• 제목/요약/키워드: Polypropylene(PP)

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나노 케냐프 셀룰로오스가 폴리프로필렌 복합소재의 물성 증가에 미치는 영향 (Nano-Kenaf Cellulose Effects on Improved Mechanical Properties of Polypropylene Composite)

  • 오정석;이성훈;범석훈;김광제
    • 폴리머
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    • 제37권5호
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    • pp.613-617
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    • 2013
  • 나노입자크기의 케냐프섬유를 폴리프로필렌에 첨가하였을 시, 복합소재의 물성변화를 관찰하였다. 천연크기의 케냐프섬유를 나노입자크기의 케냐프섬유로 대체하였을 시, 그 복합소재의 인장강도, 휨강도, 충격강도, 열변형온도가 증가한 반면에, 용융지수, 연신율(%), 충격강도 등이 감소하였다. 이는 나노입자크기의 케냐프섬유가 폴리프로필렌과 접촉하는 표면적의 증가와 섬유표면에 존재하는 휘발성 추출물질 등의 불순물의 감소에 따른 것으로 판단된다.

엔진커버용 폴리프로필렌/유리섬유/대나무섬유 복합체의 물리적 특성에 대한 대나무섬유의 용제 처리의 영향 (Effects of Solvent Treatment of Bamboo Fiber on Physical Properties of Polypropylene/Glass Fiber/Bamboo Fiber Composite)

  • 이수경;임성욱;신형식;우승건;박은영
    • 한국염색가공학회지
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    • 제31권1호
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    • pp.42-47
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    • 2019
  • In this study, the effects of surface treatment of bamboo fiber on the physical properties of polypropylene(PP)/glass fiber(GF)/Bamboo fiber(BF) composite for engine cover were investigated. PP, GF and BF were fixed at 40%, 40% and 20% and the surface of bamboo fibers were treated to 0.5, 1.0 and 2.0% as an acid and alkali solution. PP/GF/BR composites using surface treated bamboo fibers were prepared and their tensile strength, bursting strength and impact strength were measured by universal testing machine(UTM). The composites with alkali treated bamboo fiber showed better mechanical properties than the acid treated composites. It was checked that the optimum alkali content was at 1.0% from the results of mechanical properties. The effect of surface treatment on the mechanical properties was confirmed by SEM images of fractured surface.

유리섬유-폴리프로필렌 복합재료의 압축 공정 중 뒤틀림 예측에 관한 연구 (A Study on the Prediction of Warpage During the Compression Molding of Glass Fiber-polypropylene Composites)

  • 김규형;조동혁;이주원;김상덕;신철민;윤정환
    • 소성∙가공
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    • 제32권6호
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    • pp.367-375
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    • 2023
  • Composite materials, known for their excellent mechanical properties and lightweight characteristics, are applied in various engineering fields. Recently, efforts have been made to develop an automotive battery protection panel using a plain-woven composite composed of glass fiber and polypropylene to reduce the weight of automobiles. However, excessive warpage occurs during the GF/PP compression molding process, which makes car assembly challenging. This study aims to develop a model that predicts the warpage during the compression molding process. Obtaining out-of-plane properties such as elastic or shear modulus, essential for predicting warpages, is tricky. Existing mechanical methods also have limitations in calculating these properties for woven composite materials. To address this issue, finite element analysis is conducted using representative volume elements (RVE) for woven composite materials. A warpage prediction model is developed based on the estimated physical properties of GF/PP composite materials obtained through representative volume elements. This model is expected to be used for reducing warpages in the compression molding process.

개질 PP섬유의 제조 및 염색성 (The Preparation and Dyeing Properties of Modified Polypropylene)

  • 손태원;김삼수;이남순
    • 한국염색가공학회지
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    • 제13권6호
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    • pp.405-412
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    • 2001
  • In order to impart dyeability on to Polypropylene fiber, PP/EVA blend in the form of fibers and film were preparared using melt blending process. Ethylene vinylacetate containing 28wt% of vinylacetate(EVA(28)) was used as a copolymer. In the study of mechanical properties, tenacity and initial modulus decreased with Increasing EVA concentrations, whilst extension at break increased with increasing EVA contents. Their results in the dyeing behavior show that dye adsorption increased with increased EVA contents iota both blend fibers and films. The extent of dye uptake of red dye to modified polypropylene fibers was greater than that of Blue and Yellow counterparts due to the difference behavior of dye particles in dyeing bath.

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개질 PP섬유의 제조 및 염색성 (The Preparation and Dyeing Properties of Modified Polypropylene)

  • 손태원;김삼수;이남순
    • 한국염색가공학회지
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    • 제13권6호
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    • pp.47-47
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    • 2001
  • In order to impart dyeablility on to Polypropylene fiber, PP/EVA blend in the form of fibers and film were preparared using melt blending process. Ethylene vinylacetate containing 28wt% of vinylacetate(EVA(28)) was used as a copolymer. In the study of mechanical properties, tenacity and initial modulus decreased with increasing EVA concentrations, whilst extension at break increased with increasing EVA contents. Their results in the dyeing behavior show that dye adsorption increased with increased EVA contents for both blend fibers and films. The extent of dye uptake of red dye to modified polypropylene fibers was greater than that of Blue and Yellow counterparts due to the difference behavior of dye particles in dyeing bath.

금형온도가 Polystyrene 과 Polypropylene 성형품의 수축 및 외관품질에 미치는 영한에 관한 연구 (Effects of mold temperature on the shrinkage and surface quality of the Polystyrene and Polypropylene parts made by injection molding)

  • 이재원;김동학
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2002년도 춘계학술발표논문집
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    • pp.130-133
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    • 2002
  • 금형온도가 사출 성형품에 미치는 영향 중에 결정성수지인 PP(Polypropylene)와 비결정성수지인 PS(Polysyene)는 금형온도가 높아짐에 따라 각기 다른 결과를 나타내었다. PS성형품은 금형온도가 높을수록 수축율이 줄어들고 두께 편차가 적어지는 경향을 관찰할 수 있었고, PP성형품의 경우에는 결정의 생성으로 인한 상반된 경향이 관찰되었다. 또한, 금형온도에 따른 캐비티의 매끄러운 면과 거친 면의 결과로 볼 때 금형온도가 높을수록 캐비티의 충전성 및 전사성이 향상되었다. MmSH(Momentary Mold Surface Heating)조건인 경우는 수축율과 전사성 모두다 양호한 결과를 보여주었다.

Structure -Properties Relations of Polypropylene/ Liquid Crystalline Polymer Blends

  • Sahoo, N.G.;Das, C.K.;Jeong, Hye-Won;Ha, Chang-Sik
    • Macromolecular Research
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    • 제11권4호
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    • pp.224-230
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    • 2003
  • The blends of polypropylene (PP) with glass filled thermotropic liquid crystalline polymer (LCP-g) have been prepared by melt mixing techniques at different blend ratios. The thermal, dynamic mechanical, crystalline and morphological characteristics of these blends were investigated. Higher percent crystallinity was observed for 10% level of LCP-g in the blend in comparison to that of other blend ratios. The thermal stability increased with LCP-g concentration in the blend with PP. The variation of storage modulus, stiffness and loss modulus as a function of blend ratios suggested the phase inversion at the 50% level of LCP-g in the blend. The scanning electron microscopy (SEM) photographs showed the creation of voids and destruction of the fiber structures during the dynamic mechanical measurements. Processing behavior of the blends depended on the fiber forming characteristics of LCP-g, which again varied with the molding temperatures.

Thermal and Dynamic-Mechanical Characterization of Rice-Husk Filled Polypropylene Composites

  • Rosa, Simone M.L.;Nachtigall, Sonia M.B.;Ferreira, Carlos A.
    • Macromolecular Research
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    • 제17권1호
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    • pp.8-13
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    • 2009
  • Natural fiber-filled polymer composites have attracted great interest due to increasing environmental concerns and their low costs. In this study, the properties of rice husk flour-filled polypropylene (PP) were analysed in view of the large quantities of this agricultural product available as residue in Brazil. The rice husk flour (RHF) was characterized by SEM and particle size distribution. The properties of the composites were studied by MFI, DMA, DSC and TGA analyses. A commercial PP modified with maleic anhydride (MAPP) was used as coupling agent. It was verified that RHF decreased the MFI of the composites and that the coupling agent decreased it even more. The efficiency of MAPP was confirmed by the high storage modulus and high loss factor of the coupled composites.

순수 폴리올레핀(PP/UHMWPE) 소재용 초소수성 보라색 염료의 합성 (Synthesis of a Super Hydrophobic Violet Dye for Pure Polyolefin(PP/UHMWPE) Fibers)

  • 김태경;이창환
    • 한국염색가공학회지
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    • 제25권3호
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    • pp.165-171
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    • 2013
  • A new monoazo violet dye optimized for polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers was synthesized and its dyeability was investigated. Two hexyl groups were introduced to coupler, 2,5-dimethoxyaniline, in order to increase hydrophobicity of the dye. The maximum absorption wavelength was appeared at 580nm, which meant that the dye showed violet color. From the dyeing results at various conditions, the optimum dyeing was determined as $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing at least 4 for both fibers. Light fastness was acceptable for polypropylene fibers giving ratings 3~4. However, relatively poor light fastness was obtained in case of ultra high molecular weight polyethylene fibers showing ratings 2.

Thermal effects on the mechanical properties of cement mortars reinforced with aramid, glass, basalt and polypropylene fibers

  • Mazloom, Moosa;Mirzamohammadi, Sajjad
    • Advances in materials Research
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    • 제8권2호
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    • pp.137-154
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    • 2019
  • In this study, thermal effects on the mechanical properties of cement mortars with some types of fibers is investigated. The replaced fibers were made of polypropylene (PP), aramid, glass and basalt. In other words, the main goal of this paper is to study the effects of different fibers on the mechanical properties of cement mortars after subjecting to normal and sub-elevated temperatures. The experimental tests used for investigating these effects were compressive, splitting tensile, and four-point bending tests at 20, 100 and $300^{\circ}C$, respectively. Moreover, the microstructures of the specimens in different temperatures were investigated using scanning electron microscope (SEM). Based on the experimental results, the negative effects of sub-elevated temperatures on four-point bending tests were much more than the others. Moreover, using the fibers with higher melting points could not improve the qualities of the samples in sub-elevated temperatures.