• Bulletin of the Korean Chemical Society
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• 제35권10호
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• pp.2963-2968
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• 2014

We report synthesis and photovoltaic properties of two new conjugated copolymers, PCPDTQxF and PDTSQxF, with 6,7-difluoro-2,3-dihexylquinoxaline unit prepared by Stille coupling reaction. The advantage of 6,7-difluoro-2,3-dihexylquinoxaline based copolymer are high PCEs due to lower HOMO energy level, long wavelength absorption and high hole mobility. The solid films of PCPDTQxF and PDTSQxF showed absorption bands with maximum peaks at about 623 and 493 nm and the absorption onsets at 711 and 635 nm, corresponding to band gaps of 1.74 and 1.95 eV, respectively. The oxidation onsets of the PCPDTQxF and PDTSQxF polymers were estimated to be 0.68 and 0.95 V, which correspond to HOMO energy levels of -5.48 and -5.75 eV, respectively. The PDTSQxF has lower HOMO energy level as compared to PCPDTQxF to lead higher $V_{OC}$ value. The device comprising PCPDTQxF:PCBM (1:2) dissolved to a concentration of 1 wt % in ODCB showed $V_{OC}$ value of 0.62 V, $J_{SC}$ value of $1.14mA/cm^2$, and FF of 0.35, which yielded PCE of 0.25%.

• 한국자기학회지
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• 제16권1호
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• pp.66-70
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• 2006

본 연구에서는 음향화학법을 적용한 공침 기술을 이용, 균일한 마그네타이트 나노 입자를 합성하였다 이 방법을 통하여 합성된 마그네타이트 나노 입자를 이용하여 마그네타이트 나노 입자들이 균일하게 분산된 마이크로미터 크기의 키토산 미소구체를 제조하였다. 이 연구의 목적은 생분해성, 저독성, 생체친화성의 특징을 갖고 있는 키토산과 균일한 마그네타이트 나노 입자를 이용하여 자기공명 영상의 조영제와 혈관 폐색을 위한 혈관 색전물질 등에 활용 가능성 있는 초상자성 특성을 갖는 미소구체를 제조하는 것이다. 우리는 $1\%$ 아세트산 용액을 사용하여 키토산 용액을 제조, 마그네타이트 나노 입자들을 분산시켰다. 키토산이 알칼리 수용액에서 겔화되는 성질을 이용하여, 마그네타이트 나노 입자들이 분산된 키토산 용액을 알칼리 용액에 분무하여 초상자성 특성을 갖는 자성 키토산 미소구체를 제조하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.631-631
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• 2013

Battery has major drawbacks including its size and life expectancy, and environmental problem. As an alternative, energy harvesting is emerging as a potential solution to replace battery along with more energy-efficient IT devices. The idea of harnessing energy from our living environment is sustainable, semi-permanent, and eco-friendly. Also, unlike battery, energy harvester does not require much space to store energy. Therefore, energy harvesting can provide a better source of power for small, portable, and wireless devices. Among various ways of harvesting energy from our surroundings, triboelectricity is chosen due to its potential to be miniaturized, and efficient. Triboelectric effect occurs as two different materials with different polarity of charge separation come into contact through friction, and then become separated so that electric potential difference is achieved. In this research, such characteristic of triboelectricity is used as a way to convert ambient mechanical energy into electric energy.Series of recent researches have shown promising results that the triboelectric energy harvester can be simple and cost effective. However, sufficient electricity level required to operate mobile devices has not yet been achieved.In this research, our group focuses on the design and optimization of triboelectric energy harvesting device to enhance its output. By using maskless lithography to pattern Kapton film and silicon substrate, which is used as a mold for PDMS thin layer, and sputtering metal electrodes on each side, we fabricate and demonstrate different designs of triboelectric energy harvester that utilizes the contact electrification between a polymer thin film and a metal thin foil. In order to achieve optimized result, the output voltage and current are measured under diverse conditions, which include different surface structure and pattern, material, and the gap between layers.

• 한국결정성장학회지
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• 제28권3호
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• pp.106-111
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• 2018

할라이드 페로브스카이트 나노결정은 고색순도 및 우수한 발광특성을 바탕으로 LED 응용에 대한 연구가 활발히 진행되고 있다. 고온주입법을 통하여 $CsPbX_3$(X = I, Br, and Cl) 나노결정을 합성하였고 할로젠 이온의 조성 변화를 통하여 발광파장을 제어하였다. 고분자 바인더를 사용하여 녹색과 적색의 필름을 제작하였다. 합성된 나노결정 및 제작된 필름의 우수한 광특성을 확인하였고, 이를 InGaN 청색 LED칩에 적용하여 우수한 색영역의 wLED를 구현하였다.

• 대한전자공학회논문지SD
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• 제37권12호
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• pp.18-23
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• 2000

본 논문에서는 유리기판 위에 공액고분자 물질인 MEH-PPV를 스핀 코팅한 후 Al 전극 사이에 초박막의 CsF층을 진공증착으로 삽입한 유기발광소자를 제안하였다. 이러한 구조에서 CsF층은 음극을 통해 주입된 전자들이 원활히 발광층으로 전송되어 유기발광소자의 발광효율을 증대시켰다. 또한 CsF층의 두께변화를 $2{\AA},\;4{\AA},\;8{\AA},\;10{\AA},\;20{\AA},\;50{\AA},\;75{\AA}$으로 변화를 주어 전류- 전압- 발광 특성을 조사하였다. 그리고 CsF/Al와 CsF/Au 및 Cs/Au 전극을 각각 진공증착하여 비교하였다. CsF층 두께가 $4{\AA}$에서 양자효율이 0.6%로 최대값을 나타냈고 $8{\AA}$ 이상에선 효율이 감소하였지만 CsF층이 없는 순수한 Al전극층에서 효율이 0.01%인 것에 비해 높은 양자효율 값을 유지하였다.

• Bulletin of the Korean Chemical Society
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• 제28권1호
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• pp.33-40
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• 2007

We have designed and synthesized three Zn(II)-porphyrin derivatives, such as Zn(II) porphyrin ([G-0]Zn-P1) and aryl ether-typed dendron substituted Zn(II)-porphyrin derivatives ([G-1]Zn-P1 and [G-1]Zn-P-CN1). Their chemical structures were characterized by 1H-NMR, FT-IR, UV-vis absorption, EI-mass, and MALDI-TOF mass spectroscopies. Their electrochemical properties were studied by cyclic voltammetry measurement. These Zn(II)-porphyrin derivatives have been used to fabricate dye-sensitized solar cells (DSSCs) based on solid polymeric electrolytes as dye sensitizers and their device performances were evaluated by comparing with that of a standard Ru(II) complex dye. [G-1]Zn-P-CN1 showed the enhanced power conversion efficiency than those of other porphyrin derivatives, as expected. Short-circuit photocurrent density (Jsc), open-circuit voltage (Voc), fill factor (FF), and power conversion efficiency (η) of solid-typed DSSC for [G-1]Zn-P-CN1 were evaluated to be Jsc = 11.67 mA/cm2, Voc = 0.51 V, FF = 0.46, and η = 2.76%, respectively.

• 대한기계학회논문집B
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• 제35권8호
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• pp.847-853
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• 2011

주위 매질의 움직임에 반응하는 섬유상 감각모는 대부분의 생물체에 존재하여 먹이, 침입자, 또는 동족 여부를 감지하는 역할을 한다. 이 기능을 모방한 인공 감각모를 설계 제작하기 위하여 유연 감각모를 기초로 한 수학모델을 제안하고, 작동영역에서의 응답특성을 파악하기 위하여 매개변수 해석을 수행하고 각 인자들의 영향을 고찰하였다. 유동 감각모의 변위를 일반화 좌표 및 고유 진동모드로 나타낸 결과, 탄성계수가 비교적 큰 Cytop 감각모의 경우 고유진동의 기본모드가 지배적인 것으로 나타났다. 주어진 유동 중에 있는 감각모의 동적거동은 형상에 크게 의존하였다. 또한 탄성계수가 큰 인공 감각모에서는 생물학적으로 중요한 주파수 범위 내에서 공진현상은 나타나지 않았다.

• 대한전자공학회논문지SD
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• 제37권5호
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• pp.39-48
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• 2000

제작 공정이 단순하고 결합길이가 매우 짧은 폴리머를 이용한 수직형 비대칭 광 결합기를 새로이 제안하고, 폴리머를 이용한 열광학 변조기를 제작하였다. 전산모의를 통하여 광통신 파장대인 1.33㎛ TE모드에서 중간 버퍼층 두께 t=0.4㎛이고, n/sub u/=1.522, n/sub l/=1.51이고 nt=1.49일 때, 결합길이가 277㎛이며, 최고 94%의 결합 및 재결합 효율을 얻음으로써 비대칭 구조에서의 최적화를 도모하였다. 또한 반전된 립도파로와 평면 도파로를 상하부 수직형태로 갖는 광결합기를 제작하고 폴리머를 이용한 열광학 변조기를 구현하였다. 변조특성은 구동전력 4.5㎽, 소멸비 17㏈, 변조대역 600㎐로 삽입손실은 4.5㏈였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.502-502
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• 2007

Current thin film process using memory device fabrication process use expensive processes such as manufacturing of photo mask, coating of photo resist, exposure, development, and etching. However, direct printing technology has the merits about simple and cost effective processes because inks are directly injective without mask. And also, this technology has the advantage about fabrication of fine pattern line on various substrates such as PCB, FCPB, glass, polymer and so on. In this work, we have fabricated the fine and thick metal pattern line for the electronic circuit board using metal ink contains Ag nano-particles. Metal lines are fabricated by two types of printing methods. One is a conventional printing method which is able to quick fabrication of fine pattern line, but has various difficulties about thick and high resolution DPI(Dot per Inch) pattern lines because of bulge and piling up phenomenon. Another(Second) methods is sequential printing method which has a various merits of fabrication for fine, thick and high resolution pattern lines without bulge. In this work, conductivities of metal pattern line are investigated with respect to printing methods and pattern thickness. As a result, conductivity of thick pattern is about several un.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2009년 추계학술발표대회
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• pp.217-220
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• 2009

Conductive adhesives have been investigated for use in microelectronics packaging as a lead-free solder substitute due to their advantages, such as low bonding temperature. However, high resistivity and poor mechanical behavior may be the limiting factors for the development of conductive adhesives. The metal fillers and the polymer resins provide electrical and mechanical interconnections between surface mount device components and a substrate. As metal fillers used in conductive adhesives, silver is the most commonly used due to its high conductivity and the stability. However the cost of conductive adhesives with silver fillers is much higher than usual lead-free solders and silver has poor electro-migration performance. So, copper can be a promising candidate for conductive filler metal due to its low resistivity and low cost, but oxidation causes this metal to lose its conductivity. In this study, electrically conductive adhesives (ECAs) using surface modified copper fillers were developed. Especially, in order to overcome the problem associated with the oxidation of copper, copper particles were coated with silver, and the silver-coated copper was tested as a filler metal. Especially the effect of silver coating on the electrical resistance just after curing and after aging was investigated. As a result, it was found that the electrical resistance of ECA with silver-coated copper filler was clearly lower and more stable than that of ECA with pure copper filler after curing process. And, during high temperature storage test, the degradation rate of electrical resistance for ECA with silver coated copper filler was quite slower than that for ECA with pure copper filler.