• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.382-382
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• 2009

In this study, we prepared electrodes containing ionic liquid for high temperature polymer electrolyte fuel cells. Effects of ILs on electrochemical properties of the electrodes were investigated carrying out measurement of cyclic voltammograms of the various electrodes with the content of IL in a strong supporting electrolyte. As the ILs content increased in electrodes, electrochemical surface area(ESA) decreased due to the leakage of ILs from Nafion ionomer. In addition, two case of cyclic voltammograms under two simulated environment, i.e. IL leakage from Nafion ionomer in I) electrode and ii) polymer electrolyte, were investigated. As a result, IL leakage from polymer electrolyte showed worse results in electrochemical properties of the electrode.

• Macromolecular Research
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• v.17 no.10
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• pp.729-733
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• 2009

Solution casting films of sulfonated poly[styrene-b-(ethylene-r-butylene)-b-styrene] copolymer (sSEBS)-based composite membranes that contained different amounts of organic, nanorod-shaped polyrotaxane were annealed at various temperatures for 1 h. The films' properties were characterized with respect to their use as polymer electrolyte membranes in direct methanol fuel cells (DMFCs). Different aspect ratios of polyrotaxane were prepared using the inclusion-complex reaction between $\alpha$-cyclodextrin and poly(ethylene glycol). The presence of the organic polyrotaxane inside the membrane changed the morphology during the membrane preparation and reduced the transport of methanol. The conductivity and methanol permeability of the composite membranes decreased with increasing polyrotaxane content, while the annealing temperature increased. All of the sSEBS-based, polyrotaxane composite membranes annealed at $140^{\circ}C$ showed a higher selectivity parameter, suggesting their potential usage for DMFCs.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.4
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• pp.245-255
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• 2021

Various studies about metallic bipolar plates have been conducted to improve fuel cell performance through flow field design optimization. These research works have been mainly focused on fuel cells for vehicle, but not fuel cells for building. In order to reduce the price and volume of fuel cell stacks for building, it is necessary to apply a metallic flow field, In this study, for a metallic flow field applied to a fuel cell for building, the effect of a change in the flow field shape on the performance of a polymer electrolyte membrane fuel cell was confirmed using a model and experiments with a down-sizing single cell. As a result, the flow field using a metal foam outperforms the channel type flow field because it has higher internal differential pressure and higher reactants velocity in gas diffusion layer, resulting in higher water removal and higher oxygen concentration in the catalyst layer than the channel type flow field. This study is expected to contribute to providing basic data for selecting the optimal flow field for the full stack of polymer electrolyte membrane fuel cells for buildings.

• International Journal of Automotive Technology
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• v.7 no.7
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• pp.867-872
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• 2006

Fuel cells are devices that convert chemical energy directly into electrical energy. Owing to the high efficiency of the fuel cells, a large number of research work have been done during these years. Among many kinds of the fuel cells, a polymer electrolyte membrane fuel cell is such kind of thing which works under low temperature. Because of the specialty, it stimulated intense global R&D competition. Most of the major world automakers are racing to develop polymer electrolyte membrane fuel cell passenger vehicles. Unfortunately, there are still many problems to be solved in order to make them into the commercial use, such as the thermal and water management in working process of PEMFCs. To solve the difficulites facing the researcher, the analysis of the inner mechanism of PEMFC should be implemented as much as possible and mathematical modeling is an important tool for the research of the fuel cell especially with the combination of experiment. By regarding some of the assumptions and simplifications, using the finite element technique, a two-dimensional electrochemical mode is presented in this paper for the further comparison with experimental data. Based on the principals of the problem, the equations of electronic charge conservation equation, gas-phase continuity equation, and mass balance equation are used in calculating. Finally, modeling results indicate some of the phenomenon in a unit cell, and the relationships between potential and current density.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.7
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• pp.715-720
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• 2010

We propose an electroosmosis-based air delivery scheme for polymer electrolyte fuel cells and experimentally investigate its feasibility. An electroosmotic pump under a low-frequency AC electric field is used to displace initially a volume of pump working liquids. This working liquid is then pumped into a space enclosed by a flexible membrane and the movement of the membrane delivers air to a fuel cell. We successfully demonstrated the operation of a forced-convection fuel cell using this technique. In this preliminary study, however, the power consumption of the pump exceeds the power generated by the fuel cell. We conclude this paper with a discussion of several ways to reduce the pump-to-fuel cell power ratio.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.1
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• pp.35-41
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• 2009

This paper proposes a stand alone type single-phase fuel cells micro-source with a voltage sag compensator for compensating the ac output voltage variations (sag or swell) of micro-source. The proposed micro-source is consist of a PEM(polymer electrolyte membrane) fuel cells simulator, a full bridge de converter, a 60Hz PWM(pulse width modulation) VSI(voltage source inverter), and a voltage sag compensator. Voltage sag compensator is similar to the configuration of hybrid series active power filter, and it is directly connected to micro-source through the injection transformer. Compensation algorithm of a voltage sag compensator adopts a single phase p-q theory. Effectiveness of the proposed the system is verified by the PSIM(power electronics simulation tool) simulation in the steady state and transient state which the proposed system is able to simultaneously compensate the harmonic current and source voltage sag or swell.

• Journal of the Korean Electrochemical Society
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• v.16 no.1
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• pp.30-38
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• 2013

In this study, a catalyst slurry was prepared with a Pt/C catalyst, Nafion ionomer solution as a binder, an ionic liquid (IL) (1-butyl-3-methylimidazolium tetrafluoroborate), deionized water and ethanol as a solvent for the application to polymer electrolyte fuel cells (PEFCs) at high-temperatures. The effect of the IL in the electrode of each design was investigated by performing a cyclic voltammetry (CV) measurement. Electrodes with different IL distributions inside and on the surface of the catalyst electrode were examined. During the CV test, the electrochemical surface area (ESA) obtained for the Pt/C electrode without ILs gradually decreased owing to three mechanisms: Pt dissolution/redeposition, carbon corrosion, and place exchange. As the IL content increased in the electrode, an ESA decrement was observed because ILs leaked from the Nafion polymer in the electrode. In addition, the CVs under conditions simulating leakage of ILs from the electrode and electrolyte were evaluated. When the ILs leaked from the electrode, minor significant changes in the CV were observed. On the other hand, when the leakage of ILs originated from the electrolyte, the CVs showed different features. It was also observed that the ESA decreased significantly. Thus, leakage of ILs from the polymer electrolyte caused a performance loss for the PEFCs by reducing the ESA. As a result, greater entrapment stability of ILs in the polymer matrix is needed to improve electrode performance.

• Applied Microscopy
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• v.47 no.3
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• pp.101-104
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• 2017

In this investigation, synchrotron X-ray imaging was used to investigate the water distribution inside newly developed gas diffusion media in polymer electrolyte membrane fuel cells. In-situ radiography was used to reveal the relationship between the structure of the microporous layer (MPL) and the water flow in a newly developed MPL equipped with randomly arranged holes. A strong influence of these holes on the overall water transport was found. This contribution provides a brief overview to some of our recent activities on this research field.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.277-280
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• 2005

Air-breathing polymer electrolyte membrane fuel cells (PEMFC) are highly promising particularly for small-power applications up to tens watts class. A distinctive feature of the air-breathing PEMFC is its simple system configuration in which axial fans operate for dual purposes, supplying both oxidant and coolant in a single manner. In the present study, a nominal SOW air-breathing PEMFC system is developed and investigated to determine the optimal operating strategy through parametric studies (i.e., reactant humidity, and fan-blowing flow rate). The cell voltage distributions are examined as a function of time to evaluate the system performance under various operating conditions.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.320-323
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• 2006

A numerical study is made of a manifold and bipolar plate in polymer electrolyte fuel cells, the aim of the present study is to describe the characteristics of flow pattern In manifold and bipolar plate. The present work shows that the flow pattern in the bipolar plate is affected by the penetration flow through GDL characterized by clamping pressure and GDL intrusion in to a channel area. Manifold geometry also affects the flow distribution. The recirculation flow by bent duct destroy even distribution In manifold, the present work shows that corner rounding can improve the manifold performance.