• Title/Summary/Keyword: Polymer-resin

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Investigation of Compressive Strength and Foaming Characteristics of Acid Anhydride Epoxy Foam by Foaming Agent (발포제에 따른 산무수물계 에폭시 폼의 압축강도 및 포밍특성 분석)

  • Kwon, Dong-Jun;Kim, Jong-Hyun;Park, Sung-Min;Kwon, Il-Jun;Park, Joung-Man
    • Composites Research
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    • v.31 no.4
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    • pp.133-138
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    • 2018
  • Polymer foams were used to fill the void in the structure in addition to flame retardant and heat insulation. Polymer foams such as polyurethane, polyisocyanurate, poly(vinyl chloride), polyethylene terephthalate were used to weight lighting materials. In this study, epoxy foam was used to improve mechanical properties of polymer foam. Acid anhydride type hardener reacts with polyol. Using this phenomenon, if blowing agent was added into epoxy resin using acid anhydride type hardener, formation and compressive properties of epoxy foam was studied. Formation of polymer foam was compared with type of blowing agent and concentration of blowing agent via compressive test. As these results, optimized condition of epoxy foam was found and epoxy foam had better compressive property than other polymer foam.

Development of Polymer Mortar Defensive Block for Erosion Control Works (폴리머 모르터를 이용한 사면보호재의 개발)

  • 유능환;연규석;김기성;지경용
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1998.10a
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    • pp.107-112
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    • 1998
  • The objective of this study was to develop a polymer mortar defensive block with high strength and durability using unsaturated polyester resin to complement defects of conventional cement mortar defensive block. Physical and mechanical properties of the polymer mortar defensive block were also investigated. Low absorptivity, high impact strength, and great bending strength of the polymer mortar defensive block was compared with those of the conventional cement defensive block. In conclusion, the polymer mortar defensive block is excellent and useful as industrial products for erosion control works.

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Development of Polymer Mortar Guide Block for the Blind Handicapped People (폴리머 복합재료를 이용한 유도 블럭의 개발)

  • 이기원;연규석;이윤수;지경용
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1999.10c
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    • pp.330-335
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    • 1999
  • The objective of this stu요 was to develop a polymer mortar guide block for the blind handicapped people. A high strength and a long durability polymer concrete using unsaturated polyester resin was used to developed the block and to improve the exiting cement mortar guide bloc. Physical and mechanical properties of the polymer mortar guide block were investigated with respect to absorptivity, impact strength, bending strength compared to those of the conventional cement guide block. The polymer mortar guide block was proven to have properties , indication that the block have better industrial applications.

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A Study on new Photoinitiator of Visible Light Dental Composite Resin (치과용 가시광선 중합형 복합수지의 새로운 광개시제에 관한 연구)

  • Choi, Yong-Seok;Sun, Gum-Ju
    • Journal of Technologic Dentistry
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    • v.23 no.2
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    • pp.49-59
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    • 2002
  • The photopolymerization efficiency and surface hardness of composite resin containing 1,2-phenylpropanedione (PD) and diacetyl (DA) as photoinitiators were studied by IR and Vickers hardness and the results were compared with that of camphorquinone (CQ). Relative photopolymerization efficiency of the photoinitiators increased in the order of DA < CQ < PD. Vickers hardness of composite resin containing the photoinitiators increased in the order of CQ < PD < DA. Thus, PD is a new visible light photoinitiator for dental composite resin with higher photopolymerization efficiency and surface hardness than that of CQ. Mechanical properties such as Vickers hardness, diametral tensile strength, and flexural strength of the experimental resin composite prepared by addition of the photosensitizer into a resin of bis-GMA improved with increasing the photosensitizer content and irradiation time. The resin composite of bis-GMA containing DA or PD shows better mechanical properties than that of CQ.

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A Study on the dynamic viscoelasticity of UV curing polymer and alkyd resin composite materials (UV경화성 수지와 Alkyd수지 복합재료의 경화거동과 동적 점탄성에 관한 연구)

  • 정원식;최정병;김용욱
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.29-41
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    • 1998
  • The ultraviolet(UV)-curable materials wildly have been used as a ink and coating materials. A according to measure UV polymerization phase separation of acryl groups 2,3,4-functional monomer, a few experiments were performed gel fraction, dynamic viscosity of alkyd resin blend system. Dependence of photoiniator concentration and various monomer, alkyd resin content investigated structural changes of films cured by UV irradiation. Curing rate measured UV irradiation under $25^{\circ}C$, cell gap 7cm and film thickness 100${\mu}{\textrm}{m}$. In results, it was through that the viscoelastic properties of films cured with increasing the ratios of monomer/alkydresin contents are network polymer in properties such as viscoelasticity.

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The Viscosity Change of ABS Resin According to Inert Gas Amount (가스의 용해량에 따른 ABS 수지의 점도 변화)

  • 정태형;하영욱;정대진
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.585-590
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    • 1997
  • Conventional foaming process has defects such as lower mechanical properties than ur~foaming material due to non-uniform cell distribution and environmental pollution problem caused by chemical blowing agency. So, a new foaming process such as Microcelluar plastics has been introduced to use inactive gases as a foaming agency. In order to apply Microcellular plastics for mass production process system such as extrusion, injection molding and blow molding, it needs to predict the change in material properties of polymer according to the amount of meltingas. In Polymer molding applying Microcelluar plastics, the change of viscosity among several material properties is the most important factor. Therefore, this paper is aimed to establish the method which not only finds out but also predicts the change of viscosity of ABS(Acrylonitri1e Butadiene Styrene) resin according to inert gas amount in extrusion molding.

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Low- Temperature Decomposition of Epoxy Resin

  • Katsuhiko Saido;Hiroyuki Taguchi;Yoichi Kodera;Takeshi Kuroki;Park, Jeong-Hun;Chung, Seon-Yong
    • Macromolecular Research
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    • v.12 no.5
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    • pp.490-492
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    • 2004
  • We report a new method using a heating medium for the thermal decomposition of epoxy resin (EP) at temperatures ranging from 50 to 200$^{\circ}C$. EP decomposition also occurred below 50$^{\circ}C$ during a 6-day period to generate bisphenol A (BPA) at concentrations as high as 5 ppm. When polyethylene glycol was used as a heating medium, we determined the kinetics of the EP decomposition at low temperature. We determined the apparent activation energy of the overall decomposition to be 40.8 kJ/mol and the frequency factor to be 2.3${\times}$10$^3$ by monitoring the rate of BPA formation. Thus, EP is clearly unstable upon the application of heat.

Toughnening of Dielectric Material by Thermoplastic Polymer

  • Lee, Jung-Woo;Cho, Jae-Choon;Ra, Seung-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.207-208
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    • 2007
  • Recently, high performance microelectronic devices are designed in multi-layer structure in order to make dense wiring of metal conductors in compact size. Imprint lithography have received significant attention due to an alternative technology for photolithography on such devices. In this work, we synthesized dielectric composite materials based on epoxy resin, and investigated their thermal stabilities and dynamic mechanical properties for thermal imprint lithography. In order to enhance the mechanical properties and toughness of dielectric material, various modified polyetherimide(PEI) was applied in the resin system. Curing behaviours, thermal stabilities, and dynamic mechanical properties of the dielectric materials cured with various conditions were studied using dynamic differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA), and Universal Test Method (INSTRON).

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Preparation and Characterization of BCB Resin-BNT Composite Substrate Materials (BCB Resin-BNT 복합 기판 소재의 제조 및 특성 평가)

  • Kim, Un-Yong;Chun, Myoung-Pyo;Cho, Jung-Ho;Kim, Byung-Ik;Lee, Yong-Hyun;Myoung, Sung-Jae;Han, Ik-Hyun;Shin, Dong-Uk
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.179-183
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    • 2007
  • BCB $Resin-BaNd_2Ti_4O_{12}$(BNT) composites with BNT contents were prepared by tape casting method and epoxy resin-BNT composites were prepared by using heating press. Their dielectric properties and microstructures were investigated. The dielectric properties such as dielectric constant and dielectric loss at 1 MHz for epoxy resin-BNT composites and BCB resin-BNT composites are improved with an increase of BNT volume fraction. The dielectric constant of the Epoxy-BNT composite increased from 5.9 to 7.8 as the volume fraction of BNT increased from 15 to 25. The dielectric constant of the BCB-BNT composite increased from 9.1 to 15.5 as the volume fraction of BNT increased from 30 to 50. The dielectric behavior of BCB-BNT system can be explained by Lichtenecker's equation. The dielectric constant of epoxy resin-BNT composite is smaller than that of BCB resin-BNT composite. These results are considered to be related with the dispersion of BNT filler in polymer matrix from the result of SEM photograph.

Preparation of Coated-Wire Nitrate Ion Selective Electrode and its Application for Environmental Analysis (질산이온 선택성 피복선 전극의 제작 및 환경분석에의 응용)

  • 李龍根;金昌圭;朴廷泰;金京燮;黃圭子
    • Journal of Korean Society for Atmospheric Environment
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    • v.1 no.1
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    • pp.99-107
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    • 1985
  • A coated wire ion selective electrode for nitrate (nitrate-CWE_ was constructed using epoxy resin, ion exchanger and plasticizer as a polymer membrane. It's stility, the composition of a polymer membrane, the response characteristics, the selectivity were examined and applied to the environmental analysis. The nitrate-CWE was prepared using a copper wire, wihch was coated with epoxy resin being incorporated with the nitrate ion exchanger and plasticizer. The best composition of the polymer membrane for the nitrate-CWE was obtained by mixing epoxy resin, ion exchanger and plasticizer in the ratio of 2:1:0.4. The potential (56.3$\pm$0.5 mV) of stick form nitrate-CWE in this composition was close to that (59.2 mV) of Nernstian response. The detection limit for nitrate ion were found to the about $6 \times 10^{-5}M$ and the useful pH was 2.5 $\sim$ 10.3. Furthermore, the selectivity of iodide and perchrorate for the nitrage-CWE was also much improved compared with that for a liquid membrane nitrate electrode. The nitrate-CWE was used to determind $NO_x$ in stack gas. The results were in good agreement with those obtained either by electrode method or by the improved NEDA method within a relative error of 4.0%.

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