• 제목/요약/키워드: Polyurethane Form Matrix

검색결과 12건 처리시간 0.03초

다공질 폴리우레탄 폼 매트릭스 축류 회전형 열교환기의 성능특성에 관한 실험적 연구 (Experimental Study on the Performance of Axial Flow Rotary Heat Exchanger with the Porous Polyurethane Foam Matrix)

  • 태춘섭;박상동;조성환;최영돈
    • 설비공학논문집
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    • 제5권1호
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    • pp.44-54
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    • 1993
  • This is an experimental study to identify the performance of air-to-air rotary heat exchanger with polyurethane foam matrix. The experimental apparatus including heating AHU(Air Handling Unit), cooling AHU, sensor chamber, and heat exchanger testing unit was designed and manufactured in this study. The performance of heat exchanger with porous polyurethane foam matrix was tested with variations of the density and the thickness of matrix, regulating the wind velocity and the rotational speed of matrix. The actual heat recovery effectiveness, air leakage rate, and pressure drop of heat exchanger were measured and analyzed.

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난연.기능성 복합성형체 제조 및 특성

  • 현병민;강영구
    • 한국산업안전학회:학술대회논문집
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    • 한국안전학회 2002년도 춘계 학술논문발표회 논문집
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    • pp.457-460
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    • 2002
  • 현재 건축단열재, 흡음재, 바닥재로 사용되는 panel 성형, 제작하기 위해 다종의 유기고분자 matrix가 사용되고 있으며 polyurethane, vinyl acetate, urea-formaldehyde resin 또는 melamine-formaldehyde, phenol-form aldehyde resin 등을 사용하고 있으나 이러한 고분자 matrix를 사용한 건축용 panel의 경우 화재시 유독 gas와 더불어 급격한 화재전파의 매개체로 사용될 수 있어 난연제 첨가로 이러한 현상을 억제하고 있다.(중략)

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Segmented Polyurethanes with BHPP, 2, 2-bis[4-(2-hydroxy-ethoxy)phenyl] propane, as a Chain Extender.

  • Lee, Dong-Won;Lim, Sang-Kyoo;Jang, Doo-Sang;Koo, Kang;Son, Tae-Won
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 봄 학술발표회 논문집
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    • pp.5-8
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    • 1998
  • Polyurethane elastomers are segmented cocoplymer with an [HS]n-type structure. Typically, these materials are two-phase systems, prepared from relatively polar and stiff component called the hard segment(H) and relatively flexible component known as the soft segment(S). Diisocyanate and chain extender together form the hard segment, which is dispersed within a matrix of the soft segment, composed of the macrodiolos.(omitted)

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Effect of Surfactants on the Electrochemical Performance of Cation-Selective Membrane Electrodes

  • Oh, Hyun-Joon;Cha, Geun-Sig;Nam, Hak-hyun
    • Bulletin of the Korean Chemical Society
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    • 제24권1호
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    • pp.37-44
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    • 2003
  • We examined the effect of polyether-type nonionic surfactants (Brij 35, Triton X-100, Tween 20 and Tween 80) on the potentiometric properties of sodium-, potassium- and calcium-selective membranes which are prepared with widely used ionophores and four kinds of polymer matrices [poly(vinyl chloride) (PVC), polyurethane (PU), PVC/PU blend, and silicone rubber (SR)]. It was found that the PVC-based membranes, which provide the best performance among all other matrix-based membranes in the absence of nonionic surfactants, exhibited larger change in their potentiometric properties when nonionic surfactants are added to the sample solution. On the other hand, the sodium-selective SR-based membrane with calix[4]arene, potassium-selective PVC/PU- or SR-based membrane with valinomycin, and the calcium-selective SR-based membrane with ETH 1001 provide almost identical analytical performance in the presence and absence of Tween 20 or Tween 80 surfactants. The origin of nonionic surfactants effect was also investigated by interpreting the experimental results obtained with various matrices and ionophores. The results suggest that the nonionic surfactant extracted into the membrane phase unselectively form complexes with the primary and interfering ions, resulting in increased background potential and lower binding ability for the ionophore. Such effects should result in deteriorated detection limits, reduced response slopes and lower selectivity for the primary ions.

Removal of radioactive methyliodide from the gas stream with a composite sorbent based on polyurethane foam

  • Obruchikov, Alexander V.;Magomedbekov, Eldar P.;Merkushkin, Aleksei O.
    • Nuclear Engineering and Technology
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    • 제52권5호
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    • pp.1093-1097
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    • 2020
  • A composite iodine sorbent was obtained in the form of porous polymer matrix with activated carbon particles impregnated with triethylenediamine deposited on its surface. A comparative assessment of the radioactive methyliodide capturing efficiency by the composite sorbent and a sample of industrial charcoal sorbent was conducted. It was shown that under the selected testing conditions, the hydraulic resistance of the composite sorbent is lower, and the sorption capacity is higher than that of the industrial charcoal sorbent. A method for comparing the effectiveness of iodine sorbents, based on the calculation of the ratio of the sorption capacity index to the minimum capacity index, needed for the required purification degree was proposed.

유청단백질을 이용한 미세캡슐의 응용 (Water-insoluble, Whey Protein-based Microcapsules for Controlled Core Release Application)

  • 이성제
    • 한국유가공학회:학술대회논문집
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    • 한국유가공기술과학회 2005년도 창립 30주년 기념 국제심포지움 - 웰빙시대의 우유.유제품의 새로운 발견
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    • pp.37-61
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    • 2005
  • 미세캡슐 (microencapsulation)은 내부 물질(core material)의 방출을 제어하기 위하여 여러 천연 및 생분해성 물질이 사용된다. 유청단백질은 이러한 목적에 아주 적합한 것으로 여겨지고 있는데 이는 독특한 이화학적 특성에 기인되는 것이다. 본 연구팀은 drug이나 생리활성물질을 피복하기 위하여 cross-linking 물질로 glutaraldehyde를 사용하여 수용성 이면서 유청단백질을 근간으로 하는 미세캡슐 제조기술을 개발하였다. 또한 생리적 조건에서 이들 캡슐의 분해 및 포집물질의 방출에 대한 연구를 수행하였는데 수용성 drug으로 사용된 theophylline은 유청단백질에 잘 분산되는 것으로 확인되었다. 이 분산액은 !%의 생리활성물질인 polyurethane을 함유하는 dichloromethane과 hexane 혼합불에 잘 확산이 되었다. 미세캡슐공정에서 피복물질로 사용되는 여러 물질중에서 유청단백질은 생리적 효능이 뛰어나고 여러 물리적 작용이 있기 때문에 새로운 피복소재로써 그 효용성이 매우 높다. 지금까지의 연구결과 유청단백질을 이용한 미세캡슐의 제조는 유청단백질이 가지는 기능적 효과와 내부물질이 지니는 약리효과를 동시에 이용할 수 있다는 점에서 향후 고부가 식품 의약품 첨가물질로써 유용성이 기대된다고 하겠다.

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생분해성 다공질 Calcium Metaphosphate 블록의 조직적합성에 관한 연구 (Biocompatibility and Bone Conductivity of Porous Calcium Metaphosphate Blocks)

  • 이용무;김석영;신승윤;구영;류인철;정종평
    • Journal of Periodontal and Implant Science
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    • 제28권4호
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    • pp.559-568
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    • 1998
  • direct bone apposition during bone remodelling. To address these problem, we developed a new ceramic, calcium metaphosphate(CMP), and report herein the biologic response to CMP in subcutaneous tissue, muscle and bone. Porous CMP blocks were prepared by condensation of anhydrous $Ca(H_2PO_4)_2$ to form non-crystalline $Ca(PO_3)_2$. Macroporous scaffolds were made using a polyurethane sponge method. CMP block possesses a macroporous structure with approximate pore size range of 0.3-1mm. CMP blocks were implanted in 8mm sized calvarial defect, subcutaneous tissue and muscle of 6 Newzealand White rabbits and histologic observation were performed at 4 and 6 weeks later. CMP blocks in subcutaneous tissue and muscle were well adapted without any adverse tissue reaction and resorbed slowly and spontaneously. Histologic observation of calvarial defect at 4 and 6 weeks revealed that CMP matrix were mingled with and directly apposed to new bone without any intervention of fibrous connective tissue. CMP blocks didn't show any adverse tissue reaction and resorbed spontaneously also in calvarial defect. This result revealed that CMP had a high affinity for bone and was very biocompatible. From this preliminary result, it was suggested that CMP was a promising ceramic as a bone substitute and tissue engineering scaffold for bone formation.

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Water-insoluble, Whey Protein-based Microcapsules for Controlled Core Release Application

  • Lee, Sung-Je
    • Journal of Dairy Science and Biotechnology
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    • 제23권2호
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    • pp.115-123
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    • 2005
  • Microcapsules consisting of natural, biodegradable polymers for controlled and/or sustained core release applications are needed. Physicochemical properties of whey proteins suggest that they may be suitable wall materials in developing such microcapsules. The objectives of the research were to develop water-insoluble, whey protein-based microcapsules containing a model water-soluble drug using a chemical cross-linking agent, glutaraldehyde, and to investigate core release from these capsules at simulated physiological conditions. A model water soluble drug, theophylline, was suspended in whey protein isolate (WPI) solution. The suspension was dispersed in a mixture of dichloromethane and hexane containing 1% biomedical polyurethane. Protein matrices were cross-linked with 7.5-30 ml of glutaraldehyde-saturated toluene (GAST) for 1-3 hr. Microcapsules were harvested, washed, dried and analyzed for core retention, microstructure, and core release in enzyme-free simulated gastric fluid (SGF) and simulated intestinal fluid(SIF) at $37^{\circ}C$. A method consisting of double emulsification and heat gelation was also developed to prepare water-insoluble, whey protein-based microcapsules containing anhydrous milkfat (AMF) as a model apolar core. AMF was emulsified into WPI solution (15${\sim}$30%, pH 4.5-7.2) at a proportion of 25${\sim}$50%(w/w, on dry basis). The oil-in-water emulsion was then added and dispersed into corn oil ($50^{\circ}C$) to form an O/W/O double emulsion and then heated at $85^{\circ}C$ for 20 min for gelation of whey protein wall matrix. Effects of emulsion composition and pH on core retention, microstructure, and water-solubility of microcapsules were determined. Overall results suggest that whey proteins can be used in developing microcapsules for controlled and sustained core release applications.

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MEK 제거를 위한 바이오필터용 담체의 선택 (Selection of Biofilter Support for Removing MEK)

  • 정귀택;이광연;이경민;선우창신;이우태;정승호;차진명;장영선;박돈희
    • KSBB Journal
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    • 제21권1호
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    • pp.34-41
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    • 2006
  • 본 악취제거용 바이오필터에 필요한 담체에 대하여 실험한 결과 다음과 같은 결론을 얻었다. 합성악취가스의 조성이 MEK 250 ppm을 바이오필터에 통과시켰을 때, 폴리프로필렌 섬유상은 $586.6g-MEK/m^3\;hr$로 실험담체 중에서 최고 제거량을 나타내었다. 폴리우레탄 담체는 $359.7g-MEK/m^3\;hr$을 제거용량을 나타내었다. 화산석 담체의 제거량은 $56.2g-MEK/m^3\;hr$으로 평가되었다. 본 연구에서 사용한 담체 중에서 MEK 제거에 사용될 수 있는 최적의 담체로는 폴리플로필렌 섬유상 담체로 평가되었다.

식도암 치료용 $^{166}Ho$-Stent 개발 (Development of $^{166}Ho$-Stent for the Treatment of Esophageal Cancer)

  • 박경배;김영미;김경화;신병철;박응우;한광희;정영주;최상무;이종두
    • 대한핵의학회지
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    • 제34권1호
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    • pp.62-73
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    • 2000
  • 목적: 식도암은 종양자체 혹은 주위조직의 침범으로 인한 식도 내강의 협착으로 음식물 섭취가 곤란하고 이에 따른 영양결핍, 면역력 약화등으로 생존율이 매우 낮은 것으로 보고되고 있다. 본 연구에서는 좁아진 식도 내강을 넓혀줄 뿐만 아니라 종양에 방사선 치료도 병행할 수 있는 새로운 형태의 식도암 치료용 방사성 stent를 개발하고자 한다. 대상 및 방법: ${\ulcorner}$하나로${\lrcorner}$ 연구로를 이용하여 금속 stent 외부를 $^{166}Ho$ 동위원소가 함유된 원통형의 방사성슬리브로 덮어 씌운 방사성 stent 어셈블리($^{166}Ho$-SA)를 전 방사능화법과 후 방사능화법에 의하여 제조하였다. 결과: 폴리우레탄 :매트릭스 내에 함유되어 있는 $^{165}Ho(NO_3)_3$$^{166}Ho(NO_3)_3$의 분포도를 전자현미경 사진과 자가방사기록법으로 확인한 결과 이들 화합물이 균일하게 분포되어 있음을 알 수 있었다. 식도의 구조적 특성을 고려한 전산용 기하학적인 모델을 개발하여 식도벽에 전달되는 흡수선량을 평가하였다. 본 연구에서 개발된 방사성 stent를 황견을 대상으로 식도부위에 삽입한 결과 육안적으로 점막층의 함몰이 일어나 식도내강이 넓어짐을 확인할 수 있었다. 결론: 금속 stent 외부에 $^{166}Ho$ 동위원소가 함유된 얇은 원통형 sleeve를 덮어씌워 균일한 방사선을 방출할 수 있는 방사성 stent를 개발하였으며, 이를 좁아진 식도부위에 삽입하면 물리적 압력에 의한 식도 내강의 확장과 함께 서서히 방사선 효과에 의해 종양괴사를 유도함으로 시간이 지남에 따라 종양 크기의 증대에 의한 이차적 폐쇄를 현저히 감소시킬 수 있을 것으로 기대된다.

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