• 한국염색가공학회지
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• 제28권3호
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• pp.156-163
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• 2016

The 6 novel super hydrophobic bluish-green dyes, showing the maximum absorption at 600~650nm, were synthesized to dye polyolefin fibers such as polypropylene and high strength polyethylene fibers. Their absorption spectra appeared almost the same at visible range, which meant the length of alkyl substituents did not affect on color appearance of the dyes. The optimum length of alkyl group was determined as hexyl substituents from the practical point of view. From the dyeing results, the optimum dyeing condition was $130^{\circ}C$ for 1 hour. The good fastness ratings to washing, rubbing were obtained showing 4-5 for both fibers. Light fastness was obtained also good rating 4 for both fibers.

• Elastomers and Composites
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• 제25권3호
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• pp.203-210
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• 1990

The structure and properties of blends of ethylene-propylene-diene terpolymer(EPDM) and polyolefin blends have been investigated. The rheology and tensile properties of the EPDM/HDPE(high density polyethylene), EPDM/PP(polypropylene) binary and EPDM/PP/HDPE ternary blends were studied along with morphological analyses. Those properties were affected by preferential interaction of EPDM on HDPE, compared to that of EPDM on PP, for the binary blends. The preferetial interaction may stem from the molecular characteristics of EPDM to possess more ethylene units than propylene units in the elastomer. The EPDM played a role as compatibilizer for HDPE and PP in the EPDM/PP/HDPE ternary blends.

• Elastomers and Composites
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• 제50권2호
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• pp.119-125
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• 2015

Because of their low surface free energy and absence of polar groups at the surface, polyolefins are substrates whose wetting and adhesion are very difficult. Free radical grafting of monomers to backbone polymer is one of the most attractive ways for the chemical modification of polymers. Synthesis of graft copolymer through graft polymerizations of PE and/or PP with phthalic anhydride (PhAn) was made and FTIR spectra of the graft polymer were the examined. And also the effects of phthalic anhydride content on the grafting ratio, thermal properties and contact angle of the graft polymer were examined.

• Korean Membrane Journal
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• 제5권1호
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• pp.31-35
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• 2003

The permeation characteristics of the wastewater containing Si fine particles were examined by ultrafiltration using the polyolefin tubular membrane module. Flux with time was due to the growth of Si cake deposited on the membrane surface and the pore plugging by fine particles. The rate of flux decline in the initial stage increased with the trans-membrane pressure. The pore blocking resistance was the dominant resistance at the initial period of filtration and the cake resistance began to dominate with the initial pore blocking resistance. The larger pores compared with the fine particles, the more the membrane pores could be blocked by the fine particles. Before and after treatment, the distribution of particle size was shifted toward to the left. Then, the average size of fine particles in the permeate was 20 nm.

• Elastomers and Composites
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• 제55권1호
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• pp.1-5
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• 2020

This study examined the effects of the addition of maleic anhydride-grafted polypropylene (PP-g-MA) and polyolefin elastomer (POE) on polyamide 66 (PA66) and polypropylene (PP) blends. The blends of PA66/PP with PP-g-MA and POE were prepared using a twin screw extruder. Mechanical testing results revealed that the tensile, flexural, and izod impact strengths of the blends were maximized at a PP-g-MA content of 2 phr. The increased mechanical strength of the blends with PP-g-MA was attributed to the compatibilizing effect of the PA66 and PP blends. In addition, as the POE content increased, the impact strength of the blends increased. However, at a high POE content, the tensile and flexural strengths decreased, seemingly because of the lower mechanical properties of POE.

• 한국염색가공학회지
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• 제25권3호
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• pp.165-171
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• 2013

A new monoazo violet dye optimized for polyolefin fibers such as polypropylene and ultra high molecular weight polyethylene fibers was synthesized and its dyeability was investigated. Two hexyl groups were introduced to coupler, 2,5-dimethoxyaniline, in order to increase hydrophobicity of the dye. The maximum absorption wavelength was appeared at 580nm, which meant that the dye showed violet color. From the dyeing results at various conditions, the optimum dyeing was determined as $130^{\circ}C$ for 1 hour with 5% owf of dyes. The good fastness ratings to washing, rubbing were obtained showing at least 4 for both fibers. Light fastness was acceptable for polypropylene fibers giving ratings 3~4. However, relatively poor light fastness was obtained in case of ultra high molecular weight polyethylene fibers showing ratings 2.

• 한국산업융합학회 논문집
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• 제27권3호
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• pp.619-627
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• 2024

By analyzing the structure of the currently used Lead Tab tape structure, the outermost layer, low-temperature fusion functionalized olefin, was composed of pp base. To determine whether this could be used as the outermost layer of tab tape, the adhesive strength to metal foils such as copper and aluminum was measured and the adhesive strength was compared with commercially available functionalized olefin. When chlorine was grafted onto PP among the PP used in the composition, the average adhesive strength was similar to that of commercially available LT200T and superior to RE140R and LE320V. The maximum adhesive strength exceeded that of LE200T. When it comes to solvents, xylene has been shown to be better than any other. Physical methods such as substitution of other monomers, switching of additives or let-down hardly changed the adhesion of grafted PP, and the selection of PP is an important factor in preparing functional polymers.

• 한국고분자학회지:고분자과학과기술
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• 제4권1호
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• pp.35-44
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• 1993

• 식품기술
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• 제25권3호
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• pp.230-256
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• 2012

• 공업화학
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• 제3권3호
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• pp.361-370
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• 1992