• 제목/요약/키워드: Polymeric effect

검색결과 399건 처리시간 0.029초

Evaluation of thermal stability of quasi-isotropic composite/polymeric cylindrical structures under extreme climatic conditions

  • Gadalla, Mohamed;El Kadi, Hany
    • Structural Engineering and Mechanics
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    • 제32권3호
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    • pp.429-445
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    • 2009
  • Thermal stability of quasi-isotropic composite and polymeric structures is considered one of the most important criteria in predicting life span of building structures. The outdoor applications of these structures have raised some legitimate concerns about their durability including moisture resistance and thermal stability. Exposure of such quasi-isotropic composite/polymeric structures to various and severe climatic conditions such as heat flux and frigid climate would change the material behavior and thermal viability and may lead to the degradation of material properties and building durability. This paper presents an analytical model for the generalized problem. This model accommodates the non-linearity and the non-homogeneity of the internal heat generated within the structure and the changes, modification to the material constants, and the structural size. The paper also investigates the effect of the incorporation of the temperature and/or material constant sensitive internal heat generation with four encountered climatic conditions on thermal stability of infinite cylindrical quasi-isotropic composite/polymeric structures. This can eventually result in the failure of such structures. Detailed critical analyses for four case studies which consider the population of the internal heat generation, cylindrical size, material constants, and four different climatic conditions are carried out. For each case of the proposed boundary conditions, the critical thermal stability parameter is determined. The results of this paper indicate that the thermal stability parameter is critically dependent on the cylinder size, material constants/selection, the convective heat transfer coefficient, subjected heat flux and other constants accrued from the structure environment.

닥나무 뿌리 추출물을 함유하는 고분자 마이크로입자 제조 및 평가 (Preparation and Evaluation of Polymer Microspheres Containing Broussonetia Kazinoki Root Extract)

  • 임형준;이진영;김한별;김도훈;신송석
    • 대한화장품학회지
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    • 제39권2호
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    • pp.89-96
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    • 2013
  • 본 연구에서는 폴리에틸렌아디페이트와 폴리메틸메타크릴레이트로 구성된 고분자 마이크로입자에 닥나무 뿌리 추출물을 함유시켜 닥나무 뿌리 추출물의 안정도와 상용성을 성공적으로 향상시켰다. 마이크로입자를 구성하는 고분자의 비율에 따라 마이크로입자에 함유된 닥나무 뿌리 추출물의 장기안정도에 미치는 영향을 평가하였다. 폴리에틸렌아디페이트 마이크로입자의 물리적 강도를 높여주기 위하여 폴리메틸메타크릴레이트를 도입하였으며, 이는 마이크로입자에 안정화시킨 닥나무 뿌리 추출물의 안정도에는 큰 영향이 없었다. 광학현미경, 편광현미경, 주사전자현미경을 이용하여 고분자 마이크로입자의 물리적 안정도를 관찰하였고, in vitro 실험을 통하여 고분자 마이크로입자로 안정화된 닥나무 뿌리 추출물의 미백 효과도 잘 유지되고 있음을 확인하였다.

흡습효과가 섬유강화 고분자 복합재료의 압축 ${\cdot}$ 굽힘 잔류강도에 미치는 영향 (Effect of Moisture Absorption on the Compressive and the Bending Residual Strength in Fiber-Reinforced Polymeric Composites)

  • 김혁;한길영;이동기;김이곤;김기성
    • 한국해양공학회지
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    • 제9권2호
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    • pp.133-140
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    • 1995
  • This paper deals with the residual strength characteristics of composite materials under the environment of high temperature and humidity. Two types of GFRP, one with unidirection and randomly oriented, are used to investigate the features of moisture absorption and the residual strength. The results show that, when exposed longterms in high temperature and humidity, the randomly oriented composites is more stable than the unidirection one.

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단섬유강화 고분자 복합재료의 압축성형에 있어서 섬유배향에 관한 연구 (The Planar Orientation of Fibers During Compression Molding of Short-Fiber Reinforced Polymeric Composites)

  • 김혁;전상기;이동기;한길영;김이곤
    • 한국해양공학회지
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    • 제10권3호
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    • pp.34-43
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    • 1996
  • In this study basic equations of fiber orientations is cimpared with experimental results. It is found that fiber orientations of short fiber reinforced polymeric composite under compression molding are governed by slope of flow speed in x-y direction. Fiber orientation angle of mold is also found to increase with closure speed and the compression ratio. At the middle of the mold, the slope of flow speed is larger in x-direction than in y-direction. At the wall of the mold, the shope of flow speed in y-direction occurs due to the effect of friction, hence affects the fiber orientation. The effect of partial flow, which incurs y-direction orientation causes to increase the fiber orientation angle at the fore part of the flow.

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오손액의 표면장력이 폴리머 복합재의 트래킹 열화에 미치는 영향 (The Effect of the Surface Tension of Contaminants on Tracking Ageing of Polymeric Composites)

  • 조한구;천종욱;이운용;한동희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
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    • pp.435-438
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    • 2002
  • In this paper, the effect of surface tension, wettability, flow rate of contaminants with varying surfactant content and frequency of applied voltage on the tracking breakdown of epoxy insulating materials were investigated. As the flow rate of contaminant is increased, the surface resistivity is decreased, and the leakage current is increased, the time to tracking breakdown is decreased. It is found that time to tracking breakdown depends on the surface tension of contaminant, that is difference of wettability And as the frequency of applied voltage is increased, time to tracking breakdown decreased.

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항에이즈 약물의 경피흡수에 미치는 합성고분자 멤브레인의 영향 (The Effect of Synthetic Polymer Membranes on the Skin Permeation of Anti-AIDS Drugs)

  • 이경진;김대덕
    • Journal of Pharmaceutical Investigation
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    • 제28권1호
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    • pp.1-5
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    • 1998
  • The effect of synthetic polymer membranes on the permeation rate of dideoxynucleoside-type anti-HIV drugs through hairless rat skin was studied using ethylene/vinyl acetate copolymer (EVA) and ethylene/methyl acrylate copolymer (EMA) membranes fabricated by solvent casting method. In vitro skin permeation kinetics study of DDC (2',3'-dideoxythymidine), DDI (2',3'-dideoxyinosine) and AZT (3'-azido-3'-deoxythymidine) across the (membrane/skin) composite was conducted for 24 hours at $37^{\circ}C$ using the Valia-Chien skin permeation system. The results showed that skin permeation rate of each drug across the (skin/membrane) composite was mainly dependent on the property of the membrane. Proper selection of the polymeric membrane which resembles hydrophilicity/lipophilicity of the delivering drug was important in controlling the skin permeation rate.

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Simultaneous Transfer and Patterning of CVD-Grown Graphene with No Polymeric Residues by Using a Metal Etch Mask

  • 장미;정진혁;;이내응
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.642-642
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    • 2013
  • Graphene, two dimensional single layer of carbon atoms, has tremendous attention due to its superior property such as high electron mobility, high thermal conductivity and optical transparency. Especially, chemical vapor deposition (CVD) grown graphene has been used as a promising material for high quality and large-scale graphene film. Unfortunately, although CVD-grown graphene has strong advantages, application of the CVD-grown graphene is limited due to ineffective transfer process that delivers the graphene onto a desired substrate by using polymer support layer such as PMMA(polymethyl methacrylate). The transferred CVD-grown graphene has serious drawback due to remaining polymeric residues generated during transfer process, which induces the poor physical and electrical characteristics by a p-doping effect and impurity scattering. To solve such issue incurred during polymer transfer process of CVD-grown graphene, various approaches including thermal annealing, chemical cleaning, mechanical cleaning have been tried but were not successful in getting rid of polymeric residues. On the other hand, lithographical patterning of graphene is an essential step in any form of microelectronic processing and most of conventional lithographic techniques employ photoresist for the definition of graphene patterns on substrates. But, application of photoresist is undesirable because of the presence of residual polymers that contaminate the graphene surface consistent with the effects generated during transfer process. Therefore, in order to fully utilize the excellent properties of CVD-grown graphene, new approach of transfer and patterning techniques which can avoid polymeric residue problem needs to be developed. In this work, we carried out transfer and patterning process simultaneously with no polymeric residue by using a metal etch mask. The patterned thin gold layer was deposited on CVD-grown graphene instead of photoresists in order to make much cleaner and smoother surface and then transferred onto a desired substrate with PMMA, which does not directly contact with graphene surface. We compare the surface properties and patterning morphology of graphene by scanning electron microscopy (SEM), atomic force microscopy(AFM) and Raman spectroscopy. Comparison with the effect of residual polymer and metal on performance of graphene FET will be discussed.

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Si-O Bridged 실리카가 충진된 치아수복용 고분자 복합체의 중합 특성 (Polymerization Behavior of Polymeric Dental Restorative Composites Filled with Si-O Bridged Silica)

  • 김오영;이정수
    • 공업화학
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    • 제16권5호
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    • pp.672-676
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    • 2005
  • 치아수복용 고분자 복합체(polymeric dental restorative composite, PDRC)의 전치부와 구치부에의 응용 가능성을 높이고자 PDRC를 구성하는 실리카 충진재를 다양한 온도에서 열처리시켜 siloxane 기로 연결된 구조의 개질된 실리카를 제조하고 이를 PDRC 제조에 사용하였다. 제조된 PDRC의 중합 특성을 중합전환률, 중합깊이, 그리고 체적 중합수축률 등을 분석하여 고찰하였다. 실험 결과, 사용된 실리카의 열처리 온도가 높아짐에 따라 제조된 PDRC의 중합깊이는 감소하였고 체적 중합수축률과 중합전환률 값은 실리카 입자의 평균크기 감소에 따른 PDRC 내 resin matrix의 상대적 양의 증가로 인해 일정하게 증가함을 알 수 있었다.

Gd$_2O_3$:Eu phosphor particles with spherical and filled morphology

  • Roh, Hyun-Sook;Kang, Yun-Chan;Park, Hee-Dong;Park, Seung-Bin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.253-256
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    • 2002
  • $Gd_2O_3$:Eu phosphor particles were prepared by largescale ultrasonic spray pyrolysis process. The morphological control of $Gd_2O_3$:Eu particles in spray pyrolysis was performed by adding polymeric precursors into spray solution containing nitrate salts. The effect of composition and amount of polymeric precursors on the morphology, crystallinity, and photoluminescence characteristics of $Gd_2O_3$:Eu particles was investigated. The influence of chain length of PEG on the morphology and photoluminescence intensity was investigated. $Gd_2O_3$:Eu particles prepared from aqueous solution containing no polymeric precursors had a hollow structure and rough surfaces after annealing process. The phosphor particles prepared from solution containing 0.1M CA and 0.lM PEG with high molecular weight as 1,500 had a spherical and filled morphology and the highest photoluminescence intensity, which was 48% higher than that of the $Y_2O_3$:Eu commercial product.

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