• Journal of the Computational Structural Engineering Institute of Korea
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• v.26 no.6
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• pp.423-430
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• 2013

In this research, a paramteric study to account for the effect of interfacial strength and nanotube agglomeration on the elastoplastic behavior of carbon nanotube reinforced polypropylene composites is performed. At first, the elastoplastic behavior of nanocomposites is predicted from molecular dynamics(MD) simulations. By combining the MD simulation results with the nonlinear micromechanics model based on the Mori-Tanaka model, a two-step domain decomposition method is applied to inversely identify the elastoplastic behavior of adsorption interphase zone inside nanocomposites. In nonlinear micromechanics model, the secant moduli method combined with field fluctuation method is used to predict the elastoplastic behavior of nanocomposites. To account for the imperfect material interface between nanotube and matrix polymer, displacement discontinuity condition is applied to the micromechanics model. Using the elastoplastic behavior of the adsorption interphase zone obtained from the present study, stress-strain relation of nanocomposites at various interfacial bonding condition and local nanotube agglomeration is predicted from nonlinear micromechanics model with and without the adsorption interphase zone. As a result, it has been found that local nanotube agglomeration is the most important design factor to maximize reinforcing effect of nanotube in elastic and plastic behavior.

• Magazine of the Korea Concrete Institute
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• v.6 no.2
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• pp.97-107
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• 1994

The objective of this study is to develop polymer-impregnated concrete(PIC), which is a newly developed composite material made by impregnating polymer impregnanls into hardened normal concrete, and to develop analytical techniques for its proper applications. Crystalline methyl methacrylate(MMA) is chosen as a monomer of polymer impregnants. The corrlpositions of polymer impregnants and producing processes are developed by analyzing the effects of penetration, polymerization, thermal safety, and strengthening characteristics. On t he basis of experimental results of this study, various strength characteristics and stress strain constitutive relations are formulated in terms of the compressive strength of normal concrete and the polymer loadings, which can be applied for analysis and design of PIC members. In order to provide a model for fracture analysis of flexural members, fracture toughness, fracture energy, critical crack width, and tension softening relations near crack tip are also formulated in terms of member depth, initial notch depth, and the flexural strength of normal concrete. The structural analysis procedure and the finite element computer program developed in the study are applicable to evaluate elastic behavior, ultimate strength, and tension softening behavior of MMA type PIC structural members subject to various loading conditions. The accuracy and effectiveness of the developed computer program is examined by comparing the anal ytical results with the experimental results. Therefore, it is concluded that the developed structural analysis procedure and the finite element computer program are applicable to analysis and design of in-situ and precast PIC structural members.

• Elastomers and Composites
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• v.31 no.5
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• pp.327-334
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• 1996

A correlative analysis has been carried out to predict the average particle size of rubber dispersed phase In high impact polystyrene manufactured by bulk polymerization. To do the correlation, a mechanistic model suggested previously by the author was used for describing the size of stabilizing particles agitated under the turbulent viscous shear subranges in a prepolymerization reactor, where the rubber particles were assumed to be formed at the time of phase inversion in the reactor. Viscosities required for the model were postulated to describe the overall behavior of butadiene rubber and polystyrene mixture along the wide range of conversion. The good agreement between the model and the experimental data from a plant was quite satisfactory for the prediction of the average rubber particle size of high impact polystyrene.

• KSBB Journal
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• v.6 no.1
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• pp.79-83
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• 1991

Using PHB biopolymer as polymer matrix, the release mechanism of a model drug, silver sulfadiazine was studied. The release behavior actually conformed to the Higuchi's diffusion controlled model. The release rate was delayed with an increasing proportion of PHB, whereas decreased as glycerine concentration incresed. The release rate was increased as the polymer matrix thickness increased.

• Biotechnology and Bioprocess Engineering:BBE
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• v.6 no.5
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• pp.326-331
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• 2001

With the aim of developing of pH-sensitive controlled drug release system, a poly(Llysine) (PLL) based cationic semi-interpenetrating polymer network (semi-IPN) has been synthesized. This cationic hydrogel was designed to swell at lower pH and de-swell at higher pH and therefore be applicable for achieving regulated drug release at a specific pH range. In addition to the pH sensitivity, this hydrogel was anticipated to interact with an ionic drug, providing another means to regulate the release rate of ionic drugs. This semi-IPN hydrogel was prepared using a free-radical polymerization method and by crosslinking of the polyethylene glycol (PEG)-methacrylate polymer through the PLL network. The two polymers were penetrated with each other via interpolymer complexation to yield the semi-IPN structures. The PLL hydrogel thus prepared showed dynamic swelling/de-swelling behavior in response to pH change, and such a behavior was influenced by both the concentrations of PLL and PEG-methacrylate. Drug release from this semi-IPN hydrogel was also investigated using a model protein drug, streptokinase. Streptokinase release was found to be dependent on its ionic interaction with the PLL backbones as well as on the swelling of the semi-IPN hydrogel. These results suggest that a PLL semi-IPN hydrogel could potentially be used as a drug delivery platform to modulate drug release by pH-sensitivity and ionic interaction.

• Macromolecular Research
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• v.13 no.5
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• pp.397-402
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• 2005

To explore the potential of shell crosslinked micelle (SCM) as a drug carrier, the drug release behavior of poly($\varepsilon$-caprolactone)-b-poly(acrylic acid) (PCL-b-PAA) SCMs was investigated. PCL-b-PAA was synthesized by ring opening polymerization of $\varepsilon$-caprolactone and atom transfer radical polymerization of tert-butyl acrylate, followed by selective hydrolysis of tert-butyl ester groups to acrylic acid groups. The resulting amphiphilic polymer was used to prepare SCMs by crosslinking of PAA corona via amidation chemistry. The drug release behavior of the SCMs was studied, using pyrene as a model drug, and was compared with that of non-crosslinked micelles, especially below the critical micelle concentration (CMC). When the shell layers were crosslinked, the drug release behavior of the SCMs was successfully modulated at a controlled rate compared with that of the non-crosslinked micelles, which showed a burst release of drug within a short time.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.40 no.5
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• pp.20-26
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• 2008

Behavior of micro stickies was analyzed using model micro stickies prepared with PVAc emulsion adhesive. Flocculation of micro stickies increased with temperature. Acidic state also induced greater flocculation of micro stickies since they became more unstable under these conditions. Flocculation of micro stickies increased as calcium ion concentration increased. But the presence of calcium carbonates made micro stickies dispersed indicating that calcium carbonates cause two different effects on the behavior of micro stickies. Talc increased flocculation of micro stickies because of its hydrophobic nature. Cationic polymer increased flocculation of micro stickies. Especially cationic starch has far greater effect in flocculating sticky particles by forming bridging flocculations.

• Advances in concrete construction
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• v.5 no.6
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• pp.625-638
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• 2017

The flexural behavior of Fiber reinforced polymer (FRP) sheets has gained much research interest in the flexural strengthening of reinforced concrete beams. The study on flexure includes various parameters like increase in strength of the member due to the externally bonded (EB) Fiber reinforced polymer, crack patterns, debonding of the fiber from the structure, scaling, convenience of using the fibers, cost effectiveness, etc. The present work aims to study experimentally about the reasons behind the failure due to flexure of an externally bonded FRP concrete beam. In the design of FRP-reinforced concrete structures, deflection control is as critical as much as flexural strength. A numerical model is created using Finite element (FEM) software and the results are compared with that of the experiment.

• Journal of the Korea Concrete Institute
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• v.16 no.6 s.84
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• pp.767-776
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• 2004

Polymer concrete shows excellent mechanical properties and chemical resistance compared with conventional normal cement concrete. The polymer concrete is drawing a strong interest as high-performance materials in the construction industry. Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems posed by plastics and save energy. The purposed of this paper is to propose the model for the stress-strain relation of recycled-PET polymer concrete at monotonic uniaxial compression and is to investigate for the stress-strain behavior characteristics of recycled-PET polymer concrete with different variables(strength, resin contents, curing conditions, addition of silane and ages). The maximum stress and strain of recycled-PET polymer concrete was found to increase with an increase in resin content, however, it decreased beyond a particular level of resin content. A ascending and descending branch of stress-strain curve represented more sharply at high temperature curing more than normal temperature curing. Addition of silane increases compressive strength and postpeak ductility. In addition, results show that the proposed model accurately predicts the stress-strain relation of recycled-PET polymer concrete

• Macromolecular Research
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• v.15 no.6
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• pp.547-552
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• 2007

Water soluble polymer, poly(vinyl pyrrolidone) was chosen to conjugate with 1,2-dioleoyl-sn-glycero-3-phosphoethanolamine-N-(succinyl) (N-succinyl DPPE) to make a new drug delivery system. PVP with an amine group (amino-PVP) was polymerized by free radical polymerization. The amine group of amino-PVP was conjugated with the carboxylic group of N-succinyl DPPE. The resultant conjugate could form nanoparticles in the aqueous solution; these nanoparticles were termed a lipid-polymer system. The critical aggregation concentration was measured with pyrene to give a value of $1{\times}10^{-3}g/L$. The particle size of the lipid-polymer system, as measured by DLS, AFM and TEM, was about 70 nm. Lipophilic component in the inner part of the lipid-polymer system could derive the physical interaction with hydrophobic drugs. Griseofulvin was used as a model drug in this study. The loading efficiency and release profile of the drug were measured by HPLC. The loading efficiency was about 54%. The release behavior was sustained for a prolonged time of 12 days. The proposed lipid-polymer system with biodegradable and biocompatible properties has promising potential as a passive-targeting drug delivery carrier because of its small particle size.