• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.742-748
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• 1998

Experiments have been conducted to investigate synergistic effects and mechanisms of the Alaskan subbituminous coal/polypropylene (PP). Coliquefaction of coal/PP gave the synergistic effect in yields by 17% compared to independent liquefactions of coal or PP at $430^{\circ}C$. To analyse coliquefaction mechanisms, the second and zeroth order kinetic models were developed for coal and PP conversions respectively. When the models were simulated to fit coliquefaction results, those represented results successfully with the correlation coefficient of 0.99. The amount of tetralin needed to liquefy unit mass of coa 1(${\beta}$) was also calculated using the developed model. According to the calculated results, $\beta$ increased from 0.4 to 1.0 as the coliquefaction temperature increased from $410^{\circ}C$ to $470^{\circ}C$. This indicated that tetralin lowered the molecular weight of oil produced, and this phenomenon was recognized by the GPC analyses. Furthermore, it was found that tetralin prohibited the liquefaction of PP when coal was not added. On the other hand, tetralin was believed to act as a hydrogen-donor solvent to coal rather than prohibit PP liquefaction during coliquefaction. Therefore, the liquefaction rate of PP increases and synergistic effects in oil yields are mainly due to the increase in PP liquefaction during coal/PP coliquefaction.

• Korean journal of food and cookery science
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• v.12 no.4
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• pp.499-505
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• 1996

The facillities for Kimchi preservation were investigated in order to develop the taste, flavor and commercial quality of Kimchi during fermentation. Four kinds of facillities used for this experiment were PP(Polypropylene). PSC(Polypropylene+ceramic)and PPP was selected newly and laminated of three layers with PETG (Polyester G), PS (Polystyrene) and PETG. The change of total number of lactic acid Bacteria, pH, acidity, color, gas contents and free internal volume of package were measured for the Kimchi packaged by 4 facillities during 6 days fermentation at 15$^{\circ}C$. The total No. of lactic acid Bacteria within the Kimchi in the PPP facillity was more and remained longer time (120 hrs.) than other Kimchi in the PP, PS and PPC facillities. Also the pH of all Kimchi were decreased to pH 4 within 72 hrs. and the pH of Kimchi in the PPP facillity was kept as pH 4 for 120 hrs., so that was shown to be decreased more dully than others. In case of fimchi in the PPP facillity, the color was retained better, CO$_2$ contents was lower similar to PPC facillity, and swelling degree of free internal volume was higher than others. By the sensory evaluation, the Kimchi in the PPP facillity represented as better than others for color, flavor, texture and total preferences until 48 hrs. fermentation. And the PPP facillity is transparent, so these will be selected and confirmed more easily, also PPP facillity is so hard to endure the swelling pressure of internal gas. Therefore it is thought that the PPP facillity used as Kimchi package will be desirable for better taste, flavor, and commercial quality.

• Carbon letters
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• v.15 no.2
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• pp.117-124
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• 2014

Conductive polymer composites (CPCs) consist of a polymeric matrix and a conductive filler, for example, carbon black, carbon fibers, graphite or carbon nanotubes (CNTs). The critical amount of the electrically conductive filler necessary to build up a continuous conductive network, and accordingly, to make the material conductive; is referred to as the percolation threshold. From technical and economical viewpoints, it is desirable to decrease the conductive-filler percolation-threshold as much as possible. In this study, we investigated the effect of polymer/conductive-filler interactions, as well as the processing and morphological development of low-percolation-threshold (${\Phi}c$) conductive-polymer composites. The aim of the study was to produce conductive composites containing less multi-walled CNTs (MWCNTs) than required for pure polypropylene (PP) through two approaches: one using various mixing methods and the other using immiscible polymer blends. Variants of the conductive PP composite filled with MWCNT was prepared by dry mixing, melt mixing, mechanofusion, and compression molding. The percolation threshold (${\Phi}c$) of the MWCNT-PP composites was most successfully lowered using the mechanofusion process than with any other mixing method (2-5 wt%). The mechanofusion process was found to enhance formation of a percolation network structure, and to ensure a more uniform state of dispersion in the CPCs. The immiscible-polymer blends were prepared by melt mixing (internal mixer) poly(vinylidene fluoride) (PVDF, PP/PVDF, volume ratio 1:1) filled with MWCNT.

• Polymer(Korea)
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• v.24 no.6
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• pp.770-776
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• 2000

The effect of unreactive coupling agent on mechanical and thermal properties of talc-filled polypropylene (PP) composites was studied. Stearic and oleic acids were introduced as coupling agents, and tensile, flexural, and impact strength, thermal stability and melting transition temperature were measured and analyzed according to the types and concentration of coupling agents. Tensile and flexural strength were enhanced by introduction of coupling agent and the maximum effect was observed at the concentration of 3 wt% of coupling agent. Tensile and flexural strength of PP treated with oleic acid were higher than those of PP treated with stearic acid. but impact strength vice-versa. The reasons for these results were postulated by analyzing morphologies of talc-filled PP observed by SEM.

• Laser Solutions
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• v.9 no.3
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• pp.15-21
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• 2006

A Polypropylene (PP) film was ablated using a femtosecond laser with a center wavelength of 785 nm, a pulse width of 184 fs and a repetition rate of 1 kHz. Increments of both pulse energy and the shot number of pulses lead to co-occurrence of photochemical and thermal effect, demonstrated by the spatial expansion of rim on the surface of PP. The shapes of the laser-ablated PP films were imaged by a scanning electron microscope (SEM) and measured a 3D optical measurement system (NanoFocus). And, the oxygen transmission rate (ORT) of periodically laser-ablated PP film were characterized by oxygen permeability tester for modified atmosphere packaging (MAP) of fresh fruit and vegetable. Our results demonstrate that femtosecond pulsed laser is efficient tools for breathable packaging films in modifying the flow of air and gas into and out of a fresh produce container, where the micropatterns are specifically tailored in size, location and number which are easily controlled by laser pulse energy and pulse patterning system.

• Composites Research
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• v.27 no.5
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• pp.201-206
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• 2014

Utilizing waste materials in making useful products is a globally increasing trend. This can reduce the cost and environmental issues. In this study, oyster shell powder (OSP) is reinforced as a filler in polypropylene (PP) matrix to make a new composite. The purpose is to improve fire retardant properties of PP as a result of OSP reinforcement. Mechanical, fire retardant and water absorption properties of the new composite have been studied in this research. Concentration of OSP reinforcement in PP has been varied by wt% and its effect on the above mentioned properties has been observed. SEM (scanning electron microscopy) images of tensile and bending fractured surfaces have been taken to observe the failure mechanism during mechanical tests. An increase in the fire retardancy has been observed as a result of the OSP reinforcement while tensile strength decreased. Stiffness also increased with the addition of OSP in PP.

• Advances in concrete construction
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• v.16 no.1
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• pp.1-20
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• 2023

This study presents the experimental results performed to evaluate the effects of Polyvinyl-alcohol (PVA) and Polypropylene (PP) fibers on the fresh and residual mechanical properties of the hybrid fiber reinforced SCC before and after the exposure of 250℃, 500℃ and 750℃ temperatures. The compressive and splitting tensile strength, modulus of rupture (MOR), ultrasonic pulse velocity (UPV) as well as toughness and weight loss were investigated at different temperatures. PVA and PP fibers were added into SCC mixtures having only macro steel fiber and also having binary hybridization of both macro and micro steel fiber. The results showed that the use of micro steel fiber replaced by macro steel fiber improved the fresh and hardened properties compared to the use of only macro steel fiber. Moreover, it was emphasized that PVA or PP enhanced the residual flexural performance of SCC, generally, while it negatively influenced the workability, weight loss, UPV and the residual strengths with regards to the use of single steel fiber and binary steel fiber hybridization. Compared to the effect of synthetic fibers, PP had slightly more positive effect in the view of workability while PVA enhanced the residual mechanical properties more.

• Polymer(Korea)
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• v.26 no.1
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• pp.53-60
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• 2002

Polypropylene(PP : continuous phase)/poly (styrene-co-acrylonitrile)(SAN : dispersed phase) blends, and PP/poly(acrylonitrile-butadiene-styrene) (ABS : dispersed phase)blends, containing various amounts of compatibilizer(PP-SAN graft copolymer), were prepared at various shear rates by using twin-screw extruder. In the PP/SAN blend, the average size of the dispersed particles(SAN) was increased with SAN content, while the flexural strength and tensile strength were decreased with SAN content. When the screw rpm was increased from 10 to 60 rpm, the size of the dispersed phase was decreased while the flexural strength and the tensile strength were increased. Maximum mechanical strength and minimum droplet size were observed when the 5 phr compatibilizer was added to the PP/SAN blends. The mechanical strength of PP/ABS blends such as flexural strength and tensile strength increased by adding compatibilizer was reached maximum when blends contained 5 phr compatibilizer.

• Elastomers and Composites
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• v.44 no.2
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• pp.156-163
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• 2009

Our objective is to increase the flowability of Polypropylene(PP) compounds and achieve flow mark free surface in injection molded specimen. We have investigated flowabilities of PP compounds which were composed of PP, rubber, talc, and trace amount of additives. Flowability measurement was performed with four types PPs of which molecular weight distributions(MWD) and melt indexes(MI) were different. Rheological properties of the PP compounding materials, such as spiral flow(SF) length, MI, and shear viscosity, were evaluated. When PP with the broad MWD was used, there were remarkable cases where the spiral flow length of low MI PP compound was longer than that of higher MI PP compound. The PP compound having low MI but broad MWD PP has more flowability than the compound with only high MI.

• Elastomers and Composites
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• v.34 no.3
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• pp.212-221
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• 1999

Mechanical properties of polypropylene filled with recycled rubber dusts obtained from the buffing process in sport shoe sole manufacture were investigated. The use of these dusts eliminates the need for the size reduction process which is usually employed in rubber recycling. Two different waxes, polypropylene wax and ethylene vinyl acetate wax, were used in the PP/rubber dust compound. Two different processes, extrusion and injection moulding, were used to study the influence of the blends on the properties. The waxes gave significant improvement in the shaping of the extrudate. It was found that the impact strength of the injection moulded samples were higher than the extruded samples and the virgin PP. The tensile properties (yield stress and modulus) were dependent on the amount of rubber dust addition. An increase in the rubber dust loading gave lower yield stress and modulus.