• Title/Summary/Keyword: Polymer electrolyte membrane fuel cell(PEMFC)

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Experimental Study of Polymer Electrolyte Membrane Fuel Cell Performance Under Low Operating Temperatures (상온 작동 환경하에서의 고분자 전해질막 연료전지의 성능에 대한 실험적 연구)

  • Cha, Dowon;Kim, Bosung;Kim, Yongchan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.8
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    • pp.687-693
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    • 2014
  • In this study, the performance characteristics of a polymer electrolyte membrane fuel cell (PEMFC) were investigated at low operating temperatures under steady-state and dynamic conditions. The performance of the PEMFC was analyzed according to the external humidifying rate and air stoichiometry. The ohmic resistance was also investigated using EIS tests. At the operating temperature of $35^{\circ}C$, voltage fluctuation occurred to a greater degree compared to that at $45^{\circ}C$. Therefore, it was found that the air stoichiometry should be higher than 2.5 for the stable operation of the fuel cell. In addition, the relative humidity of the reactant gases should be higher than 60 to reduce the ohmic resistance.

PROPERTY CHANGES OF POLYMER ELECTROLYTE MEMBRANES WITH FREEZE/THAW CYCLES (동결/해동 조건에서 고분자막의 특성 변화 연구)

  • Park Gu-Gon;Lim Nam-Yun;Sohn Young-Jun;Park Jin-Soo;Lee Won-Yong;Kim Sae-Hoon;Lim Tae-Won;Kim Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.281-283
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    • 2005
  • Water management in polymer electrolyte membrane fuel cells(PEMFCs) is one of the most challenging issues. Freeze start-up in the automotive applications is also important research topic in the PEMFC field. Transportation of proton and separation of reactant gases are main roles of polymer electrolyte membranes. It has been known that water in the membrane conducts as a vehicle for the proton transportation. At sub-zero temperature, the frozen water blocks the access of reactant gases to the active sites of electrode as well as occurs the physical destruction of fuel cell structures. In this study, property changes of electrolyte membranes in the freeze conditions $(at\;-25^{\circ}C)$ were investigated. For the various amount of water contained membranes, the property changes, especially for the proton conductivity, were observed after several times of freeze/thaw$(-25\~80^{\circ}C)$ cycle.

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Fuel Cell-based Cogeneration System for Greenhouse Cooling and Heating (온실 냉난방을 위한 연료전지 기반 열병합 발전 시스템)

  • JIN YOUNG PARK;TUANANH BUI;SEUNGYONG PARK;DONGKEUN LEE;YONGGYUN BAE;YOUNGSANG KIM;SANG MIN LEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.6
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    • pp.667-672
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    • 2023
  • This study proposes polymer electrolyte membrane fuel cell (PEMFC) based cogeneration system for greenhouse heating and cooling. The main scope of this study is to examine the proposed cogeneration system's suitability for the 660 m2-class greenhouse. A 25 kW PEMFC system generates electricity for two identical air-cooled heat pumps, each with a nominal heating capacity of 70 kW and a cooling capacity of 65 kW. Heat recovered from the fuel cell supports the heat pump, supplying hot water to the greenhouse. In cooling mode, the adsorption system provides cold water to the greenhouse using recovered heat from the fuel cell. As a result, the cogeneration system satisfies both heating and cooling capability, performing 175 and 145 kW, respectively.

Cost Policy Effects of Economic Feasibility of 1kw household PEMFC System (요금 정책이 PEMFC 시스템 경제성에 미치는 영향)

  • Kim, Ki-Young;Hwang, Nam-Sun;Kong, Min-Seok;Kim, Hee-Su;Oh, Si-Doek
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.31-34
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    • 2007
  • Fuel cell with high electric efficiency has many probabilities of commercial use. Especially, polymer electrolyte or proton exchange membrane fuel cell (PEMFC) which is a low operating temperature and has less influence on $CO_2$ concentration is considered the power generation system of small building and household. We calculated the optimal operational plans of 1 kW household PEMFC power system based on daily electric and heat demand patterns of various size of apartments. Calculated results show that the economic feasibility of PEMFC power system is very sensitive to the cost policy of electricity and natural gas.

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A Study on the Performance Analysis of Mobile Fuel Cell (모바일용 연료전지의 성능해석에 관한 연구)

  • Kim, Kwang-Soo;Choi, Jong-Pil;Jeong, Chang-Ryeol;Jang, Jae-Hyeok;Jeon, Byeong-Hee;Kim, Byeong-Hee
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.1
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    • pp.115-121
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    • 2008
  • In this paper, a three-dimensional computational fluid dynamic model of a proton exchange membrane fuel cell(PEMFC) with serpentine flow channel is presented. A steady state, single phase and isothermal numerical model has been established to investigate the influence of the GDL (Gas Diffusion Layer) parameters. The GDL is made of a porous material such as carbon cloth, carbon paper or metal wire mesh. For the simplicity, the GDL is modeled as a block of material having numerous pathways through which gaseous reactants and liquid water can pass. The porosity, permeability and thickness of the GDL, which are employed in the model parameters significantly affect the PEMFC performance at the high current region.

Preparation of Pt impregnated Nafion self-humidifying membranes for PEMFC using supercritical $CO_2$ (초임계 함침법을 이용한 PEMFC용 Pt/Nafion 자가가습막의 제조 연구)

  • Synn, Woo-Kyun;Kim, Hwa-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.433-437
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    • 2006
  • Pt/Nafion self-humidifying membranes for Polymer Electrolyte Membrane Fuel Cell(PEMFC) were synthesized via supercritical-impregnation methods. The Nafion 112 membranes were impregnated with Pt(II)$(acetylacetonate)_2$ from a supercritical carbon dioxide $(scCO_2)$ solution at $80^{\circ}C$ and 30MPa. After the impregnation, the pressure decreased slowly by releasing $CO_2$. And the Pt-impregnated Nafion membrane was converted Pt deposited Nafion membrane by reducing agent, sodium borohydride $(NaBH_4)$ with various concentrations under $50^{\circ}C$ and 2 hours. The prepared Pt-impregnated Nafion (Pt/Nafion) composite membrane were investigated by Electron Prove Micro analysis (EPMA) and X-rat Diffraction analysis (XRD) which showed distribution of Pt particle and Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) a which revealed morphology of surface of Pt/Nafion composite membrane. The performance of the Pt/Nafion 112 membranes was examined in PEMFC as aself-humidifyin membranes using purpose-built equipment.

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Model-based Fault Detection Method for the Air Supply System of a Residential PEM Fuel Cell (가정용 고분자전해질 연료전지 공기공급시스템의 모델 기반 고장 검출 기술)

  • WON, JINYEON;KIM, MINJIN;LEE, WON-YONG;CHOI, YOON-YOUNG;HONG, JONG SUP;OH, HWANYEONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.6
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    • pp.556-566
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    • 2019
  • Recently, as the supply of residential polymer electrolyte membrane fuel cells (PEMFCs) increases, the durability and lifetime of the PEMFC system are becoming important. The related studies have been mainly focused on the durability and lifetime of materials while the research on the durability and maintenance of the system level is insufficient. In this paper, a model-based fault detection method is developed considering an air supply system that is dominant to the system performance and efficiency. A commercial 1 kW residential fuel cell system is built, and experiments are conducted under various operation loads and states (normal, 6 faults). From the experimental data, nominal models and residuals are generated. With the residual pattern obtained from real-time data, the detection and classification of various faults can be possible. The technical importance of this paper is to minimize extra sensor installation by using the empirical model rather than a complex mathematical model, and to decrease the number of models by using the applicable model at three loads. Finally, the model-based fault detection method for the air supply system of a PEMFC is established and is expected to be applicable to other subsystems.

Computational Fluid Dynamics Study on Uniform Cooling of Polymer Electrolyte Membrane Fuel Cells by Parallel Multi-pass Serpentine Flow Fields (병렬 사형유로를 채택한 냉각판을 통한 고분자 전해질 연료전지의 균일 냉각에 대한 전산유체역학 해석 연구)

  • Yu, Seung-Ho;Baek, Seung-Man;Nam, Jin-Hyun;Kim, Charn-Jung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.10
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    • pp.885-891
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    • 2010
  • Thermal management is important for enhancing the performance and durability of polymer electrolyte membrane fuel cells (PEMFCs) and is taken into account in the design of PEMFCs. In general, cooling pates with circulating liquid coolant (water) are inserted between several unit cells to exhaust the reaction heat from PEMFCs. In this study, computational fluid dynamics (CFD) simulations were performed to characterize the uniform cooling performance of parallel multipass serpentine flow fields (MPSFFs) that were used as coolant flow channels in PEMFCs. The cooling performances of conventional serpentine and parallel flow fields were also evaluated for the purpose of comparison. The CFD results showed that the use of parallel MPSFFs can help reduce the temperature nonuniformity, and thus, can favorably enhance the performance and durability of PEMFCs.

A Study on Performance of Polymer Electrolyte Membrane Fuel Cell Using Metal Foam (Metal foam을 사용한 고분자 전해질 연료전지 성능 연구)

  • KIM, MYO-EUN;KIM, CHANG-SOO;SOHN, YOUNG-JUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.6
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    • pp.554-559
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    • 2015
  • Single cell of PEMFC (polymer electrolyte membrane fuel cell) is composed of bipolar plates, gasket, GDL and the MEA. Bipolar plate's function is the collecting electricity, helping oxygen/hydrogen gas diffuse evenly and draining the water and heat. In this work, we have conducted experiments to low contact resistance and improve the performance of a $25cm^2$ single cell by using metal forms. We have following experimental cases: 1) Conventional graphite serpentine channel bipolar plate; 2) Channel-less bipolar plate with nickel(Ni) based metal foam which coated by various materials. We focused the difference in contact resistance and performance of the single cell with metal foam depending on various coating materials. The experimental results show the similar performance of single cells between with serpentine channel bipolar plates and with channel-less bipolar plate using metal foams. In addition, single cell with metal foam shows potential to higher performance than conventional channel.

A Study on PWM Converter/Inverter Drive System by a Fuel Cell Simulator (연료전지 Simulator에 의한 PWM 컨버터/인버터 구동시스템에 관한 연구)

  • 이태원;장수진;김진태;구자성;원충연;김창현
    • The Transactions of the Korean Institute of Power Electronics
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    • v.9 no.3
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    • pp.222-230
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    • 2004
  • In this paper, a 3㎾ fuel cell generation system with an active fuel cell simulator has been proposed. The developed fuel cell simulator generates the actual voltage and current output characteristics of the Polymer Electrolyte Membrane Fuel Cell (PEMFC), so that the overall performance and the dynamics of the proposed system could be effectively examined and tested. In This paper, at first, the system configuration and operational principle of the developed fuel cell simulator has been investigated and the design process of the fuel cell generation system is explained in detail. In addition, the validity of the proposed system has been verified lly the informative simulation and experimental result