• 제목/요약/키워드: Polymer LED

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Preparation of Hybrid Proton Conductor by Sol-Gel Process from Nafion Solution

  • Kim, Sang-Ock;Kim, Jeong-Soo
    • Macromolecular Research
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    • v.10 no.3
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    • pp.174-177
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    • 2002
  • Proton-conducting hybrid materials composed of silica and Nafion polymer were prepared from the sol-gel synthesis of silica in aqueous Nafion solution. The compositions of hybrid proton conductors were adjusted with the changing ratios of tetraethyl orthosilicate to Nafion. The thermal analysis, FTIR, SEM, and X-ray diffraction studies have proved the formation of Nafion/silica hybrid materials and no remarkable phase separation was observed, which led to an assumption that the macromolecular chain of silica and Nafion was homogeneously interlaned.

Performance Improvement of Polymer Light Emitting Diodes by Insertion of a Silane Layer

  • Lee, Jun-Yeob
    • Journal of Information Display
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    • v.8 no.3
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    • pp.1-4
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    • 2007
  • The influence of a silane layer on the performances of polymer light emitting diode(pLED)s has been studied. Glycidoxypropyltrimethoxysilane(GPS) with an epoxy functional group was used as a surface modifier for ITO substrates. The GPS layer was inserted between an ITO and a poly(3,4)-ethylenedioxythiophene/polystyrenesulfonate(PEDOT) by wet process and the performances of PLEDs were investigated. The introduction of GPS layer increased the brightness and efficiency of PLEDs by 30%. In addition, the lifetime of PLEDs was also improved considerably by using GPS as a surface modifier.

Comparative Analysis of Thermal Dissipation Properties to Heat Sink of Thermal Conductive Polymer and Aluminum Material (열전도성 고분자와 Al재질의 Heat Sink 방열 성능 비교 분석)

  • Choi, Doo-Ho;Choi, Won-Ho;Jo, Ju-Ung;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.2
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    • pp.137-141
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    • 2015
  • The purpose of this study is examining thermal dissipation materials for the lighting and radiate efficiency improvement of 8W LED and confirming the properness of the thermal dissipation materials for LED heat sink. Solid Works flow simulation on 8W class COB was done based on the material characteristics of thermal conductive polymer materials. According to the result of simulation, Al had better thermal dissipation performance than PET. Highest temperature was $7.6^{\circ}C$ higher while lowest temperature was $7.8^{\circ}C$ lower. The test on the heat sinks made by the materials, highest temperature was $4.1^{\circ}C$ higher and lowest temperature was $3.9^{\circ}C$ lower. It is possible to confirm that Al heat sink has better thermal dissipation efficiency because it has better dispersion of heat generated at junction temperature and less heat cohesion. The weight of PET heat sink was reduced than Al heat sink by 46.9% by the density difference between Al and PET. In conclusion, thermal dissipation performance of thermal conductive polymer is lower than Al material however, it is possible to lighting heat sink because thermal conductive polymer has better formability, has lower specific weight and enables various design options.

Improvement of PLED Efficiency by Post-annealing Process

  • Seo, Jun-Seon;Kim, Jae-Hyun;Hong, Seok-Min;Kang, Byoung-Ho;Kim, Do-Eok;Kim, Hak-Rin;Kang, Shin-Won
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.846-849
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    • 2009
  • In this study, we manufactured polymer-LED using light emitting copolymer as the active layer. After cathode layer deposition, we did post-annealing at $150^{\circ}C$ during 10 min in $N_2$ glove box. Then, we confirmed that the efficiency of the device was significantly enhanced by post annealing process. Its value was increased from 0.18(cd/A) to 1.32(cd/A), approximately 7 times. This phenomenon is a result of improved stability between polymer and metal cathode for injection of electrons as the contact density increases.

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Synthesis of Conjugated Copolymers with phenothiazine and Azomethine Units and their Electro-Optic Properties

  • Seo, Hyeon-Jin;Jang, Byeung-Jo;Chang, Jin-Gyu;Park, Lee-Soon
    • Journal of Information Display
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    • v.2 no.4
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    • pp.8-14
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    • 2001
  • Three types of conjugated polymers, poly(PZ-Pi), poly(PZ-BPI) and poly(PZ-NPI) were synthesized by Schiff-base reaction. These new conjugated polymers exhibited improved solubility in common organic solvents due to the presence of alkyl side chains as well as azomethine groups, Double layer LEDs made with the synthesized polymers as emitting layer and $Alq_3$, as electron transporting layer exhibited enhanced EL emission and efficiency compared to those of single layer LEDs. Double layer LEDs exhibited gradual shift in the emission peak th the single layer LED, made of only $Alq_3$ as the emitting layer as the thickness of $Alq_3$ layer increased.

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Multi-head Inkjet Patterning System for Manufacturing a Full Color Polymer Light Emitting Device (pLED) (고분자 유기 EL 제조를 위한 멀티헤드형 잉크젯 패터닝 시스템)

  • Oh, Je-Hoon;Kim, Si-Kyoung;Yoon, Hee-Youl;Oh, Se-Il;Kang, Yoo-Myung;Kim, Kwang-Il
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1219-1225
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    • 2003
  • According to the increase of lifetime and efficiency, the interest in the pLED has dramatically increased recently because pLED can be applied to large-size and flexible displays. The core process in the manufacture of pLED is the printing process of red, green and blue light emitting polymers (LEP), and inkjet printing method is one of the promising technology to print red, green and blue LEP on glass substrates. In this work, we developed a multi-head inkjet patterning system with 3 heads for each color. The developed inkjet patterning system is composed of the precise positioning system, head controller circuit, real-time ink drop evaluation system, maintenance system, and stable ink supply system. Finally, we investigated the stability and reliability of the system by printing red, green and blue LEP on the dummy substrate.

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Characteristics of CCD Based Optical CT Scanner for Therapeutic Radiation Dosimetry (치료방사선량평가를 위한 CCD 기반 광학컴퓨터단층촬영 스캐너의 특성)

  • Lee, Jae Choon;Kim, Ae Ran;Ji, Young Hoon;Kwon, Soo-Il
    • Progress in Medical Physics
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    • v.27 no.2
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    • pp.72-78
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    • 2016
  • A CCD camera and an LED light source were combined to fabricate a compact optical CT scanner for the therapeutic radiation dose evaluation of a polymer gel dosimeter. After the collimated beam emitted by the LED passed through aquarium, gel phantom, and telecentric lens, an image was collected by the CCD camera and reconstructed using MATLAB. By using a stepping motor and LabVIEW, the gel dosimeter was rotated at every $0.72^{\circ}$, and the time for collecting 500 slice images per a revolution was within 20 min. At a spatial frequency of 4.5 lp/mm of the optical CT scanner, the modulation transfer function value was 72%. The linear correlation coefficient of the optical CT scanner for the polymer gel dosimeter was 0.987.

Next-generation active-matrix polymer OLED displays

  • Vaart, N.C. Van Der;Meulenkamp, E.A.;Young, N.D.;Fleuster, M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.337-342
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    • 2004
  • Since 1992, Philips has been developing polymer OLEDs resulting in a first commercial monochrome display just 10 years later. Philips is now focusing on the technology development required to mass-produce full-color polymer OLDE displays, based on passive and active-matrix addressing. High precision inkjet printing has been chosen as the deposition technology for the OLED material. In this paper, we give an overview of the activities of Philips in the area of mobile OLED applications and explore the route towards large screen OLED television.

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Improved Efficiency of Polymer LEDs using Electron Transporting Layer

  • Kim, Jong-Lae;Kim, Jai-Kyeong;Cho, Hyun-Nam;Kim, Dong-Young;Hong, Sung-Il;Kim, Chung-Yup
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.125-126
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    • 2000
  • We report the use of fluorene based copolymers containing quinoline(POF66, PIF66) and pyridine(PFPV) units as electron transporting polymers for multi-layered LEDs. Double-layer device structure combining PIF66 as electron-transporting layer with the emissive MEHPPV showed a maximum quantum efficiency of 0.03%, which is 30 fold increased compared with ITO/MEHPPV/Al single-layer device. PFPV layer increased the quantum efficiency up to 0.1% in the device structure of ITO/(P-3:PVK)/PFPV/Al. The ETL with the electron deficient moiety improved the LED performance by the characteristics of electron transporting as well as hole blocking between emissive layer and metal cathode.

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Synthesis and Characterization of New Blue Light Emitting Alternating Terphenylenevinylene Carbazylenevinylene Copolymer

  • Kim Yun-Hi;Park Jung-Cheol;Kang Hun-Jin;Park Jong-Won;Kim Hyung-Sun;Kim Jin-Hak;Kwon Soon-Ki
    • Macromolecular Research
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    • v.13 no.5
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    • pp.403-408
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    • 2005
  • A new terphenylenevinylene carbazylenevinylene alternating copolymer with the advantage of poly(p-phenylenevinylene) (PPV), poly(p-phenylene )(PPP) and poly(carbazole) was designed, synthesized and characterized. The polymer structure was confirmed by various spectroscopic analyses and the number average molecular weight ($M_n$) of the obtained polymer was 7,800. The resulting polymer was thermally stable with high glass transition temperature ($T_g$) ($150^{\circ}C$), and was readily soluble in common organic solvents. Cyclic voltammetry study revealed that the HOMO and LUMO energy levels of the polymer were 5.37 and 2.47 eV, respectively. The ITO/PEDOT/polymer/AI device fabricated from the polymer emitted bright sky blue light with a maximum peak of around 478 nm. The device showed the maximum brightness of 1,200 nW with a turn-on voltage of 7V.