• Title/Summary/Keyword: Polymethyl Methacrylate(PMMA)

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Investigation of Thermal Fusion Bonding and Separation of PMMA Substrates by using Molecular Dynamics Simulations (분자동역학을 이용한 PMMA 평판의 열접합 및 분리에 대한 연구)

  • Yi, Taeil
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.5
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    • pp.111-116
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    • 2018
  • Thermal fusion bonding is a method to enclose open microchannels fabricated on polymer chips for use in lab-on-a-chip (LOC) devices. Polymethyl methacrylate (PMMA) is utilized in various biomedical-microelectromechanical systems (bio-MEMS) applications, such as medical diagnostic kits, biosensors, and drug delivery systems. These applications utilize PMMAs biochemical compatibility, optical transparency, and mold characteristics. In this paper, we elucidate both the conformational entanglement of PMMA molecules at the contact interfacial regime, and the qualitative nature of the thermal fusion bonding phenomena through systematic molecular dynamics simulations.

Surface Modification of Polymethyl methacrylate(PMMA) by Laser Surface Treatment for Microfluidic Chip (유체소자 성능향상을 위한 Polymethyl methacrylate(PMMA)의 레이저 표면처리)

  • Shin, Sung-Kwon;Lee, Sang-Don;Lee, Cheon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.2
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    • pp.334-337
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    • 2007
  • After the advent of micro-Total Analysis Systems(${\mu}-TAS$) based on silicon various polymer for microfluidic chip has been studied. Polymer materials for microfluidic compared with silicon and glass which were traditional materials of a microfluidic chip, have the advantages of economical efficiency simple manufacturing process and wide materials selectivity corresponding to fluids. Surface energy of polymers we, however lower than silicon or glass. To overcome this problem, various surface modification methods have been investigated. The surface modification using laser has the advantage of the simple experiment that only directly irradiated laser beam on the material surface in the air. This work discuss the surface modification of polymethly methacrylate(PMMA) by 4th harmonic Nd:YAG laser (${\lambda}266nm$, pulse) treatment. After the laser treatment, the PMMA surface was investigated using a contact angle measuring instrument. The contact angle was decreased with a increase of the surface oxygen content. This result means the surface energy of PMMA was increased by the laser treatment without changing of its bulk characteristics.

Evaluation of Image Quality for Scattered X-rays using in Digital Radiography (디지털방사선영상에서 산란선의 영상특성 평가)

  • Kim, Hansol;Kim, Changsoo
    • Journal of the Korean Society of Radiology
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    • v.16 no.4
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    • pp.395-403
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    • 2022
  • Flat-panel detector (FPD) used in digital radiographic imaging systems was used to perform a quantitative power spectrum evaluation as a result of the thickness change of polymethyl methacrylate (PMMA), a tissue equivalent. As the PMMA thickness increases with the resolution-chart phantom image, the effect of the scattering line increases, indicating that the modulation characteristics decrease, and the image is bright. The results show that the noise of the image increases, and noise-power spectral images are obtained by Fourier transform to confirm by spatial frequency. Thus, it can be verified that the PMMA thickness and noise are proportional through the result of evaluating the change of resolution characteristics and representing the 2D noise-power spectrum as one-dimensional values by evaluating the change of scattering line with MTF as the PMMA thickness increases in the image.

The Role of MMA and EGDMA in Enhancing the Mechanical Properties of PMMA Composites (PMMA 복합재의 기계적 특성 향상을 위한 MMA 및 EGDMA의 역할 연구)

  • Aqila Che Ab Rahman;Shiyoung Yang;Sooman lim
    • Journal of Integrative Natural Science
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    • v.17 no.2
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    • pp.53-58
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    • 2024
  • This study explores the enhancement of mechanical properties in Polymethyl Methacrylate (PMMA) composites through the incorporation of Methyl Methacrylate (MMA) and Ethylene Glycol Dimethacrylate (EGDMA). Utilizing Digital Light Processing (DLP) technology, we conducted a series of experiments to analyze the impact of varying concentrations of MMA and EGDMA on PMMA. The results indicate that while MMA demonstrates non-linear and variable mechanical strength across different PMMA concentrations, EGDMA consistently improves mechanical strength as PMMA concentration increases. This consistent enhancement by EGDMA suggests a stable and predictable reinforcement effect, which is critical for applications requiring high mechanical strength. Our comparative analysis highlights that EGDMA is a more effective additive than MMA for optimizing the mechanical performance of PMMA composites. Specifically, EGDMA's ability to provide uniform reinforcement across various PMMA concentrations makes it ideal for high-strength applications. These findings are significant for material scientists and engineers focused on the design and development of advanced PMMA-based materials. In conclusion, this research underscores the importance of selecting appropriate additives to enhance the mechanical properties of PMMA composites. The superior performance of EGDMA in reinforcing PMMA suggests its potential for broader applications in fields such as automotive, construction, medical devices, and 3D printing. This study provides valuable insights that can guide future research and development in high-performance composite materials, paving the way for innovative applications and improved material efficiency.

Experimental Study on the Effect of Flow around Solid Combustibles and Thermal Thickness on Heat Release Rate Characteristics (고체 가연물 주위의 유동과 열적 두께의 변화가 열방출률 특성에 미치는 영향에 관한 실험적 연구)

  • Hong, Ter-Ki;Seo, Dong-Pyo;Park, Seul-Hyun
    • Fire Science and Engineering
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    • v.34 no.3
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    • pp.28-34
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    • 2020
  • In this study, an ISO 5660-1 cone calorimeter experiment was conducted to examine the effects of changes in flow and thermal thickness around solid combustibles on heat release rate characteristics. Polymethyl methacrylate (PMMA) is a solid combustible material that does not generate char during the combustion reaction. Hence, it was selected for the experiment, and the thermal penetration depth was calculated to distinguish the thermal thickness of PMMA. Furthermore, the thermal decomposition characteristics were analyzed by measuring the heat release rate measured during the combustion of PMMA. This was performed after generating the forced flow around the combustibles by setting the duct flow of the cone calorimeter to 12, 24, and 40 L/s. The results confirmed that the thermal release rate of the thermally thin combustible material was not significantly affected by the change in the surrounding flow. Hence, the thermally thick combustible material was significantly affected by the change in the flow rate.

A Study on the Scatter X-ray Signal and Noise Characteristics of Indirect Conversion-Type Detector for Radiography (산란선이 간접변환방식 엑스선 검출기의 신호 및 노이즈 특성에 미치는 영향에 관한 연구)

  • Kim, Junwoo
    • Journal of the Korean Society of Radiology
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    • v.15 no.3
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    • pp.345-353
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    • 2021
  • Digital radiography imaging systems can also help diagnose lesions in patients, but if x-rays that enter the human body cause scatter x-ray due to interaction with substances, they affect the signal and noise characteristics of digital x-ray images. To regard the human body as polymethyl methacrylate (PMMA) and observe the properties of scattered x-ray generated from PMMA on x-ray images, we analyze signal and noise in the spatial domain as well as noise-power spectrum (NPS), and detective quantum efficiency (DQE) at zero frequency. As PMMA thickness increased, signals decreased, the noise increased, and NPS degradation was identified in overall spatial frequencies. Based on these characteristics, zero-frequency performance was also shown to be degraded. Comparative analysis with Monte-carlo simulations will need to be made to analyze the zero-frequency performance by scattered x-ray of indirect conversion-type x-ray detectors more quantitatively.

Successful Carapace Puncture Wound Repair with Polymethyl Methacrylate (PMMA) in an Amur Softshell Turtle (Pelodiscus maackii)

  • Ha, Minjong;Lee, Do Na;Ahmed, Sohail;Han, Janghee;Yeon, Seong-Chan
    • Journal of Veterinary Clinics
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    • v.39 no.4
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    • pp.185-191
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    • 2022
  • An Amur softshell turtle with multiple shell injuries was admitted to the Seoul Wildlife Center on 19 May 2021. The most severe lesion was a puncture wound requiring urgent closure. In addition to routine supportive therapy, the damaged shell was patched with biocompatible polymethyl methacrylate (PMMA) materials (bone cement and dental acrylic) and fiberglass. Despite a few methods to repair the carapace or plastron of hard-shelled turtles, shell repair in the Amur softshell turtle has rarely been reported. This paper reports the repair process of a puncture wound in the carapace of a softshell turtle using polymethyl methacrylate (PMMA). PMMA is a biocompatible acrylic polymer that forms a tight structure that holds the implant against tissue defects, such as skin, bones, and dentures. Fiberglass, a preferred fiber in various medical fields, was used with PMMA to provide extra strength and waterproof capability. After the procedure, there were no signs of edema, inflammation, bleeding, skin discoloration, or any other complications. Accordingly, this can be a method of choice in softshell turtles using biocompatible materials to cover the lesion in the carapace and provide appropriate wound management, supportive therapy, and a suitable course of antibiotics considering all other circumstances.

Evaluation of polymethyl methacrylate resin mechanical properties with incorporated halloysite nanotubes

  • Abdallah, Reham M.
    • The Journal of Advanced Prosthodontics
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    • v.8 no.3
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    • pp.167-171
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    • 2016
  • PURPOSE. This study inspects the effect of incorporating halloysite nanotubes (HNTs) into polymethyl methacrylate (PMMA) resin on its flexural strength, hardness, and Young's modulus. MATERIALS AND METHODS. Four groups of acrylic resin powder were prepared. One group without HNTs was used as a control group and the other three groups contained 0.3, 0.6 and 0.9 wt% HNTs. For each one, flexural strength, Young's modulus and hardness values were measured. One-way ANOVA and Tukey's test were used for comparison (P<.05). RESULTS. At lower concentration (0.3 wt%) of HNT, there was a significant increase of hardness values but no significant increase in both flexural strength and Young's modulus values of PMMA resin. In contrast, at higher concentration (0.6 and 0.9 wt%), there was a significant decrease in hardness values but no significant decrease in flexural strength and Young's modulus values compared to those of the control group. CONCLUSION. Addition of lower concentration of halloysite nanotubes to denture base materials could improve some of their mechanical properties. Improving the mechanical properties of acrylic resin base material could increase the patient satisfaction.

Characteristics of PMMA Sheet with Phosphorous Flame Retardant Additives (인계 첨가제를 이용한 PMMA판재의 난연성 물성 특성)

  • Kim, Yong-Ryeol;Lim, Sun-Young
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.224-230
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    • 2012
  • In this paper, flame-resisting PMMA(polymethyl methacrylate) sheet was manufactured and its characteristics were tested. PMMA was synthesized by bulk polymerization of a monomer methyl methacrylate with addition of phosphorous flame retardant, triethyl phosphate and ethylene glycol dimethacrylate as a cross linking agent. PMMA sheet was manufactured by using the cell molding method, which does not alter or affect the existing property of PMMA. Then the characteristics of PMMA sheet were tested for the TEP content, the content and curing time of EGDMA. As TEP content increases, the length of carbonization lessens and the amount of char production increases. As a result, it strengthened the effect of flame retardants. But the hardness of the sheet decreased as TEP content increased. However, hardness increased when EGDMA was added up to 3 wt% while curing time was decreased from 3 hours to 2 hours. There was no change of hardness when more than 3 wt% of EGDMA was used.

h Study on the Preparation of PMMA/PSt Composite Particles by Sequential Emulsion Polymerization (단계중합법에 의한 PMMA/PSt Composite Particle의 제조에 관한 연구)

  • 이선룡;설수덕
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.617-624
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    • 2001
  • The core-shell composite latexes were synthesized by stage emulsion polymerization of methyl methacrylate (MMA) and styrene (St) with ammonium persulfate after preparing monomer pre-emulsion in the presence of anionic surfactant. However, in preparation of core-shell composite latex, several unexpected results are observed, such as, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve the disadvantages, We study the effect of initiator concentrations, surfactant concentrations, and reaction temperature on the core-shell structure of polymethyl methacrylate/polystyrene and polystyrene/polymethyl methacrylate. Particle size and particle size distribution were measured using particle size analyzer, and the morphology of the core-shell composite latex was determined using transmission electron microscope. Glass temperature was also measured using differential scanning calorimeter. To identify the core-shell structure, pH of the two composite latex solutions were measured.

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