• Title/Summary/Keyword: Polyol

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Polyol Synthesis of Ruthenium Selenide Catalysts for Oxygen Reduction Reaction

  • Lee, Ki-Rak;Woo, Seong-Ihl
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3145-3150
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    • 2010
  • Ruthenium catalysts modified by selenium have been introduced as alternative materials to Pt in Direct methanol fuel cells (DMFCs). RuSe nano-particles were synthesized on the Vulcan XC72R carbon supports via polyol method. The prepared catalysts were electrochemically and physically characterized by cyclic voltammetry (CV,) linear sweep voltammetry, methanol tolerance test, X-ray diffraction (XRD), Transmission electron microscopy (TEM), Energydispersive Spectrometer (EDS) and X-ray photoelectron spectroscopy (XPS). Increasing the Se concentration up to 20 at % increased the electro-catalytic activity for the oxygen reduction. By increasing Se amount, Ru metallic form on the surface was increased. The $Ru_{80}Se_{20}$/C catalysts showed the highest oxygen reduction reaction (ORR) activity and outstanding methanol tolerant property in half cell tests as well as single cell test.

Preparation of Temperature-sensitive Polyurethane Membrane and Its Permeation Characteristics (온도감응성 Polyurethane 막의 제조 및 투과특성)

  • 김진홍;이영무
    • Membrane Journal
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    • v.6 no.4
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    • pp.236-241
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    • 1996
  • We prepared temperature-sensitive polyurethane and its water permeation characteristics for possible uses as drug delivery systems. Mechanical properties and Tg of polyurethane depend on the molecular weight of polyol and the amount of hard segment. We confirmed the increase of permeability with temperature. This fact indicates the future use of the present material in drug delivery systems.

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Synthesis of Multiferroic Nanocomposites by a Polyol Method

  • Shim, In-Bo;Pyun, Jeffrey;Park, Yong-Wook;Uhm, Young-Rang;Kim, Chul-Sung
    • Journal of Powder Materials
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    • v.14 no.3 s.62
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    • pp.180-184
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    • 2007
  • The material design and synthesis are of important to modem science and technology. Here, we report the synthesis of multifunctional nanomaterials with different properties: feroelecties $YMnO_3$ and multiferroic materials such as $CoFe_2O_4-YMnO_3,\;Fe_3O_4-YMnO_3,\;CoFe_2O_4-Cd_{0.85}Zn_{0.15}S,\;and\;Fe_3O_4-Cd_{0.85}Zn_{0.15}S$ nano-composites by using a chemical synthesis process. These results provide a simple and convenient synthesis process to produce multifunctional nanocomposites.

Trends on Synthesis of Cu Nanoparticles by a Wet Reduction Method (습식 환원법에 의한 Cu 나노입자의 합성 동향)

  • Shin, Yong Moo;Chee, Sang-Soo;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.3
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    • pp.11-18
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    • 2013
  • Interest in copper nanoparticles has increased as an alternative for substituting silver nanoparticles because of its lower cost and less electromigration effect than silver. In this paper, the recent research trends and main results in wet-chemical synthesis of sub-100 nm Cu nanoparticles were summarized. The characteristics of synthesis were discussed with a classification such as modified polyol synthesis, modified hydrothermal synthesis, solvothermal synthesis, and the others, focussing on effects of capping agents, reductants, and pH. Information on the oxidation of synthesized copper nanoparticles were additionally commented.

Modified-Polyol Synthesis of Nanocrystalline $LaPO_4:Ce^{3+}$, $Tb^{3+}$ Phosphors for Transparent Display

  • Song, Woo-Seuk;Byun, Ho-June;Yang, Hee-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1290-1292
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    • 2009
  • Modified-polyol protocol was utilized for synthesis of green-emitting ($^5D_4-^7F_j$ transitions of $Tb^{3+}$ ion) nanocrystalline $LaPO_4:Ce^{3+}$, $Tb^{3+}$ phosphors. Experimental parameters including chemical composition and annealing temperature were optimized to produce highly efficient, uniformly sized nanophosphors. Spin-deposited layer of $LaPO_4:Ce^{3+}$, $Tb^{3+}$ nanophosphors on glass substrate exhibited a transmittance of more than 80 %, indicating their efficacy for transparent display.

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Effect of NCO Index on the Particle Size of Polycarbonate Diol-based Polyurethane Dispersion

  • Kim, Dong-Eun;Kang, Seung-Oh;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.20-25
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    • 2020
  • The effect of the isocyanate index (NCO index) on the particle size and particle size distribution of a waterborne polyurethane dispersion (WPUD) with polycarbonate-diol was determined. The WPUDs were prepared using a conventional acetone process with polycarbonate-polyol (Mn = 2028), 4,4'-methylenebis(cyclohexyl isocyanate) (H12MDI), 2,2-bis(hydroxymethyl) propionic acid (DMPA), and dibutyltin dilaurate catalyst. At NCO index values below 1.5, the number average particle diameter of the WPUDs significantly increased with the NCO index, whereas the particle diameter slightly varied at higher NCO indexes. The dependency of the WPUD viscosity on the NCO index exhibited similar behavior to that of the particle size. The relative values of the full width at half maximum of the WPUD particle distribution curves at various NCO indexes were not influenced by the NCO index.

Localization of phenoloxidases in coprinus congregatus grown on a low-temperature-liquifying medium (저온 액화성 응고제를 사용한 고체배지에서 자란 coprinus congregatus의 phenoloxidase들의 localization)

  • ;Ross, Ian K.
    • Korean Journal of Microbiology
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    • v.28 no.3
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    • pp.274-277
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    • 1990
  • The hyphal tip phenoloxidases of Coprinus congregatus were localized by the protoplast-concanavalin A method. Protoplast were generated from cultures grown on a solid medium which was solidified with a new gelling agent, Pluronid Polyol F127, instead of agar. the enzymes were associated with the cell membrane which might work as a transducer in the light recepter complex.

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