• Title/Summary/Keyword: Polymer concentration

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Development of Washable Wool Using Environmental-friendly Spray UV-cure Finishing Technique - Using Photocrosslinkable Polymerr Dextran-methacrylate- (환경친화적 Spray UV-Cure 가공 기술을 이용한 물세탁 모직물(washable wool)의 개발 -광가교 고분자인 dextran-methacrylate를 이용하여-)

  • 김신희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.11
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    • pp.1507-1515
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    • 2004
  • Washable wool was developed using environmental-friendly spray UV-cure technique. Photocrosslinkable polymer, dextran-methacrylate, was synthesized starting from natural biopolymer, dextran. The aqueous solution of dextran-methacrylate was applied to wool fabric with various concentrations to find out the optimum condition in minimizing felting shrinkage. The wool fabric subsequently cured by 365 nm UV, The effects of UV-cure time and photoinitiator concentration on felting behavior of wool were examined. As the concentration of dextran-methacrylate increased, the felting shrinkage decreased gradually. At concentration 0.5g/ml, the felting shrinkage of wool was negligible. Other properties such as air permeability, moisture content, wrinkle recovery, thickness and wettability were also evaluated. The surface coating of dextran polymer onto wool fiber was identified by SEM.

Effect of polymer concentration in cryogelation of gelatin and poly (vinyl alcohol) scaffolds

  • Ceylan, Seda;Demir, Didem;Gul, Gulsah;Bolgen, Nimet
    • Biomaterials and Biomechanics in Bioengineering
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    • v.4 no.1
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    • pp.1-8
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    • 2019
  • The aim of this study was to investigate the effect of total polymer concentration on the chemical structure, morphology of pores, porosity, swelling ratio, degradation of gelatin-poly (vinyl alcohol) (Gel-PVA) cryogel scaffolds. Porous cryogels were prepared with cryogelation technique by using glutaraldehyde as a crosslinker. Functional group composition of cryogels after crosslinking was investigated by Fourier Transform Infrared (FTIR). The morphology of cryogels was characterized via scanning electron microscopy (SEM) and porosity analysis. All of the cryogels had a porous structure with an average pore size between $45.58{\pm}14.28$ and $50.14{\pm}4.26{\mu}m$. The cryogels were biodegradable and started to degrade in 14 days. As the polymer concentration increased the swelling ratio, the porosity and the degradation rate decreased. Spongy and mechanically stable Gel-PVA cryogels, with tunable properties, can be potential candidates as scaffolds for tissue engineering applications.

Effects of Solvent Size on Microscopic Structures and Properties in Polymer Solutions

  • Li, Yunqi;Shi, Tongfei;An, Lijia
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.116-117
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    • 2006
  • Increasing the solvent molecular size leads to shrinkage of the polymer chains and increase of the critical overlap concentrations. In addition, the dependency of $R_{g}$ on polymer concentration under normal solvent conditions and solvent molecular size is in good agreement with scaling laws. When the solvent molecular size approaches the ideal end-to-end distance of the polymer chain, an extra aggregation of polymer chains occurs, and the solvent becomes the so-called medium-sized solvent. When the size of solvent molecules is smaller than the medium size, the polymer chains are swollen or partially swollen. However, when the size of solvent molecules is larger than the medium size, the polymer coils shrink and segregate, enwrapped by the large solvent molecules.

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Modification of Nafion Membranes for Reduction of Methanol Transport Rate

  • Kang, Dong-Hoon;Kim, Duk-Joon
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.127-128
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    • 2006
  • Nafion/basic polymer composite membranes were prepared to reduce the methanol crossover for the application of direct methanol fuel cell. The thermal and mechanical properties increased with increasing basic polymer contents due to the formation of complex via acid/basic interaction. The water uptake, proton conductivity, methanol permeability decreased with increasing basic polymer concentration by reduction of acidity associated with the formation of acid/base complex. The molecular effect on those properties was not considerable.

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Evaluation of Inhomogeneous Deformation and Stress Concentration In Polymer Composites Injection Weld by means of Thermoelastic Techniques

  • Lim, Jae-Kyoo;Kim, Yon-Jig
    • Journal of Mechanical Science and Technology
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    • v.15 no.12
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    • pp.1616-1622
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    • 2001
  • Fiber composite materials are widely used in aerospace industries due to their high specific strength and stiffness. Especially, the increasing use of polymer composite materials for injection of automobile components has led to a considerable interest in the application of stress pattern analysis by thermal emission to these composite materials. Therefore, in this study the microstructure of glass fiber orientation at the parent and weld line of polycarbonate is observed by a light transmission. And we also investigate a stress concentration model of a notch including short glass fibers. Especially the polymer injection weld reorients the fiber to suggest a new method for the evaluation of inhomogeneous deformation.

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Aqueous alkali-developable Photosensitive Barrier Rib Paste for PDP and Photolithographic Process

  • Park, Lee-Soon;Jeong, Seung-Won;Kim, Soon-Hak;Tae, Heung-Sik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.177-179
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    • 2000
  • Barrier rib for the plasma display panel (PDP) was made by photolithographic process utilizing photosensitive barrier rib paste. The barrier rib paste was prepared by first dissolving poly(MMA-co-MAA) binder polymer in butyl carbitol(BC) solvent at 15 wt% concentration. To this solution were added a mixture of functional monomers , Irgacure 651 photoinitiator, and barrier rib power and then the whole mixture was dispersed in the three roll mill for 2 hour. The effect of component and concentration of photosensitive barrier rib paste was studied. After optimization of the paste formulation and photolithographic process, barrier rib could be obtained with good resolution up to 110-120 ${\mu}m$ height and 80-90 ${\mu}m$ width.

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An Experimental Study on the Degradation of Polymer in Closed Flow System (밀폐계 유동시스템내에서 고분자물질의 퇴화에 관한 실험적 연구)

  • 김재근
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.5
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    • pp.679-686
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    • 1999
  • This study is to investigate the effect of a substantial drag reduction caused by the polymer(A611P) when the working fluids flow to the vertical direction in the vertical cylindrical equipment of closed flow system. The drag reduction is associated with the mechanical degrada-tion thermal degradation and heat transfer. By ignore the heat fluxs within the closed system the pressure drop due to the polymer concentration the flow velocity and flow time have been mea-sured. By taking into account the mechanical and thermal degradation in the closed system an experiment has been focused on the determination of the condition which could improve the pump capacity in the heat union electric power plant. Under the condition of non-boiling it has been found out that the change of heat flux has little influence on the drag reduction.

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Compatibility at Polymer/Polymer Mixture Interfaces in the Presence of Solvent

  • Yoon, Kyung-Sup;Park, Hyung-Suk;Lee, Jo-Woong;Chang, Tai-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.15 no.3
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    • pp.214-221
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    • 1994
  • We present some results obtained from theoretical study on a non-symmetrical A/BC polymeric system including solvent which consists of two phases, a polymeric phase A on one side and a mixture of polymers B (as a compatibilizer) and C on the other in the presence of a solvent. By employing the functional integral techniques we derive the mean-field equations and solve them numerically to deduce the physical properties of the interface involving the polymers and solvent concentration profiles in the limit that molecular weights of all the polymers involved tend to infinity. The calculations are performed for typical values of the Flory interaction parameters and for the volume fraction of polymer B in the asymptotic phase and of solvent. In the polymers/solvent blend under consideration the interfacial adsorption of polymer B, the solvent concentration, and degrees of the specific interaction between the polymers are found to play important roles in modification of the interfacial properties.

Application of Electronic Nose for Aroma Analysis of Persimmon Vinegar Concentrates (감식초 농축액들의 향기성분 분석에 대한 전자코의 적용)

  • Lee, Boo-Yong
    • Korean Journal of Food Science and Technology
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    • v.31 no.2
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    • pp.314-321
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    • 1999
  • This study was performed to test application possibility of electronic nose with 32 conducting polymer sensor arrays for aroma analysis of persimmon vinegar. The 20, 30, 40, 50, 60, and $70^{\circ}Bx$ persimmon vinegar concentrates were prepared by vacuum concentration at $55^{\circ}C$. The recovery yield of water soluble solid to concentrates was 55.5% on $20^{\circ}Bx$ persimmon vinegar concentrate. As the concentration of persimmon vinegar concentrates increased, pH of concentrates increased and acidity as acetic acid decreased. From sensory evaluation for persimmon vinegar concentrates, as the concentration of persimmon vinegar concentrates increased, their cooking odor and umami taste increased, sour taste and acidic odor decreased, salty odor and astringency were not changed. Aroma analysis by electronic nose (AromaScan) showed no difference in normalized pattern and odor intensity among persimmon vinegar concentrates. All quality factors among concentrates also were less than 1.042. And so the electronic nose with conducting polymer sensor was not suitable for aroma analysis of persimmon vinegar concentrate.

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