• Title/Summary/Keyword: Polymer science

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Photochromism of A Styrene-Derived Polymer Having Pendant Phenoxyanthraquinones

  • Ju, Sang-Yong;Ahn, Kwang-Duk;Han, Dong-Keun;Suh, Dong-Hack;Kim, Jong-Man
    • Journal of Photoscience
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    • v.7 no.4
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    • pp.131-133
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    • 2000
  • A Styrene-derived polymer having pendent phenoxyanthraquinones for photochromism was prepared by AIBN-initiated radical polymerization. Syntgesus of the monomers was straightforward and the polymer was obtained in 65% yield. Photoinduced rearrangement from the “trans” quinone forms to the “ana” quinone forms readily occurred both in solution and in film when the polymer was irradiated with UV light.

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Poly(vinyl alcohol) based Solid Polymer Electrolyte with Fast Cationic Transport Process

  • Jo, Yun-Kyung;Lee, Yu-Jin;Jo, Nam-Ju
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.187-187
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    • 2006
  • A new type solid polymer electrolyte (SPE) composed of poly (vinyl alcohol) (PVA) and lithium trifluoromethanesulfonate ($LiCF_{3}SO_{3}$) was prepared by means of the solution cast technique to observe that Li ion can move by ion hopping decoupled from polymer segmental motion inside of the 'fast cationic transport process'. The highest ion conductivity of the SPEs obtained from ac impedance measurements was $1.42{\times}10^{-3}S/cm$ at room temperature for SPE with 80wt% of salt concentration. Using LSV, we found that the SPEs had good electrochemical stabilities and using FT-IR and AFM, we found the formation of network-like structure.

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Polymer/LC Composite for Holographic Grating

  • Kim, Byung-Kyu;Woo, Ju-Yeon;Kim, Eun-Hee
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.218-218
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    • 2006
  • A number of new ideas have been implemented to control the droplet morphology and electrooptic properties of holographic polymer dispersed liquid crystal (HPDLC). Doping of conductive fullerene particles to the conventional HPDLC induced dual effects of reducing both droplet coalescence and operating voltage. Chain transfer agent gave higher gel content with lower crosslink density, less dark reactions and less grating shrinkage with much smooth LC-polymer interfaces. Addition of octanoic acid (OA) to the formulation of HPDLC gave a decrease in droplet size and monotonic increase of the off state diffraction throughout the OA content.

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Effect of Solubility Parameter Mismatch in Holographic PDLCs

  • Jung, Ju-Ai;Kim, Eun-Hee;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1216-1219
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    • 2004
  • LC and polymer miscibility in HPDLC has been studied in terms of solubility parameter. It was found that better grating formation and diffraction efficiency were obtained when the difference in solubility parameters between polymer and LC is greater.

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