• Title/Summary/Keyword: Polymer composites

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Surface Modified Glass-Fiber Effect on the Mechanical Properties of Glass-Fiber Reinforced Polypropylene Composites

  • Park, Sanghoo;Kim, Su-Jong;Shin, Eun Seob;Lee, Seung Jun;Kang, Beom Mo;Park, Kyu-Hwan;Hong, Seheum;Hwang, Seok-Ho
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.182-187
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    • 2019
  • To improve the mechanical properties of glass-fiber-reinforced polypropylene (PP) composites through interfacial adhesion control between the PP matrix and glass fiber, the surface of the glass fiber was modified with PP-graft-maleic anhydride (MAPP). Surface modification of the glass fiber was carried out through the well-known hydrolysis-condensation reaction using 3-aminopropyltriethoxy silane, and then subsequently treated with MAPP to produce the desired MAPP-anchored glass fiber (MAPP-a-GF). The glass-fiber-reinforced PP composites were prepared by typical melt-mixing technique. The effect of chemical modification of the glass fiber surface on the mechanical properties of composites was investigated. The resulting mechanical and morphological properties showed improved interfacial adhesion between the MAPP-a-GF and PP matrix in the composites.

Health monitoring of carbon fiber-reinforced polymer composites in γ-radiation environment using embedded fiber Bragg grating sensors

  • Jing Zhong;Feida Chen;Yuehao Rui;Yong Li;Xiaobin Tang
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.3039-3045
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    • 2023
  • Fiber-reinforced polymer (FRP) composites are considered suitable candidates for structural materials of spacecrafts due to their excellent properties of high strength, light weight, and corrosion resistance. An online health monitoring method for FRP composites must be applied to space structures. However, the application of existing health monitoring methods to space structures is limited due to the harsh space environment. Here, carbon fiber-reinforced polymer (CFRP) composites embedded with fiber Bragg grating (FBG) sensors were prepared to explore the feasibility of strain monitoring using embedded FBG sensors in γ-radiation environment. The analysis of the influence of radiation on the strain monitoring demonstrated that the embedded FBG can be successfully applied to the health monitoring of FRP composites in radiation environment.

Interfacial Shear Strength and Thermal Properties of Electron Beam-Treated Henequen Fibers Reinforced Unsaturated Polyester Composites

  • Pang Yansong;Cho Donghwan;Han Seong Ok;Park Won Ho
    • Macromolecular Research
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    • v.13 no.5
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    • pp.453-459
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    • 2005
  • Natural fiber henequen/unsaturated polyester (UPE) composites were fabricated by means of a compression molding technique using chopped henequen fibers treated at various electron beam (EB) dosages. The interfacial shear strength (IFSS), dynamic mechanical properties, and thermal expansion behavior were investigated through a single fiber microbonding test, fractographic observation, dynamic mechanical analysis, and thermomechanical analysis, respectively. The results indicated that the interfacial and dynamic mechanical properties significantly depended on the level of the EB treatment irradiated onto the henequen fiber surfaces. The effect of EB treatment on the IFSS, storage modulus and fracture surface of the henequen/UPE composites agreed with each other. The results of this study also suggested that the modification of henequen fiber surfaces at 10 kGy EB is the most effective for improving the interfacial properties of the henequen/UPE composites.

Dielectric Properties of Polymer-ceramic Composites for Embedded Capacitors

  • Yoon, Jung-Rag;Han, Jeong-Woo;Lee, Kyung-Min
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.4
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    • pp.116-120
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    • 2009
  • Ceramic-polymer composites have been investigated for their suitability as embedded capacitor materials because they combine the processing ability of polymers with the desired dielectric properties of ceramics. This paper discusses the dielectric properties of the ceramic ($BaTiO_3$)-polymer (Epoxy) composition as a function of ceramic particle size at a ceramic loading of 40 vol%. The dielectric constant of these ceramic-polymer composites increases as the powder size decreases. Results show that ceramic-polymer composites have a high dielectric constant associated with the $BaTiO_3$ powder with a 200 nm particle size, high insulation resistance, high breakdown voltage (> 22 KV/mm), and low dielectric loss (0.018-0.024) at 1 MHz.

Nano-Hydroxyapatite Modified by Grafting Polylactide and its Tissue Engineering Application

  • Zhuang, Xiuli;Zhang, Peibiao;Qiu, Xueyu;Chen, Xuesi;Jing, Xiabin
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.182-182
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    • 2006
  • PLLA grafted Hydroxyapatite / polylactide (g-HA/PLA) composites were prepared by three grafting methods. The modified particles (p-HA) were dispersed more uniformly in the PLLA matrix than pure n-HA. The p-HA/PLLA composites exhibited better mechanical properties and thermal stability than the n-HA/PLLA composites. The composites also demonstrated improved cell compatibility due to the good biocompatibility of the HAP nanoparticles and the more uniform distribution of the PLLA-grafted HAP nanoparticles on the film surface. All of these results indicated that the p-HAP/PLLA nano-composites might have a promising medical application in bone repair and in bone tissue-engineering.

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Microstructure and Properties of Fully Aliphatic Polyimide/Mesoporous Silica Hybrid Composites

  • Mathewst, Anu Stella;Jung, Yu-In;Lee, Tae-Sung;Park, Sung-Soo;Kim, Il;Ha, Chang-Sik;Selvaraj, M.;Han, Mi-Jeong
    • Macromolecular Research
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    • v.17 no.9
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    • pp.638-645
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    • 2009
  • We report the effect of the amount of the mesoporous material, SBA-15, on the basic traits of fully aliphatic polyimides (API). For this purpose, water soluble, fully aliphatic poly(amic acid) triethyl amine salts ($PAA_{(s)}$) were prepared and mixed with various amounts of SBA-15. Fully aliphatic polyimide hybrid composites containing the SBA 15-type mesoporous silica were synthesized successfully from bicyclo [2.2.2] oct-7-ene-2,3,5,6-tetracarboxylic dianhydride and alicyclic diamine, 4,4'-methylene bis(2-methylcyclohexylamine). The structure of the hybrid composites was confirmed by IR spectroscopic analysis. Scanning electron microscopy revealed the morphology of the compounds. The hybrid composites exhibited good thermal stability, reasonable transparency, and a low dielectric constant.

Fabrication and Characterization of graphite reinforced conductive polymer composites (탄소 보강 전도성 고분자 복합재료의 제조 및 특성 평가)

  • Heo S. I.;Yun J. C.;Jung C. K.;Han K. S.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.147-150
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    • 2004
  • Graphite reinforced conductive polymer composites were fabricated by the compression molding technique. Graphite powder (conductive filler) was mixed with an epoxy resin to impart electrical property in composites. The ratio of graphite powder was varied to investigate electrical property of cured conductive composites. In this study, graphite filled conductive polymer composites with high filler loadings$(>60wt.\%)$ were manufactured to accomplish high electrical conductivity(> 100S/cm). Graphite powder increase electrical conductivity of composites by direct physical contact between particles. While high filler loadings are needed to attain good electrical property, the composites becomes brittle. So the ratio of filler to epoxy was varied to optimize of cured composites. The optimum molding pressure according to filler was proposed experimentally.

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Preparation and Property of Ceramic/Polymer 3-3 Composites with Matrices (각종 Matrix를 이용한 Ceramic/Polymer 3-3 Composies의 제작 및 특성)

  • Park, J.H.;SaGong, G.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1122-1124
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    • 1993
  • In this study, piezoceramics/polymer composites with 3-3 connectivity were made by BURPS(Burnout Plastic Sphere) technique with PZT ceramics and PVA sphere. And physical and dielectric properties dependent on the PVA wt.% were investigated. The density of porous piezoceramic and pieaoceramic/polymer composites were decreased almost linearly with increasing the PVA wt.%.

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Nanocarbon Polymer Composites (나노탄소 고분자 복합재료)

  • Choe, Chul Rim
    • Composites Research
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    • v.26 no.3
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    • pp.147-154
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    • 2013
  • Nanocarbons such as carbon nanotubes (CNT) and graphene are considered to be ideal fillers for polymer composites, because of their outstanding mechanical properties and high length-to-diameter ratio. There has been much effort to realize the implementation of their full potential, but a large number of unsolved problems still must be challenged, for example, effective processing for fabrication. This review deals with the progress that has already been made in the area of nanocarbon polymer composites using CNT and graphene. Mechanical reinforcement of various nanocarbon polymer composites is analyzed and compared, and future perspectives in research and development that need to be done are discussed.