• 제목/요약/키워드: Polymer coating

검색결과 787건 처리시간 0.023초

대두종자의 polymer coating 연구 1. polymer coating 종자의 conductivity 차이 (Studies on Polymer Coating in Soybean Seeds 1. Difference of Electrolyte Leaching of Polymeric Coating Soybean Seed)

  • 이성춘
    • 한국작물학회지
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    • 제39권2호
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    • pp.158-164
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    • 1994
  • Polyme coating 종자의 환경적응성을 구명하기 위한 일환으로 콩 종자에 10종의 polymer를 coating하여 각 coating polymer별 conductivity, 발아력, 수분흡수력을 조사하였던 바 그 결과를 요약하면 다음과 같다. 1. Conductivity는 polymer coating한 종자가 coating하지 않은 종자보다 높았으며, 가장 높았던 polymer는 waterlock이었다. 2. Conductivity는 침종 후 시간이 경과할 수록 높아졌고, 100립중이 무거울 수록 높았다. 3. 수확년도가 오래된 종자의 conductivity가 당년에 수확한 종자보다도 높게 나타났다 4. 수분흡수 정도는 coating polymer에 따라 각각 달랐는데 daran 8600은 질이 떨어지는 종자에서는 수분흡수를 크게 저 해하였다. 5. Coating polymer 중 waterlock, captan, klucel, sacrust 등은 발아율을 상승시켰고, daran 8600은 발아율을 저하시켰으며 나머지 polymer는 품종에 따라 각각 달랐고 그 정도는 질이 떨어지는 종자에서 훨씬 컸다. 6. Polymer의 특성에 따라 수분흡수를 저해하거나 조장하였다.

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Bend Resistance of Polymer Cement Slurry Coated Reinforcing Bars

  • Kim, Wan-Ki;Chang, Sung-Ju;Kim, Hyun-Ki;Soh, Yang-Seob
    • KCI Concrete Journal
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    • 제13권2호
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    • pp.42-48
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    • 2001
  • The bend resistance of coated reinforcing bar is greatly influenced by both the adhesion strength between bar and coating materials, and the followed transformation of coating material as bars bend. Especially, tearing state or partial microscopic cracks are predicted on the inside and outside of bending angle, because tensile strength and elongation of polymer film are very different according to types of polymer dispersions in bar coating, and these damaged parts are rapidly corroded by penetration of corrosive factors. In this study, polymer cement slurry coated reinforcing bars with various polymer dispersions are prepared by following combined conditions, polymer-cement ratio of 50% and 100%, coating thickness of 250$\mu$m and 450$\mu$m, coating number, curing age of 3, 7, 14 and 28days. Then the specimens are tested for working life and bend resistance at bending angles $90^{\circ}$, $135^{\circ}$and $180^{\circ}$ to observe the microscopic damage effect as the bars bend. Also, epoxy-coated reinforcing bars for control experiment were used with 250$\mu$m of coating thickness. The tensile strength for polymer films is performed. From the test results, the working life of the polymer cement slurry is within 90 seconds. Among four types of polymer dispersion, polymer cement slurry coated reinforcing bar using St/BA-1 emulsion has the excellent bend resistance, which is remarkably improved than that of epoxy-coated reinforcing bar. And the bend resistance is more related to elongation than tensile strength of polymer film. Polymer cement slurry with a polymer-cement ratio of 100%, a coating thickness of $450\mu$m and one coating using St/BA emulsion is selected as a most suitable coating material for coated reinforcing bar.

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경제적이고 효과적인 경피 약물전달을 위한 3차원 구조의 코팅 고분자 마이크로니들 (3-Dimensional Coating Polymer Microneedles for Economical and Efficient Transdermal Drug Delivery)

  • 이한솔;박정환
    • 폴리머
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    • 제38권3호
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    • pp.391-396
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    • 2014
  • 고분자 마이크로니들은 몰딩 공정으로 쉽고 저렴하게 생산할 수 있지만 3차원 고분자 마이크로 구조체에 수용액 기반의 약물 코팅은 어려움이 있다. 2차원 형태의 평면 금속 마이크로니들에 약물을 코팅한 기존의 코팅 마이크로니들과 비교하여 볼 때 3차원 구조의 고분자 마이크로니들은 코팅 면적이 2배 넓고 단위면적당 마이크로니들의 수를 크게 증가시킴으로써 두 배 이상의 약물을 경피를 통해 전달할 수 있다. 증점제와 계면활성제 첨가 방법의 경우 2차원의 평면에는 균일한 코팅을 얻을 수 있었지만 3차원 구조의 고분자 마이크로니들 표면에서는 만족할 코팅을 얻지 못했다. 하지만, 고분자 마이크로니들 표면을 금속 코팅 혹은 UV/ozone으로 처리한 경우 3차원의 마이크로 니들 표면에 만족할 코팅을 얻을 수 있었으나 금속 코팅의 경우 피부에 찌르고 제거하는 과정에서 금속이 피부 안에 남는 안전성 문제가 있어 UV/ozone을 최종 표면 처리 방법으로 선정하였다. 이렇게 처리한 고분자 마이크로니들 표면에 calcein이 첨가된 코팅물질로 코팅된 마이크로니들은 15분 이상의 피부 투여로 코팅물질을 성공적으로 진피층까지 전달할 수 있었다.

안정된 스텐트 코팅막을 형성하기 위해 금속표면과 고분자 사이의 화학적 결합을 이용한 고분자 코팅법 개발 (Development of Polymer Coating Method for Stable Stent Coating Using Chemical Bond Between Metal Surface and Polymer)

  • 남대식;이우경
    • Journal of Pharmaceutical Investigation
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    • 제37권1호
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    • pp.7-13
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    • 2007
  • To produce stable polymer coating layer using the interaction between metal stent and polymer layer, Ahx-HSAB was synthesized by coupling 6-aminoheanoic acid (Ahx) with N-Hydroxy succinimidyl 4-azidobenzonate (HSAB) containing photo reactive group. Then, Ahx-HSAB was applied to self·assembled monolayer (SAM) on $TiO_2$-coated surface, since one end of Ahx-HSAB was carboxyl acid which was known to be able to interact with $TiO_2$ surface. That SAM layer was incubated in 1% polycaprolacton (PCL) solution and photoreacted by ultraviolet light (254 nm) to produce the chemical bond between SAM and polymer layer, followed by PCL polymer coating ({\sim}5\;{\mu}m$) by the method of spray coating. The surface change was investigated by measuring of contact angle of the surface. The contact angle values of stainless steel (SS) surface, $TiO_2$-coated surface, SAM layer by Ahx-HSAB, photoreacted surface with PCL and PCL layer by spray coating were 70.48${\pm}$1.89, 38.57${\pm}$3.31, 60.14${\pm}$2.21, 54.91${\pm}$2.70 and 56.47${\pm}$2.12, respectively. The stability of polymer layers was tested by incubation of PCL-coated plates in 0.1M PBS buffer (pH 7.4, 0.05%, Tween 80) with vigorous shaking (200 rpm). While the poiymer layer prepared by these processes showed the intact surface morphology over 3 days, the polymer layers prepared by spray coating of PCL onto SS plate (control 1) and $TiO_2$-coated SS plate (control 2) were Peeled off in 3 days. Thus, the polymer coating method using SAM and photoreaction seems to be a effective method to obtain the stable polymer layer onto SS surface.

고분자 물질 도포가 미생물 부착과 생물막 성장에 미치는 영향 (Effect of Polymer Coating on the Initial Microorganism Attachment and the Biofilm Growth)

  • 박영식;송승구
    • 한국환경보건학회지
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    • 제24권2호
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    • pp.104-109
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    • 1998
  • The objective of this study was to examine the effect of polymer coating on the initial microorganism attachment and the biofilm growth. Such as nonion(polyacrylamine), anion(CMC-Na) and cation polymer coagulant(chitosan and PEI) were used for coating material of the support carrier(acryl plate). When polymer coagulant was coated with 5, 10, 20, 35, 50, 100 and 200 mg/l on the surface of acryl plate, initial microorganism attachment increased and optimum concentration for the attachment was 35 mg/l. Biofilm growth experiments were conducted with the substrate loading of 12.7gSCOD/$m^2\cdot$ day using RBC. The polymer coagulants such as CMC-Na, polyacrylamide, PEI and chitosan coating on the acryl plate facilitated the biofilm growth of microorganisms. Until the biofilm dry weight grows up to 0. 0038g/cm$^2$, biofilm growth on the plate coated with cation polymer like chitosan was better than that on the coated plate of nonion(polyacrylamine), anion(CMC-Na) polymer coagulant.

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수성 폴리머 도료를 이용한 초음파 스프레이 공정으로 형성된 폴리머 절연층 미세구조 특성 (Morphology Characteristics of Insulating Laser based on Aqueous Polymer Resin Fabricated by Ultrasonic Spray Coating Process)

  • 유정모;박채원;엄현진
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2016년도 추계학술대회 논문집
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    • pp.136-136
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    • 2016
  • Commonly used oil-based polymer resin has environmental and safety issues. Many researches for replacing the harmful solvent-borne resins to water-borne resins have been investigated to purify harmful environmental resources and follow the export and import of hazardous materials regulations. In this research, ultrasonic spray coatings of aqueous polymer resin were studied to fabricate thin insulating layer (${\sim}{\mu}m$) on the rectangular copper wire. It needs to have appropriate wettability between resin and substrate during the ultrasonic spray coating process to coat aqueous polymer uniformly. Furthermore, stabilities of coating solution and fabricating process are required to form thin insulating layer on the substrate. In here, physical characteristics such as viscosity of 6 types of commercial polymer dispersions and emersions were analyzed to confirm compatibility for ultrasonic spray coating process. These resins were dissolved in isopropyl alcohol, used for true solvent, and were diluted with ethanol, utilized for diluent. Also, solubilities, dispersion characteristics, and viscosities of these diluted polymer resin solutions were confirmed. Dispersion characteristic and viscosity of coating solution affects jetting of ultrasonic spray coating and these jetting characteristics influence morphologies of insulating layer. In conclusion, we have known that aqueous polymer solution should have outstanding dispersion characteristic and certain range of viscosity to fabricate thin polymer insulating layer uniformly with ultrasonic spray coating.

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폴리머 시멘트 페이스트의 특성에 미치는 도포방법의 영향 (Effect of Coating Method on Properties of Polymer-Modified Paste)

  • 주명기;이윤수;김윤환;한정현
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.803-806
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    • 2005
  • The effect of coating method and binder content on the tensile adhesion strength, water absorption and cl- penetration depth of polymer-modified pastes using redispersible polymer powders and ceramic powder are examined. As a result, the tensile adhesion strength of the polymer-modified pastes tend to increase with increasing binder content and: number of coating. The water absorption and cl- penetration depth of the polymer-modified pastes tend to decrease with increasing binder content and number of coating.

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벼 종자의 Polymer 피복처리가 종자세에 미치는 영향 (Effects of Polymer Coating on Seed Vigour in Rice)

  • 이성춘;정춘화;김진희;송동석
    • 한국작물학회지
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    • 제41권3호
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    • pp.274-285
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    • 1996
  • Po1ymer를 피복한 벼 종자의 종자세 향상과 환경 적응성을 구명하기 위하여 10종의 Polymer를 피복하여 수분흡수력, 호흡량, 발아력 및 포장 출아율 등을 조사하였던 바 그 결과를 요약하면 다음과 같다. 1. Polymer피복 종자의 수분흡수율은 포화습도에서 klucel이 가장 높았고 PVP가 가장 낮았으며, 물에 침청할 때는 klucel이 가장 높았고 maltrin이 가장 낮았다. 2. Polymer 피복 종자의 호흡량은 화영벼 와 일품벼 에서 polymer 피복 종자가 낮았으나, 대청벼와 진미벼는 오히려 높았는데 그 정도는 sepiret 피복 종자가 PVP 피복 종자보다 높았다. 3. Polymer피복 과정 중 기계에 의한 종자피해 정도는 발아율이 1% 내외로 저하되어 극히 미미 하였다. 4. 종자세가 양호한 종자에서는 polymer 피복에의한 발아율의 향상은 없었으나 대부분이 95% 이상의 발아율을 보였고 waterlock, surelease 45 및 sepiret등이 특정 품종에서 발아율이 극히 저조하였다. 5. 발아세는 sepiret 피복으로 향상되었고, PVP 피복으로는 약간 저하하였다. 6. Polymer피복 후 노후화 처리 종자의 발아율은 대부분의 polymer에서 피복 종자가 무처리 종자에 비하여 약간 높았으나 sepiret과klucel피복한 종자의 발아율은 현저하게 저하하였다. 7. 저온 발아성은 daran 8600, maltrin, sacrust 및 opadry 등에서는 향상되었고 나머지 polymer는 저해하였는데, 특히 PVP의 발아율이 가장 낮았다. 8. 초장은 대부분의 polymer 피복 종자에서 컸으나 watelock, PVP, maltrin등의 Polymer에서는 작았다. 저온 발아시 초장은 polymer피복으로 오히려 단축되었다. 9. 포장 출아율은 피복 종자가 훨씬 높았으며 출아 소요시간도 훨씬 단축되었다. 포장수분함량 90 %에서 출아율이 가장 양호하였고 출아 소시간도 단축되었으며, 95년 종자가 94년 종자보다도 출아률이 높았고 출아시간도 단축되었다. PVP가 sepiret보다 더 양호한 출아율을 나타냈다.

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Microbial Inhibition and Migration of Nisin-incorporated Antimicrobial Polymer Coating on Paperboard

  • Kim, Young-Min;Lee, Dong-Sun
    • 한국포장학회지
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    • 제16권1호
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    • pp.5-7
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    • 2010
  • Two kinds of polymer coating (acrylic polymer and vinyl acetate ethylene copolymer) added with 5% nisin were fabricated on the paperboards and tested in their antimicrobial activity against Micrococcus flavus ATCC 10240 inoculated into water contacting the coating at $10^{\circ}C$. Vinyl acetate ethylene copolymer giving faster and higher nisin migration presented the greater reduction in the microbial count than the other coating, which endorsed that the migrated nisin is mainly responsible for the microbial inhibition or destruction. There was also a slight effect of the coating polymer itself in the microbial inhibition.

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Conformation of single polymer molecule in a slot coating flow

  • Lee, Jeong-Yong;Ryu, Bo-Kyung;Lee, Joo-Sung;Jung, Hyun-Wook;Hyun, Jae-Chun
    • Korea-Australia Rheology Journal
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    • 제20권2호
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    • pp.89-94
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    • 2008
  • To satisfy good mechanical and optical properties of polymer-coated film products, it will be indispensable to elucidate the molecular orientation of polymer chains within coating liquids in coating flows. Using hybridized numerical method between computational fluid dynamics (CFD) and Brownian dynamics (BD) simulations can provide the useful information for the better quality control of coated films. Flexible polymer chains, e.g., ${\lambda}$-DNA molecules here, change their conformation according to the flow strength and the flow type. The molecular conformation within the coated film on the web or substrate is quite different, because the polymer chains experience the complicated flow strength and flow types in flow field. Especially in the slot coating flow, these chains are more extended by the extension-like flow field generated in the free surface curvature just beyond the downstream die region. Also, the polymer chain extension beneath the free surface can be affected by the die geometry, e.g., the coating gap, changing flow field.