• Title/Summary/Keyword: Polymer Sheet

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Functional Modification of Sanitary Nonwoven Fabrics by Chitosan Treatment (Part II) -Focused on Changes in Physical Properties- (키토산 처리에 의한 위생용 부직포의 기능성 개질화 (제2보) -물성 변화를 중심으로-)

  • Bae, Hyun-Sook;Kang, In-Sook;Park, Hye-Won;Ryou, Eun-Jeong;Kwon, Jay-Cheol
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.12
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    • pp.1662-1671
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    • 2007
  • The change in physical properties of polypropylene nonwoven fabrics used as top sheet for disposable sanitary goods was carried out using chitosan that is a type of natural polymer and has excellent human affinity by varying the molecular weight and concentration of chitosan. Low molecular weight(LMW) chitosan treated fabrics were found to be evenly coated on fabrics and had better dyeability by apparent dye uptake and its deodorization rate increased over the time. On the other hand, high molecular weight(HMW) chitosan treated fabrics showed higher add-on ratio and its dynamic water absorption rate and represented an increase in water transport rate. With chitosan treatment, its air permeability was improved. Regardless of the type of bacteria and chitosan concentration, its antibacterial activity was excellent in the case of the HMW chitosan treatment. In this regard, chitosan treatments by using a relatively high molecular weight was found as an effective way in the functional improvement of moisture properties and antibacterial activity including their most important performance in sanitary nonwoven fabrics.

Physicochemical Characteristics and Efficacy of Controlled-release Insecticide Formulation (방출조절형(放出調節型) 살충성(殺蟲性) 농약제제(農藥製劑)의 특성(特性)과 약효(藥效)에 관한 연구(硏究))

  • Kim, Jin-Hwa;Oh, Byung-Youl;Oh, Kyeong-Seok;Kim, Sung-Kee;Kim, Mee-Hea;Kim, Young-Koo
    • Korean Journal of Environmental Agriculture
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    • v.14 no.3
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    • pp.289-295
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    • 1995
  • This study was carried out to develop a controlled-release insecticide formulation for the control of rose aphid (Macrosiphum ibarae) in rose and cotton aphid (Myzus persicae) in chrysanthemum (Dendranthema grandiflorum var. Meibung) in greenhouse. Imidacloprid[1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine] was chosen as a toxicant. Two synthetic polymers, low density polyethylene(LDPE) and ethylene vinyl acetate(EVA), were used as polymer matrices. The tested plastic sheet formulations were prepared by heat-aided extrusion procedures after mixing imidacloprid technical and the polymers of three different combinations, and physicochemical properties as well as efficacy of the formulations were investigated. The amounts of imidacloprid recovered and incorporated in the formulations were recorded over 90% and 80%, respectively. Release of the active ingredient from the formulations was remarkably affected by mixing rates of polymers. The active ingredient in the formulations was chemically unstable with over 10% degradation rates after 90 day storage at $50{\pm}2^{\circ}C$. The residual amounts of imidacloprid in the soil treated with the formulations were paralleled with the release pattern of the formulations. Efficacy of the formulations on rose and cotton aphid was maintained over 90% even 120days after treatment under greenhouse.

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Flexural Performance of Slabs Strengthened by Fiber-Reinforced Polymer Sheet with Hydrophilic Epoxy (친수성 에폭시를 사용하여 FRP 시트로 보강된 슬래브의 휨거동 평가)

  • Ju, Hyunjin;Han, Sun-Jin;Cho, Hae-Chang;Lee, Deuck Hang;Kim, Kang Su
    • Journal of the Korea Concrete Institute
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    • v.28 no.1
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    • pp.85-94
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    • 2016
  • In this study, the hydrophilic chemical grout using silanol (HCGS) was introduced to overcome the limitations of conventional epoxy resin which have been used for strengthening reinforced concrete (RC) structures. Then, flexural tests on the RC slabs strengthened by FRP sheets were conducted. Three slab specimens were tested in this study; a control specimen with no strengthening, and two specimens strengthened by a typical epoxy resin or HCGS, respectively, as a binder between the slabs and the FRP sheets. In addition, an analytical model was developed to evaluate the flexural behavior of strengthened slab members, considering the horizontal shear force at the interface between concrete slabs and FRP sheets. The analysis results obtained from the proposed model indicated that the strengthened specimens showed fully composite behavior before their flexural failure. Especially, the specimen strengthened by HCGS, which can overcome the limitations of conventional epoxy resin, showed a similar flexural performance with that strengthened by a conventional epoxy resin.

A Printing Process for Source/Drain Electrodes of OTFT Array by using Surface Energy Difference of PVP (Poly 4-vinylphenol) Gate Dielectric (PVP(Poly 4-vinylphenol) 게이트 유전체의 표면에너지 차이를 이용한 유기박막트랜지스터 어레이의 소스/드레인 전극 인쇄공정)

  • Choi, Jae-Cheol;Song, Chung-Kun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.48 no.3
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    • pp.7-11
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    • 2011
  • In this paper, we proposed a simple and high-yield printing process for source and drain electrodes of organic thin film transistor (OTFT). The surface energy of PVP (poly 4-vinylphenol) gate dielectric was decreased from 56 $mJ/m^2$ to 45 $mJ/m^2$ by adding fluoride of 3000ppm into it. Meanwhile the surface energy of source and drain (S/D) electrodes area on the PVP was increased to 87 $mJ/m^2$ by treating the areas, which was patterned by photolithography, with oxygen plasma, maximizing the surface energy difference from the other areas. A conductive polymer, G-PEDOT:PSS, was deposited on the S/D electrode areas by brushing painting process. With such a simple process we could obtain a high yield of above 90 % in $16{\times}16$ arrays of OTFTs. The performance of OTFTs with the fluoride-added PVP was similar to that of OTFTs with the ordinary PVP without fluoride, generating the mobility of 0.1 $cm^2/V.sec$, which was sufficient enough to drive electrophoretic display (EPD) sheet. The EPD panel employing the OTFT-backpane successfully demonstrated to display some patterns on it.

Property of Nickel Silicides on ICP-CVD Amorphous Silicon with Silicidation Temperature (ICP-CVD 비정질 실리콘에 형성된 처리온도에 따른 저온 니켈실리사이드의 물성 변화)

  • Kim, Jong-Ryul;Choi, Young-Youn;Park, Jong-Sung;Song, Oh-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.2
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    • pp.303-310
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    • 2008
  • We fabricated hydrogenated amorphous silicon(a-Si:H) 140 nm thick film on a $180\;nm-SiO_2/Si$ substrate with an inductively-coupled plasma chemical vapor deposition(ICP-CVD) equipment at $250^{\circ}C$. Moreover, 30 nm-Ni film was deposited with a thermal-evaporator sequently. Then the film stack was annealed to induce silicides by a rapid thermal annealer(RTA) at $200{\sim}500^{\circ}C$ in every $50^{\circ}C$ for 30 minuets. We employed a four-point tester, high resolution X-ray diffraction(HRXRD), field emission scanning electron microscope(FE-SEM), transmission electron microscope(TEM), and scanning probe microscope(SPM) in order to examine the sheet resistance, phase transformation, in-plane microstructure, cross-sectional microstructure evolution, and surface roughness, respectively. We confirmed that nano-thick high resistive $Ni_3Si$, mid-resistive $Ni_2Si$, and low resistive NiSi phases were stable at the temperature of <300, $350{\sim}450^{\circ}C$, and >$450^{\circ}C$, respectively. Through SPM analysis, we confirmed the surface roughness of nickel silicide was below 12 nm, which implied that it was superior over employing the glass and polymer substrates.

Theoretical Analysis for Strengthening Effects of RC Beam with Reinforced FRP Sheet (FRP 시트로 보강된 RC 보의 보강 효과에 대한 이론적 분석)

  • Ha, Sang-Su
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.4
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    • pp.100-107
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    • 2018
  • The objective of this study is to assess the strengthening effects of fiber reinforced polymer(FRP) sheets such as Carbon fiber, Glass fiber, and PET(polyethylene terephthalate) on reinforced concrete flexural members. Variables of theoretical analysis are types of strengthening materials, material properties and amount of strengthening materials. A virtual flexural member without FRP sheets was created as a control specimen to understand the structural behavior of the non-strengthened specimen in terms of elastic and ultimate cross section. In total, 11 specimens including one non-strengthened and ten strengthened specimens were investigated. Various variables such as types of strengthening, strengthening properties, and amount of strengthening were studied to compare the behavior of the control specimen with those of strengthened specimens with regard to moment-curvature relationship. Results of theoretical analysis showed that the moment capacity of strengthened specimens was superior to that of the control specimen. However, the control specimen indicated the best ductility among all the specimens. As the amount of strengthening increased, flexural performance was improved. Furthermore, the results indicated that the ductile effect of members was affected by the ultimate strain of FRP sheets. The strengthening effect on the damaged member was similar to that on the non-damaged one since there was less than 10% difference in terms of flexural strength and ductility. Therefore, even if a damaged member is treated as non-damaged for analysis there is probably no noticeable difference.

Properties of Nanocomposites Based on Polymer Blend Containing PVDF, Carbon Fiber and Carbon Nanotube (PVDF를 포함한 고분자 블렌드와 탄소섬유/탄소나노튜브를 이용한 복합재료의 특성)

  • Kim, Jeong Ho;Son, Kwonsang;Lee, Minho
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.14-19
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    • 2014
  • Nanocomposites based on poly(methyl methacrylate) (PMMA)/poly(vinylidene fluoride) (PVDF) and poly(ethylene terephthalate) (PET)/(PVDF) blended with carbon fibers (CF) and carbon nanotube (CNT) were prepared by melt mixing in the twin screw extruder. Morphologies of the PMMA/PVDF/CF/CNT and PET/PVDF/CF/CNT nanocomposites were investigated using SEM. The aggregation of CNT was observed in PMMA/PVDF/CF/CNT nanocomposites while the good dispersion of CNT was shown in PET/PVDF/CF/CNT nanocomposites. In SEM image of PET/PVDF/CF/CNT nanocomposite, the CNT were mainly located at the PET domain of phase-separated PET/PVDF blend due to the ${\pi}-{\pi}$ interaction between the phenyl ring of PET and graphite sheet of the CNT's surface. In addition, a fairly good compatibility between PET/PVDF matrix and CF was shown in the SEM image. In the case of PET/PVDF nanocomposites blended with the co-addition of CF and CNT, the volume electrical resistivity decreased while no change was observed in PMMA/PVDF/CF/CNT composites. The degree of CNT dispersion in morphology results was consistent with the electrical conductivity results. From the DSC results, the crystallization temperature (Tc) of PET/PVDF/CF/CNT nanocomposites increased due to the co-addition of CF and CNTs acting as a nucleating agent. Flexural modulus of PET/PVDF/CF/CNT were sharply enhanced due to increasing the interaction between PET and CF.