 짧아짐을 알 수 있다. 따라서, 철근덮개의 파괴시간 예측을 위한 유한요소해석에 있어서 국부부식을 고려하는 것이 합리적인 결과를 제시할 수 있을 것으로 사료된다.

고농도 분말활성탄 결합 MBR 운전에 대한 활성탄 교체주기의 영향 (Effect of powder activated carbon replacement on HCPAC-MBR system operation)

  • 이채하;김진태;이정현;서규태;김인수
    • 상하수도학회지
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    • 제22권1호
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    • pp.141-148
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    • 2008
  • This study was conducted to evaluate the effect of PAC(Powder Activated Carbon) retention time on stable operation of high concentration powered activated carbon(HCPAC-MBR) in the treatment of secondary domestic wastewater. The pilot scale HCPAC-MBR system was operated at two different SRTs, 25 days and 100 days. The main drawback of HCPAC-MBR system was the rapid increase of trans-membrane pressure. The increase rate of trans-membrane pressure was proportional to SRT value at constant flux. This result seemed to be caused by reduced amount of EPS adsorbed on the PAC in the reactor by decreasing the SRT of the PAC. The particle size of the PAC was also influenced by SRT. The PAC size was decreased as SRT was increased. The change of particle size could be one reason for the change of trans-membrane pressure. The pore volume in the cake-layer formed on the membrane surface became to be increased by reducing SRT, because the cake-layer was highly composed of the PAC. Therefore, increased pore volume might play a role to reduce the trans-membrane pressure. The removal rate of E260 and TOC was also inversely proportional to SRT value.

Influence of Pyrolysis Conditions and Type of Resin on the Porosity of Activated Carbon Obtained From Phenolic Resins

  • Agarwal, Damyanti;Lal, Darshan;TripathiN, V.S.;Mathur, G.N.
    • Carbon letters
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    • 제4권2호
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    • pp.57-63
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    • 2003
  • In polymer precursor based activated carbon, the structure of starting material is likely to have profound effect on the surface properties of end product. To investigate this aspect phenolic resins of different types were prepared using phenol, mcresol and formaldehyde as reactants and $Et_3N$ and $NH_4OH$ as catalyst. Out of these resins two resol resins PFR1 and CFR1 (prepared in excess of formaldehyde using $Et_3N$ as catalyst in the basic pH range) were used as raw materials for the preparation of activated carbons by both chemical and physical activation methods. In chemical activation process both the resins gave activated carbons with high surface areas i.e. 2384 and 2895 $m^2/g$, but pore size distribution in PFR1 resin calculated from Horvath-Kawazoe method, contributes mainly in micropore range i.e. 84.1~88.7 volume percent of pores was covered by micropores. Whereas CFR1 resin when activated with KOH for 2h time, a considerable amount (32.8%) of mesopores was introduced in activated carbon prepared. Physical activation with $CO_2$ leads to the formation of activated carbon with a wide range of surface area (503~1119 $m^2/g$) with both of these resins. The maximum pore volume percentage was obtained in 3-20 ${\AA}$ region by physical activation method.

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스팀을 이용한 중국산 신화 석탄 촤 가스화 반응에 관한 연구 (Gasification reactivity of Chinese Shinwha Coal Chars with Steam)

  • 강민웅;서동균;김용택;황정호
    • 한국연소학회지
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    • 제15권1호
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    • pp.22-29
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    • 2010
  • In this study, carbon conversion was measured using an electronic mass balance. In a lab scale furnace, each coal sample was pyrolyzed in a nitrogen environment and became coal char, which was then gasified with steam under isothermal conditions. The reactivity of coal char was investigated at various temperatures and steam concentrations. The VRM(volume reaction model), SCM(shrinking core model), and RPM(random pore model) were used to interpret experimental data. For each model the activation energy(Ea), pre-exponential factor (A), and reaction order(n) of the coal char-steam reaction were determined by applying the Arrhenius equation into the data obtained with thermo-gravimetric analysis(TGA). According to this study, it was found that experimental data agreed better with the VRM and SCM for 1,000 and $1,100^{\circ}C$, and the RPM for 1,200 and $1,300^{\circ}C$. The reactivity of chars increased with the increase of gasification temperature. The structure parameter(${\psi}$) of the surface area for the RPM was obtained.

저농도(低濃度) 페놀의 활성탄(活性炭)에 대한 흡착특성(吸着特性)에 관(關)한 연구(硏究) (A Study on the Adsorption Characteristic of Low Concentration Phenol by Activated Carbon)

  • 권대영;박중현
    • 상하수도학회지
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    • 제8권1호
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    • pp.34-43
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    • 1994
  • It is well known that the adsorption character of activated carbon is dependent on the specific surface area and pore volume, but the relationship between the surface-chemical structure and the adsorption character has not been studied very often. The purpose of this study is to investigate the effect of the acidic surface functional groups of activated carbon and the adsorption characteristics of low concentration phenol. So three types of activated carbons and four different treatments were introduced to this isotherm experiment. These treatments were nontreatment, 1N $HNO_3$ treatment, 6N $HNO_3$ treatment, $H_2O_2$ treatment. The conclusions of this study are as followings. If the initial concentration of phenol is high as 5mg/l, the adsorption is dependent on the specific surface area. If the initial concentration of phenol is low as $100{\mu}g/l$, the adsorption is dependent on the average pore volume. The acidic surface functional groups prevent the adsorption of phenol molecules to activated carbon. And the adsorbed amount decreases more for $HNO_3$ treatment than for $H_2O_2$ treatment and more for concentrated $HNO_3$ treatment than for dilute $HNO_3$ treatment.

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Synthesis of Nanoporous Carbon as a Gas Adsorbent by Reverse Replication Process of Silica Template

  • Cho, Churl-Hee;Kim, Joon-Soo;Kim, Hong-Soo;Ahn, Young-Soo;Han, Moon-Hee;Yoo, Jong-Sung
    • 한국세라믹학회지
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    • 제40권6호
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    • pp.519-524
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    • 2003
  • Porous carbon with high surface area and pore volume was prepared by a reverse replication process and its toluene equilibrium adsorption behavior was investigated. The preparation process of the porous carbon was composed of fellowing sub-processes in series: synthesis and template preparation of silica gel, impregnation and polymerization of DVB monomer in silica template, carbonization of DVB polymer in a silica-polymer composite, and HF-assisted selective etching of silica in carbon-silica composite. The prepared porous carbon was nano porous and had ultrahigh specific surface area (2007 ㎡/g) and large pore volume (3.07 ㎤/g). The nanoporous carbon showed rapid toluene adsorption rate and good toluene adsorption capacity, compared with a commercial Y-type zeolite. In the present study, a reverse replication process to prepare nanoporous carbons will be introduced and its application potential as a gas adsorbent will be discussed.

비이온계 계면활성제 수용액에서 모직물의 표면적심과 액체보유력 향상 (Improvement of Liquid Wetting and Retention Properties of Wool Fabric in Nonionic Surfactant Solutions)

  • 김천희
    • 한국염색가공학회지
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    • 제21권2호
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    • pp.7-13
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    • 2009
  • The effects of 0.1g/dl nonionic surfactant solutions on liquid wetting and retention properties of wool fabric are reported. The 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85), wool cloth (EMPA 217), and wool soiled cloth (EMPA 107) are used in the study. Both EMPA 217 and 107 have water contact angle($\Theta$)>$90^{\circ}$, which indicates that water spreading over a fabric surface and penetration into the fabric rarely occur. However, EMPA 217 and 107 are easily wetted with perchloroethylene(PCE) having very low values of $\Theta$'s and high values of liquid retention. Water wetting properties are greatly improved by adding nonionic surfactants into the system. Generally, hydrophilic surfactants which have low number of carbon atoms or unsaturated hydrophobic structures are effective in improving water wetting of wool fabrics. The water retention of EMPA 217 and 107 in surfactant solutions have positive relations with $cos{\Theta}$, adhesion tension, and work of adhesion. 40.3% pore volume of EMPA 217 and 26.1% pore volume of EMPA 217 can be filled with water even when we assume $cos{\Theta}=1$ (${\Theta}=0^{\circ}$).

다공성 원료를 사용한 수열합성 패널의 흡습 특성 (Hygroscopic Characteristic of Hydrothermal Reacted Panels Using Porous Materials)

  • 추용식;권춘우;송훈;이종규
    • 한국세라믹학회지
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    • 제45권12호
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    • pp.832-838
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    • 2008
  • Diatomite, bentonite and zeolite were used as porous materials for fabricating hygroscopic panels. Moisture adsorption and desorption of porous materials were investigated and hydrothermal method was applied to fabricate panels. Cheolwon diatomite and Pohang zeolite showed excellent characteristics of moisture adsorption and desorption. These characteristics were caused by higher surface area and pore volume of porous materials. Correlation coefficient between surface area and moisture adsorption content of porous materials was 0.93. Moisture adsorption contents were influenced by surface area and pore volume of panels, and surface area more effected on moisture adsorption. Correlation coefficient between surface area and moisture adsorption content of panels was 0.86. Moisture adsorption content of panel with 10% Pohang zeolite was $180\;g/m^2$ and that of 10% Cheolwon diatomite was $170\;g/m^2$. Moisture desorption content of panel with 10% Pohang zeolite was $105\;g/m^2$. Moisture adsorption contents of panel with porous materials were higher than that of panel without porous materials.

다공성 원료를 사용한 수열합성 패널의 물성과 포름알데히드 흡착 특성 (Formaldehyde Adsorption and Physical Characteristics of Hydrothermal Reacted Panels Using Porous Materials)

  • 임두혁;추용식;송훈;이종규
    • 한국세라믹학회지
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    • 제46권6호
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    • pp.627-632
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    • 2009
  • Formaldehyde emissions from the construct was harmful to human. Diatomite, bentonite and zeolite were used as porous materials for fabricating panels. Formaldehyde adsorption and physical characteristics of porous materials were investigated and hydrothermal method was applied to fabricate panels. Formaldehyde adsorption contents of panels with porous materials were higher than that of panel without porous materials. The panels with Cheolwon diatomite and Pohang zeolite showed excellent characteristics of Formaldehyde adsorption. These characteristics were caused by higher surface area and pore volume of porous materials. Formaldehyde adsorption contents were influenced by surface area and pore volume of panels. Correlation coefficient between surface area and Formaldehyde adsorption content of panels was 0.87. The panels with porous materials had higher strength than that without porous materials because of bridging role particles.

메쉬 여과모듈을 이용한 잉여슬러지 농축 (Thickening of Excess Sludge using Mesh Filter)

  • 정용준;키소 요시아키;민경석
    • 한국물환경학회지
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    • 제20권4호
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    • pp.346-351
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    • 2004
  • Because of being produced a great deal of excess sludges from biological wastewater treatment process, the subject regarding treatment and disposal of them has been significantly handled in real plants. It should be considered the alternative treatment with easy operating and cost effective process in rural areas. For the thickening of wasted activated sludge from small scale wastewater treatment facilities, thus, the provisional sludge thickening system was developed by the application of mesh filter module. Three meshes with different pore size(100, 150, $200{\mu}m$) were prepared for filter modules that were used to withdraw effluent from thickening system. A filter module with $100{\mu}m$ mesh was chosen as the most effective thickening material in the viewpoint of volume reduction and effluent quality: the volume reductions of initially injected sludge with 3,600 mg/L and 9,100 mg/L were 95% and 85%, respectively, and the filtered effluents were enough good to be shown below 1.0 mg/L of SS and 1.0 NTU of turbidity. Since the filtration of thickening was influenced by the cake layer formed on mesh filter module and this system was operated in the combination of sludge thickening with gravity settling, the filter modules with smaller pore size and the larger floc size were required for long term operation safely.