• 한국안전학회지
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• 제17권4호
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• pp.133-139
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• 2002

Core-shell polymers of inorganic/organic pair, which are consisted of both core and shell component, were synthesized by sequential emulsion polymerization using ethyl methacrylate (EMA) as a shell monomer and ammonium persulfate as initiator. We found that $CaCO_3$ core should be prepared by adding 2.0wt% SDBS(sodium dodecyl benzene sulfonate), $CaCO_3$ core/PEMA shell polymerization was carried out on the surface of $CaCO_3$ particle during EMA shell polymerization in the core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring the degree on decomposition of $CaCO_3$ by HCI solution, thermal decomposition of polymer composite on thermogravimetric analyzer, glass transition temperature on differential scanning calorimeter, and morphology using scanning electron microscope.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.775-780
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• 2002

Sandwich panel made by foamed styrene and ployuretane has been used generally in the construction area because of the high thermal conductivity and light weight but they occur harmful gases to both bodies and environments in the high temperature over $50^{\circ}C$. So, the purpose of this study is to investigate the physical properties of light-weight panel using the non-structural lightweight aggregate as a part of the substitution of foamed styrene and ployuretane. This paper dealt with the effect of the addition of polymer dispersion such as SBR, St/BA-1 and St/BA-2 having polymer-cement ratio as 5, 10, 15% and the filling ratio of continuous void as 50, 60% on the strength of polymer-modified sandwich panel core. From the results, we could know that the compressive and flexural strength of the sandwich panel core using non-structural lightweight aggregate and polymer dispersion such as SBR, St/BA-1 and St/BA-2 tended to be increased with an increase in the polymer-cement ratio and the filling ratio of continuous void.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.191-191
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• 2006

The structures of the mesophases and their subunits of PS-b-P4VP in a toluene solution were studied by using SAXS, TEM and GIFT methods. The hierarchical structures of PS-b-P4VP, such as the individual micelle, the face-centered cubic (fcc) and body-centered cubic (bcc) structures and the lamellar structure, were identified for the first time. The diameter of the micelle core was ${\sim}80\;%$ of the most extended chain length of the core chain, suggesting that the core chains were quite stretched. The stretched chain in the core caused the core of the micelle to be not homogenous with a higher density at the center than at the outer part. As the concentration level increases, the fcc and both fcc and bcc appear for the packing of the micelles of PS(3.3k)-b-P4VP(4.7K) and PS(12K)-b-P4VP(11.8K), respectively. The lamellar structure was also identified, with a further increase in the concentration for PS(3.3k)-b-P4VP(4.7K). These hierarchical structures were also identified via TEM images.

• Journal of the Optical Society of Korea
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• 제18권5호
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• pp.453-458
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• 2014

A novel high birefringent polymer terahertz (THz) fiber with a suspended elliptical core is proposed in this paper. The introduction of an elliptical core can enhance asymmetry to realize high mode birefringence, and a large porous outer cladding effectively isolates the core-guided mode from interacting with the surrounding environment. A full-vector finite element method(FEM) is used to analyze the characteristics of the THz fiber. Simulation results show that the suspended elliptical fiber exhibits high mode birefringence on a level of $10^{-2}$ over a wide frequency range, and an extremely large mode birefringence(${\approx}0.06226$) is obtained when ellipticity is 0.2. Moreover, a suspended hollow elliptical core fiber is also discussed for the purpose of lower loss, however high mode birefringence and low relative absorption loss can not coexist in such a kind of fiber.

• 한국농공학회지
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• 제31권2호
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• pp.125-134
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• 1989

This study was conducted to investigate the flexural behaviour of sandwich constructions with cement concrete core and polymer concrete facings. Six different cross-sectional shapes using epoxy based polymer concrete facings were investigated. Some of the results from the static tests are given including the load-deflection responses, load-strain relationships, ultimate moment, and mode of failure. From the. results the following conclusions can be made. 1. The various strengths of polymer concrete were very high compared to the strengths for portland cement concrete, while modulus of elasticity assumed an aspect of contrast. 2. The thickness of core and facing exerted a great influence on the deflection and ultimate strenght of polymer concrete sandwich constructions. 3. The variation shape of deflection and strain depend on loading were a very close approximation to the straight line. The ultimate strain of polymer concrete at the end of tensile side were ranged from 625x10-6 to 766x10-6 and these values increased in proportion to the decrease of thickness of core and facings. 4. The ultimate moments of polymer sandwich constructions were 3 to 4 times that of cement concrete constructions which was transformed same section. It should he noted that polymer concrete have an effect on the reinforcement of weak constructions. 5. Further tests are neede to investigate the shear strain of constructions, and thermal expansion, shrinkage and creep of cement and polymer concrete which were composite materials of sandwich constructions.

• 공업화학
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• 제27권1호
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• pp.26-34
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• 2016

본 연구에서는 반응성 비닐기를 가지고 있는 반응성 양친성 고분자 전구체(Reactive Amphiphilic Reactive Polymer Precursor) (RARP)를 이용하여 제조된 소수성 세그먼트들이 가교된 코아 가교 양친성 고분자(Core-crosslinked Amphiphilic Polymer) (CCAP) 나노입자와 나노침전법을 사용하여서 소수성 유용물질을 고함량으로 담지할 수 있는 새로운 공정을 제안하였다. 극성이 각기 다른 유기용매(에탄올, 아세톤, 테트라하이드로퓨란(THF))들과 소수성 세그먼트 분자량이 다른 CCAP를 사용하여서, 모델 유용 약물인 ${\alpha}$-tocopherol의 담지 효율, 담지량 및 약물 담지 나노입자의 크기와 안정성 변화를 조사하였다. 소수성 세그먼트 분자량이 큰 CCAP와 소수성 용매인 THF를 용매로 사용한 경우에 가장 높은 유용 약물 담지량, 담지 효율을 나타내는 안정한 나노입자가 형성이 되었다. 즉 CCAP 나노입자들의 물리적 화학적으로 견고한 나노 구조로 인해서 33 wt%의 높은 담지량과 97% 이상의 담지 효율을 가지면서 물속에서 70 nm의 크기의 안정한 유용 약물 담지 고분자 나노입자를 제조할 수 있었다.

• 한국응용과학기술학회지
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• 제27권1호
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• pp.93-97
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• 2010

Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S75D) surfactant was prepared. The core-shell composite of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate(KPS) as an initiator. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant lauryl sulfate(SLS). The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

• Interaction and multiscale mechanics
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• 제1권2호
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• pp.231-250
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• 2008

The statistical two-order and two-scale method is developed for predicting the mechanics parameters, such as stiffness and strength of core-shell particle-filled polymer composites. The representation and simulation on meso-configuration of random particle-filled polymers are stated. And the major statistical two-order and two-scale analysis formulation is briefly given. The two-order and two-scale expressions for the strains and stresses of conventionally strength experimental components, including the tensional or compressive column, the twist bar and the bending beam, are developed by means of their classical solutions with orthogonal-anisotropic coefficients. Then a new effective mesh generation algorithm is presented. The mechanics parameters of core-shell particle-filled polymer composites, including the expected stiffness parameters, minimum stiffness parameters, and the expected elasticity limit strength and the minimum elasticity limit strength, are defined by means of the stiffness coefficients and elasticity strength criterions for core, shell and matrix. Finally, the numerical results for predicting both stiffness and elasticity limit strength parameters are compared with the experimental data.

• 한국응용과학기술학회지
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• 제27권2호
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• pp.183-187
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• 2010

Core-Shell polymers of silicone dioxide-styrene system were prepared by sequential emulsion polymerization. In inorganic/organic Core-Shell composite particle polymerization, silicone dioxide adsorbed by surfactant sodium dioctyl sulfosuccinate (EU-DO133L) was prepared initially and then core silicone dioxide was encapsulated emulsion by sequential emulsion polymerization using styrene at the addition of potassium persulfate (KPS) as an initiator. We found that $SiO_2$ core shell of $SiO_2$/styrene structure was formed when polymerization of styrene was conducted on the surface of $SiO_2$ particles, and the concentration sodium dioctyl sulfosuccinate (EU-DO133L) was 0.5~2.0g. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

• 한국농공학회논문집
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• 제46권6호
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• pp.29-36
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• 2004

In this study, The fatigue properties of the GFRP composite panels of which core was made of the polymer mortar and both facings were reinforced by the high-tensile GFRP were surveyed. Composite-panel specimens consisted of polymer mortar core and GFRP compressive and tensile sides with various thickness were produced for an experimental study. Flexural fatigue tests were conducted to examine the correlation between the fatigue load and the fatigue life for various thickness of core and facings, and its results are presented. The correlation obtained in this study between the fatigue load and the fatigue life for various thickness arc in good agreement with the modified Miner's law.