• Steel and Composite Structures
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• v.20 no.5
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• pp.999-1022
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• 2016

The use of Carbon Fiber Reinforced Polymer (CFRP) to strengthen steel structures has attracted the attention of researchers greatly. Previous studies demonstrated bonding of CFRP plates to the steel sections has been a successful method to increase the mechanical properties. However, the main limitation to popular use of steel/CFRP strengthening system is the concern on durability of bonding between steel and CFRP in various environmental conditions. The paper evaluates the performance of I-section steel beams strengthened with pultruded CFRP plate on the bottom flange after exposure to diverse conditions including natural tropical climate, wet/dry cycles, plain water, salt water and acidic solution. Four-point bending tests were performed at specific intervals and the mechanical properties were compared to the control beam. Besides, the ductility of the strengthened beams and distribution of shear stress in adhesive layer were investigated thoroughly. The study found the adhesive layer was the critical part and the performance of the system related directly to its behavior. The highest strength degradation was observed for the beams immersed in salt water around 18% after 8 months exposure. Besides, the ductility of all strengthened beams increased after exposure. A theoretical procedure was employed to model the degradation of epoxy adhesive.

• Microbiology and Biotechnology Letters
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• v.23 no.3
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• pp.269-274
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• 1995

For the screening of a new functional exopolysaccharide, sugar composition and rheological properties of exopolysaccharide produced from Xanthomonas sp. EPS-1 were investigated. The average molecular weight of exopolysaccharide was determined to be approximately 2.l $\times$ 10$^{6}$ dalton. The new exopolysaccharide EPS-1 was composed of mannose, glucose, galactose and gluco- samine. IR analysis showed that the exopolysaccharide EPS-1 was assumed to be polymer with carbohydrates. NMR analysis showed that exopolysaccharide EPS-1 was presumed to be 4 units of sugar and trace of CH$_{3}$ group. Exopolysaccharide EPS-1 solution showed a characteristic of non-Newtonian fluid properties. At the concentration of 1.0%, the consistency index and the flow behavior index were shown at 10.8352 poise-sec and 0.4419, respectively. All dispersions were pseudoplastic fluids described accurately by Power-law model. Exopolysaccharide EPS-1 was highly viscous at low concentration, with good stability over a wide range of pH 5 to 13. The excellent compatibility of exopolysaccharide EPS-1 was represented with salts such as sodium chloride.

• Korean Journal of Food Science and Technology
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• v.29 no.5
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• pp.932-938
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• 1997

Changes in viscosity and dynamic theological properties of Job's-tears were measured by Bohlin dynamic tester as a function of moisture, and measurement was performed within a linear viscoelastic range. The result of the shear stress vs shear rate of Job's-tears at different moisture contents $(50{\sim}75%)$ was applied to mathematical models and Herschel-Bulkley model showed the highest correlation coefficient. Lower moisture content (55%) produced higher yield stress and consistency index, but lower flow behavior index, whereas higher moisture content showed reverse effects. Job's-tears with $50{\sim}70%$ moisture contents showed a higher storage modulus (G') than loss modulus (G') at all frequencies, showing a higher concentrated polymer characteristics. However, higher moisture content (>75%) showed crossover point between G' and G', and frequency dependency. As the moisture content was increased, the amount of viscoelastic properties such as G', G', complex viscosity decreased during heating, and initial temperature and miximum value of viscoelastic properties shifted to higher temperatures, representing the moisture-dependence of Job's-tears upon theological properties.

• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.200-204
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• 2008

The curing kinetics of diglycidyl ether of bisphenol F (DGEBF) with an asymmetric cycloaliphatic amine curing agent were examined by thermal analysis in both isothermal and dynamic curing conditions. From the residual curing of the samples partially cured in isothermal condition and from the dynamic curing with various heating rates, it was found that there exist two kinds of reactions such as at low temperature and at high temperature regions. It was thus also found that the cure parameters obtained from the isothermal curing kinetic model hardly estimate experimental results for a degree of cure larger than 0.6. The activation energies and frequency factors of these two kinds of reactions were obtained from the dynamic curing experiments with various heating rates. From the curing analysis, it was verified that the total cure kinetics for low degrees of cure is dominated by the cure reaction in the low temperature region.

• ETRI Journal
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• v.36 no.4
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• pp.654-661
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• 2014

We develop accurate finite-difference time-domain (FDTD) modeling of polymer bulk heterojunction solar cells containing Ag nanoparticles between the hole-transporting layer and the transparent conducting oxide-coated glass substrate in the wavelength range of 300 nm to 800 nm. The Drude dispersion modeling technique is used to model the frequency dispersion behavior of Ag nanoparticles, the hole-transporting layer, and indium tin oxide. The perfectly matched layer boundary condition is used for the top and bottom regions of the computational domain, and the periodic boundary condition is used for the lateral regions of the same domain. The developed FDTD modeling is employed to investigate the effect of geometrical parameters of Ag nanospheres on electromagnetic fields in devices. Although negative plasmonic effects are observed in the considered device, absorption enhancement can be achieved when favorable geometrical parameters are obtained.

• Macromolecular Research
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• v.12 no.3
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• pp.293-302
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• 2004

We added surface-modified silica nanoparticles to poly(ethylene 2,6-naphthalate) (PEN) to investigate their effect on the mechanical properties on the PEN nanocomposite material. The torque and total torque values of the composites decreased in the silica nanoparticle composites. The tensile modulus of the composites reinforced with unmodified silica nanoparticles increased upon increasing the silica content, while the tensile strength and elongation decreased accordingly. In contrast, stearic acid-modified, silica nanoparticle reinforced PEN composites exhibited an increase in elongation and a decrease in tensile modulus upon addition of the silica nanoparticles because the stearic acid that had adsorbed onto the surface of the silica nanoparticle in multilayers could act as a plasticizer during melt compounding. Stearic acid modification had a small effect on the crystallization behavior of the composites. We calculated theoretical values of the tensile modulus using the Einstein, Kerner, and Nielsen equations and compared these values with the experimental data obtained from the composites. The parameters calculated using the Nielsen equation and the Nicolais- Narkis model revealed that the interfacial adhesion between silica nanoparticles and the PEN matrix could be improved.

• Membrane Journal
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• v.32 no.1
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• pp.50-56
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• 2022

In this work, the solvent permeation and separation performance of organic solvent nanofiltration (OSN) membranes were evaluated. Particularly, the PuraMem (PM) series developed for nonpolar solvents were analyzed and tested in dead-end filtration system. PM membranes exhibited higher permeance for nonpolar solvents compared to polar solvents, and their rejection data did not follow conventional trends with respect to solute size. The data showed that simple solution-diffusion model is not suitable to describe the OSN membrane behavior, and a better solvent-solute-membrane interaction parameter must be developed.

• Steel and Composite Structures
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• v.49 no.4
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• pp.393-405
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• 2023

In this paper, the energy absorption capability of a novel cruciform composite lattice structure was evaluated through the simulation of compression tests. For this purpose, several test samples of Polylactic acid cellular reinforced with continuous glass fibers were prepared for compression testing using the additive manufacturing method of material extrusion. Using a conventional path design for material extrusion, multiple debonding is probable to be occurred at the joint regions of adjacent cells. Therefore, an innovative printing path design was proposed for the cruciform lattice structure. Afterwards, quasistatic compression tests were performed to evaluate the energy absorption behaviour of this structure. A finite element model based on local material property degradation was then developed to verify the experimental test and extend the virtual test method. Accordingly, different combinations of unit cells' dimensions using the design of the experiment were numerically proposed to obtain the optimal configuration in terms of the total absorbed energy. Having brilliant energy absorption properties, the studied cruciform lattice with its optimized unit cell dimensions can be used as an energy absorber in crashworthiness applications. Finally, a cellular structure will be suitable with optimal behavior in crush load efficiency and high energy absorption.

• Macromolecular Research
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• v.16 no.2
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• pp.139-148
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• 2008

Biodegradable and elastic poly(L-lactide-co-$\varepsilon$-caprolactone) (PLCL) was electrospun to prepare nanofibers, and N-isopropylacrylamide (NIPAAm) was then grafted onto their surfaces under aqueous conditions using $^{60}Co-{\gamma}$ irradiation. The graft yield increased with increasing irradiation dose from 5 to 10 kGy and the nanofibers showed a greater graft yield compared with the firms. SEM confirmed that the PLCL nanofibers maintained an interconnected pore structure after grafting with NIPAAm. However, overdoses of irradiation led to the excessive formation of homopolymer gels on the surface of thc PLCL nanofibers. The equilibrium swelling and deswelling ratio of the PNIPAAm-g-PLCL nanofibers (prepared with 10 kGy) was the highest among the samples, which was consistent with the graft yield results. The phase-separation characteristics of PNIPAAm in aqueous conditions conferred a unique temperature-responsive swelling behavior of PNIPAAm-g-PLCL nanofibers, showing the ability to absorb a large amount of water at < $32^{\circ}C$, and abrupt collapse when the temperature was increased to $40^{\circ}C$. In accordance with the temperature-dependent changes in swelling behavior, the release rate of indomethacin and FITC-BSA loaded in PNIPAAm-g-PLCL nanofibers by a diffusion-mediated process was regulated by the change in temperature. Both model drugs demonstrated greater release rate at $40^{\circ}C$ relative to that at $25^{\circ}C$. This approach of the temperature-controlled release of drugs from PNIPAAm-g-PLCL nanofibers using gamma-ray irradiation may be used to design drugs and protein delivery carriers in various biomedical applications.

• Computers and Concrete
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• v.24 no.1
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• pp.73-83
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• 2019

Concrete reinforced with fiber reinforced polymer (FRP) bars (FRP-RC) has attracted a significant amount of research attention in the last three decades. A limited number of studies, however, have investigated the effect of bond slip on the performance of FRP-RC columns under eccentric loading. Based on previous experimental study, a finite-element model of eccentrically loaded FRP-RC columns was established in this study. The bondslip behavior was modeled by inserting spring elements between FRP bars and concrete. The improved Bertero-Popov-Eligehausen (BPE) bond slip model with the results of existing FRP-RC pullout tests was introduced. The effect of bond slip on the entire compression-bending process of FRP-RC columns was investigated parametrically. The results show that the initial stiffness of bond slip is the most sensitive parameter affecting the compression-bending performance of columns. The peak bond stress and the corresponding peak slip produce a small effect on the maximum loading capacity of columns. The bondslip softening has little effect on the compression-bending performance of columns. The sectional analysis revealed that, as the load eccentricity and the FRP bar diameter increase, the reducing effect of bond slip on the flexural capacity becomes more obvious. With regard to bond slip, the axial-force-bending-moment (P-M) interaction diagrams of columns with different FRP bar diameters show consistent trends. It can be concluded from this study that for columns reinforced with large diameter FRP bars, the flexural capacity of columns at low axial load levels will be seriously overestimated if the bond slip is not considered.