• Title/Summary/Keyword: Polymeric phthalocyanine

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Rubbing effect on orientation of Copper Phthalocyanine for flexible organic field-effect transistors

  • Kim, Hyun-Gi;Jang, Jung-Soo;Choi, Suk-Won;Ishikawa, Ken;Takezoe, Hideo;Kim, Sung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1319-1321
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    • 2009
  • Copper phthalocyanine (CuPc) Field-effect transistors (FETs) was successfully fabricated on plastic substrates. Orientation of CuPc crystallites on substrate could be obtained via rubbing process. It was revealed that CuPc crystallites were perpendicularly aligned on PES substrates with the rubbing direction. The performance of FETs was affected by orientation of CuPc on rubbed substrates.

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Syntheses and Thermal Properties of 5,10-Disubstituted-2,3,7,8-tetracyano-5,10-dihydrodipyrazino [2,3-b:2′,3′-el pyrazines and Polymeric Porphyrazines Derived from 2,3-Dichloro-5,6-dicyanopyrazine

  • Jaung, Jae-yun;Kim, Sung-Dong
    • Fibers and Polymers
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    • v.1 no.2
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    • pp.71-75
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    • 2000
  • Intermolecular cyclization of 2-alkylamino-3-chloro-5,6-dicyanopyrazine 2 in the presence of tributylamine in N,N-dimethylformamide (DMF) gave 5,10-disubstituted-2,3,7,8-tetracyano -5,10-dihydrodipyrazino〔2,3-b:2',3'-e]pyrazines 3, which showed strong mesomorphic property and were anticipated as new chromophoric system for functional dye materials. Absorption spectra, fluorescent properties and other physical properties were correlated with their chemical structures. Vanadyl oligomeric porphyrazine with long alkyl groups synthesized from 3 had satisfactory solubility in tetrahydrofuran (THF), diethyl ether and dimethylsulfoxide (DMSO). The syntheses and characterization of vanadyl polymeric porphyrazines derived from 3 with long alkyl groups are reported.

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4-Arm Star Shaped and Linear Block Copolymers for Copper Phthalocyanine Dispersion (4-Arm 스타형과 선형 블록 공중합체의 구리 프탈로시아닌 분산 연구)

  • Kim, Byoungjae;Jeong, Jonghwa;Jung, Ji-Hye;Kim, Bong-Soo;Jung, Ki-Suck;Paik, Hyun-Jong
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.671-675
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    • 2014
  • Well-defined star shaped and linear block copolymers were synthesized to study the dispersion stability of copper phthalocyanine (CuPc). We synthesized dispersants using (2-dimethylamino) ethyl methacrylate (DMAEMA) and poly(ethylene glycol) methyl ether methacrylate) (PEGMA) by activators generated by electron transfer (AGET) atom transfer radical polymerization (ATRP). pDMAEMA-b-pPEGMA copolymers were characterized by GPC and NMR. Furthermore, we studied the effect of the dispersion stability of copper phthalocyanine by controlling the degree of polymerization of PEGMA as a stabilizing group. The 4-arm star shaped polymeric dispersant showed better dispersion stability of CuPc at $25^{\circ}C$ for 7 days.

Synthesis of Well-Defined Block Copolymer Dispersants with (2-Dimethylamino)ethyl Methacrylate and Oligo(ethylene oxide)methyl Ether Methacrylate via ATRP for Dispersing Copper Phthalocyanine Pigment (Copper Phthalocyanine Pigment의 분산을 위한 (2-Dimethylamino)ethyl Methacrylate와 Oligo(ethylene oxide)methyl Ether Methacrylate를 포함하는 잘 규정된 블록 공중합체형 분산제의 원자 이동 라디칼 중합을 이용한 합성)

  • Kim, Eun-Hee;Kim, Bong-Soo;Jung, Ki-Suk;Kim, Jin-Goo;Paik, Hyun-Jong
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.104-110
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    • 2012
  • The dispersion of pigment particles is important because it is capable of increasing the color strength, contrast, and transmittance of color-LCD products. Pigment dispersion properties are very important factors for the quality of LCD color filters. The chemical structure of polymeric dispersants for pigment is important to improve dispersion stability and prevent aggregation or flocculation of pigment in organic or aqueous systems. Polymeric dispersants should contain both anchoring group that interacts with pigment surface and stabilizing group that provides steric stabilization. Moreover, the molecular weight and composition of block copolymer have the an effect on pigment dispersion. In this study, adequate dispersants, block copolymers containing (2-dimethylamino)ethyl methacrylate as anchoring group and oligo(ethylene oxide)methyl ether methacrylate as a stabilizing group were designed and synthesized by atom transfer radical polymerization in order to prepare well-defined structure, molecular weight and composition.