• Composites Research
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• 제31권4호
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• pp.133-138
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• 2018

구조용 폼의 용도는 난연, 단열 기능이외에 구조적인 목적으로 공극부위를 충진시키는 용도로 사용되고 있다. 경량 소재 개발을 위해 CFRP와 구조용 폼이 이용되고 있으며, PUR, PIR, PVC, PET와 같은 대표적인 폼이 존재한다. 본 연구에서는 구조용 폼의 특성 중 강도 강화를 위한 목적으로 에폭시 폼을 개발하고자 하였다. 에폭시 조성 중 산무수물계 경화제는 기존의 폴리올과 반응을 하기 때문에 산무수물계 에폭시 수지에 발포제를 이용할 경우 폼이 형성되는지, 형성된다면, 압축특성과 포밍 형태를 관하는 연구를 진행하였다. 에폭시 폼을 형성시키기 위한 발포제의 종류에 따른 영향 및 발포재의 농도에 따라 변화되는 폼밍의 결과 차이를 분석하였으며, 산무수물계 수지의 조성차이에 따른 폼의 압축강도를 평가하였다. 궁극적으로 에폭시 폼을 최적의 발포제 선정으로 구조적 강도가 높은 폼을 형성시킬 수 있음을 확인하였으며, 기존의 구조용 폼 소재에 비해 높은 압축강도 및 비압축 강도를 가짐을 확인하였다.

• 한국농공학회:학술대회논문집
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• 한국농공학회 1998년도 학술발표회 발표논문집
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• pp.107-112
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• 1998

The objective of this study was to develop a polymer mortar defensive block with high strength and durability using unsaturated polyester resin to complement defects of conventional cement mortar defensive block. Physical and mechanical properties of the polymer mortar defensive block were also investigated. Low absorptivity, high impact strength, and great bending strength of the polymer mortar defensive block was compared with those of the conventional cement defensive block. In conclusion, the polymer mortar defensive block is excellent and useful as industrial products for erosion control works.

• 한국농공학회:학술대회논문집
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• 한국농공학회 1999년도 Proceedings of the 1999 Annual Conference The Korean Society of Agricutural Engineers
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• pp.330-335
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• 1999

The objective of this stu요 was to develop a polymer mortar guide block for the blind handicapped people. A high strength and a long durability polymer concrete using unsaturated polyester resin was used to developed the block and to improve the exiting cement mortar guide bloc. Physical and mechanical properties of the polymer mortar guide block were investigated with respect to absorptivity, impact strength, bending strength compared to those of the conventional cement guide block. The polymer mortar guide block was proven to have properties , indication that the block have better industrial applications.

• 대한치과기공학회지
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• 제23권2호
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• pp.49-59
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• 2002

The photopolymerization efficiency and surface hardness of composite resin containing 1,2-phenylpropanedione (PD) and diacetyl (DA) as photoinitiators were studied by IR and Vickers hardness and the results were compared with that of camphorquinone (CQ). Relative photopolymerization efficiency of the photoinitiators increased in the order of DA < CQ < PD. Vickers hardness of composite resin containing the photoinitiators increased in the order of CQ < PD < DA. Thus, PD is a new visible light photoinitiator for dental composite resin with higher photopolymerization efficiency and surface hardness than that of CQ. Mechanical properties such as Vickers hardness, diametral tensile strength, and flexural strength of the experimental resin composite prepared by addition of the photosensitizer into a resin of bis-GMA improved with increasing the photosensitizer content and irradiation time. The resin composite of bis-GMA containing DA or PD shows better mechanical properties than that of CQ.

• 한국인쇄학회지
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• 제16권3호
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• pp.29-41
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• 1998

The ultraviolet(UV)-curable materials wildly have been used as a ink and coating materials. A according to measure UV polymerization phase separation of acryl groups 2,3,4-functional monomer, a few experiments were performed gel fraction, dynamic viscosity of alkyd resin blend system. Dependence of photoiniator concentration and various monomer, alkyd resin content investigated structural changes of films cured by UV irradiation. Curing rate measured UV irradiation under $25^{\circ}C$, cell gap 7cm and film thickness 100${\mu}{\textrm}{m}$. In results, it was through that the viscoelastic properties of films cured with increasing the ratios of monomer/alkydresin contents are network polymer in properties such as viscoelasticity.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 추계학술대회 논문집
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• pp.585-590
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• 1997

Conventional foaming process has defects such as lower mechanical properties than ur~foaming material due to non-uniform cell distribution and environmental pollution problem caused by chemical blowing agency. So, a new foaming process such as Microcelluar plastics has been introduced to use inactive gases as a foaming agency. In order to apply Microcellular plastics for mass production process system such as extrusion, injection molding and blow molding, it needs to predict the change in material properties of polymer according to the amount of meltingas. In Polymer molding applying Microcelluar plastics, the change of viscosity among several material properties is the most important factor. Therefore, this paper is aimed to establish the method which not only finds out but also predicts the change of viscosity of ABS(Acrylonitri1e Butadiene Styrene) resin according to inert gas amount in extrusion molding.

• Macromolecular Research
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• 제12권5호
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• pp.490-492
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• 2004

We report a new method using a heating medium for the thermal decomposition of epoxy resin (EP) at temperatures ranging from 50 to 200$^{\circ}C$. EP decomposition also occurred below 50$^{\circ}C$ during a 6-day period to generate bisphenol A (BPA) at concentrations as high as 5 ppm. When polyethylene glycol was used as a heating medium, we determined the kinetics of the EP decomposition at low temperature. We determined the apparent activation energy of the overall decomposition to be 40.8 kJ/mol and the frequency factor to be 2.3${\times}$10$^3$ by monitoring the rate of BPA formation. Thus, EP is clearly unstable upon the application of heat.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.207-208
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• 2007

Recently, high performance microelectronic devices are designed in multi-layer structure in order to make dense wiring of metal conductors in compact size. Imprint lithography have received significant attention due to an alternative technology for photolithography on such devices. In this work, we synthesized dielectric composite materials based on epoxy resin, and investigated their thermal stabilities and dynamic mechanical properties for thermal imprint lithography. In order to enhance the mechanical properties and toughness of dielectric material, various modified polyetherimide(PEI) was applied in the resin system. Curing behaviours, thermal stabilities, and dynamic mechanical properties of the dielectric materials cured with various conditions were studied using dynamic differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA), and Universal Test Method (INSTRON).

• 한국세라믹학회지
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• 제44권5호
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• pp.179-183
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• 2007

BCB $Resin-BaNd_2Ti_4O_{12}$(BNT) composites with BNT contents were prepared by tape casting method and epoxy resin-BNT composites were prepared by using heating press. Their dielectric properties and microstructures were investigated. The dielectric properties such as dielectric constant and dielectric loss at 1 MHz for epoxy resin-BNT composites and BCB resin-BNT composites are improved with an increase of BNT volume fraction. The dielectric constant of the Epoxy-BNT composite increased from 5.9 to 7.8 as the volume fraction of BNT increased from 15 to 25. The dielectric constant of the BCB-BNT composite increased from 9.1 to 15.5 as the volume fraction of BNT increased from 30 to 50. The dielectric behavior of BCB-BNT system can be explained by Lichtenecker's equation. The dielectric constant of epoxy resin-BNT composite is smaller than that of BCB resin-BNT composite. These results are considered to be related with the dispersion of BNT filler in polymer matrix from the result of SEM photograph.

• 한국대기환경학회지
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• 제1권1호
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• pp.99-107
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• 1985

A coated wire ion selective electrode for nitrate (nitrate-CWE_ was constructed using epoxy resin, ion exchanger and plasticizer as a polymer membrane. It's stility, the composition of a polymer membrane, the response characteristics, the selectivity were examined and applied to the environmental analysis. The nitrate-CWE was prepared using a copper wire, wihch was coated with epoxy resin being incorporated with the nitrate ion exchanger and plasticizer. The best composition of the polymer membrane for the nitrate-CWE was obtained by mixing epoxy resin, ion exchanger and plasticizer in the ratio of 2:1:0.4. The potential (56.3$\pm$0.5 mV) of stick form nitrate-CWE in this composition was close to that (59.2 mV) of Nernstian response. The detection limit for nitrate ion were found to the about $6 \times 10^{-5}M$ and the useful pH was 2.5 $\sim$ 10.3. Furthermore, the selectivity of iodide and perchrorate for the nitrage-CWE was also much improved compared with that for a liquid membrane nitrate electrode. The nitrate-CWE was used to determind $NO_x$ in stack gas. The results were in good agreement with those obtained either by electrode method or by the improved NEDA method within a relative error of 4.0%.