• Title/Summary/Keyword: Polymer networks

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A study on the Dielectric Properties of IPN based on the Epoxy/Silicon and Epoxy/Urethane (Epoxy/Silicon Epoxy/Urethane계 IPN 복합재료의 개발에 관한 연구)

  • Shin, Joong-Hong;Jung, Eun-Shik;Park, Chung-Hoo
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.504-507
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    • 1987
  • Interpenerating Polymer Networks (IPNs) are unique type of polymer blend, synthesized by swelling a crossed polymer (Epoxy) with second polymer (Silicon) and also we adopted Urethane as the second polymer. The relationship between dielectric and mechanical properties of high temperature curing IPNs(E/S, E/U) are investigated. The ratios of weight that we formed we re two kind of thing, one (E/S) about 1[wt%]. 3[wt%], 5[wt%], 7[wt%], 10[wt%], and the other (E/U) about 5[wt%], 15[wt%], 25[wt%]. It was heat-cured for 24hours at $100^{\circ}C$ 48 hours at $10^{\circ}C$, 5 hours at $130^{\circ}C$, 15hours at $130^{\circ}C$ in E/S and also for 5 hours at $130^{\circ}C$ in E/U. From the viewpoint of dielectric and mechanical properties, the optimum condition is obtained from the sample cured for 5hours at $130^{\circ}C$ for 1[wt%] in the E/S, and also obtained from the sample cure d for 5 hours at $130^{\circ}C$ in E/U.

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Fast Switching of a Polymer-networked Twisted Nematic Liquid Crystal Cell (폴리머 네트워크가 형성된 TN 액정셀의 고속응답 특성)

  • Jin, Hye-Jung;Kim, Ki-Han;Baek, Jong-In;Kim, Jae-Chang;Yoon, Tae-Hoon
    • Korean Journal of Optics and Photonics
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    • v.21 no.2
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    • pp.69-73
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    • 2010
  • We propose a method to enhance the response time of a twisted nematic liquid crystal (TN-LC) cell using an anisotropic polymer. Polymer networks are formed by the phase separation between a LC and a UV-curable polymer. A TN-LC cell is exposed to UV light after the mixture of LC and anisotropic polymer is injected into the TN-LC cell. As a result, turn-off time of a TN-LC cell can be decreased remarkably without any loss of the transmittance. The turn-off time of a TN-LC cell with pure LC was 16 ms, but those of polymer networked TN-LC cells were 12, 11, and 9 ms when the concentration of the polymer was 3, 5, and 10 wt%, respectively. Moreover, by virtue of the polymer network, the backflow effect and the delay time generated during the turn-off process disappeared.

Microwave Application to the Vulcanization of Rubber Compound -(I) The Heating Characteristics of While Carbon by Microwave- (마이크로파를 응용한 Rubber Compound의 가황 - (I) 마이크로파에 의한 White Carbon의 가열특성 -)

  • Park, C.Y.;Kim, J.K.;Min, S.K.
    • Elastomers and Composites
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    • v.32 no.5
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    • pp.318-324
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    • 1997
  • Since the rigid and continuous networks of high-purity silica(white carbon) were relatively transparent to microwaves, high purity silica coupled with microwaves using a zirconia susceptor at room temperature and it was then heated to its melting temperature. The low-purity silica, contained small amount of impurities, yielded greater microwave absorption owing to easy motion of the interstitial alkali ions and it was then heated to its melting temperature. X-ray diffraction patterns of the low-purity silica were broader than those of the high-purity silica due to higher concentration of non-bridging bond and more deformed random network structure. In the vulcanization process of whitened or coloured rubber compound which is employing low-purity silica(white carbon) as a reinforcing filler, vulcanizate could be obtained effectively by microwave heating energy.

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Structure Formation in Multilayered Films Prepared by the Layer-by-Layer Deposition using PAA and HM-PEO

  • Seo, Jin-Hwa;Lutkenhaus Jodie L..;Kim, Jun-Oh;Hammond Paula T.;Char Kook-Heon
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.295-295
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    • 2006
  • In present study, poly(acrylic acid) (PAA) and hydrophobically modified poly(ethylene oxide) (HM-PEO) multilayers based on the hydrogen bonding between the component polymer pair have been prepared by the LbL deposition method. Dip assembled HM-PEO/PAA multilayers yield unique film morphologies in comparison with PEO/PAA multilayers due to the micellar formation of HM-PEO owing to the hydrophobic attraction between alkyl chains end-capped with the PEO chains. Individual HM-PEO micelles were connected through the bridging PEO chains to form temporary networks on multilayer surface and induced peculiar surface morphology on HM-PEO/PAA multilayers above the critical number of bilayers.

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Computation of dilute polymer solution flows using BCF-RBFN based method and domain decomposition technique

  • Tran, Canh-Dung;Phillips, David G.;Tran-Cong, Thanh
    • Korea-Australia Rheology Journal
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    • v.21 no.1
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    • pp.1-12
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    • 2009
  • This paper reports the suitability of a domain decomposition technique for the hybrid simulation of dilute polymer solution flows using Eulerian Brownian dynamics and Radial Basis Function Networks (RBFN) based methods. The Brownian Configuration Fields (BCF) and RBFN method incorporates the features of the BCF scheme (which render both closed form constitutive equations and a particle tracking process unnecessary) and a mesh-less method (which eliminates element-based discretisation of domains). However, when dealing with large scale problems, there appear several difficulties: the high computational time associated with the Stochastic Simulation Technique (SST), and the ill-condition of the system matrix associated with the RBFN. One way to overcome these disadvantages is to use parallel domain decomposition (DD) techniques. This approach makes the BCF-RBFN method more suitable for large scale problems.

A Study on the Dielectric Characteristics in Epoxy Resins due to Variation of Network Structures (망목 구조 변화에 따른 에폭시 수지의 유전 특성에 관한 연구)

  • 김재환;손인환;심종탁;김경환;김명호;최병옥
    • Electrical & Electronic Materials
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    • v.10 no.7
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    • pp.651-658
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    • 1997
  • In this paper, effect of interpenetrating polymer network(IPN) introduction on the dielectric properties, heat proof properties, internal structure and defects of the Epoxy/SiO$_2$composite materials, were investigated. we reported a relation between network structures and electrical properties, especially dielectric characteristics with variation of network structures for epoxy composite materials. According to experimental results, the specimens which have single network structures have lower dielectric constant than interpenetrating polymer network(IPN) specimens, but have relatively larger dependency to variation of temperature and frequency. It was confirmed that change of structures is attained by introducing of IPN to insulating materials. Therefore it is counted that introduction of multiple structure including IPN is necessary to improve heat proof and electrical properties.

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3-D Underwater Object Recognition Using Ultrasonic Sensor fabricated with 3-3 Type Piezoelectric Composites (3-3형 복합압전체 초음파 센서를 이용한 3차원 수중 물체인식)

  • Cho, Hyun-Chul
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1682-1684
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    • 2000
  • In this study, 3-D underwater object recognition using ultrasonic sensor fabricated with porous PZT-polymer 3-3 composites and SCL neural networks are presented. The recognition rates for the training data and the testing dara were 100 and 94.6% respectively.

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Crystallization of Poly(vinylidene fluoride)-SiO2 Hybrid Composites Prepared by a Sol-gel Process

  • Cho, Jae Whan;Sul, Kyun Il
    • Fibers and Polymers
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    • v.2 no.3
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    • pp.135-140
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    • 2001
  • Organic-inorganic hybrid composites consisting of poly(vinylidene fluoride) (PVDF) and SiO$_2$ were prepared through a sol-gel process and the crystallization behavior of PVDF in the presence of $SiO_2$ networks was investigated by spectroscopic, thermal and x-ray diffraction measurements. The hybrid composites obtained were relatively transparent, and brittleness increased with increasing content of tetraethoxysilane (TEOS). It was regarded from FT-lR and DSC thermal analyses that at least a certain interaction existed between PVDF molecules and the $SiO_2$ networks. X-ray diffraction measurements showed that all of the hybrid samples had a crystal structure of PVDF ${\gamma}$-phase. Fresh gel prepared from the sol-gel reaction showed a very weak x-ray diffraction peak near 2$\theta$=$21^{\circ}$ due to PVDF crystallization, and Intensity increased grade-ally with time after gelation. The crystallization behavior of PVDF was strongly affected by the amount of $SiO_2$ networks. That is, $SiO_2$ content directly influenced preference and disturbance fur crystallization. In polymer-rich hybrids, $SiO_2$ networks had a favorable effect on the extent of PVDF crystallization. In particular, the maximum portent crystallinity of PVDF occurred at the content of 3.7 wt% $SiO_2$ and was higher than that of pure PVDF. However. beyond about 10 wt% $SiO_2$, the crystallization of PVDF was strongly confined.

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