• 한국유변학회:학술대회논문집
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• 한국유변학회 2000년도 춘계 학술발표회 논문집
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• pp.15-18
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• 2000

• Macromolecular Research
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• 제17권11호
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• pp.856-862
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• 2009

This study examined the effects of liquid and solid additives on the morphological, mechanical and thermal insulating properties of rigid polyurethane foams (PUFs). The PUFs synthesized with tetramethylsilane (TEMS) as a liquid-type additive showed a smaller average cell size and lower thermal conductivity than those with the aerosil 200 and clay 30B as solid-type additives. When TEMS was added, the average cell size of the PUF became more uniform and finer due to the reduced surface tension of the polymer solution, which increased the nucleation rate and number of bubbles produced and reduced cell size. The PUFs with TEMS showed the highest closed cell contents among the PUFs prepared using TEMS, aerosil 200 and clay 30B. This suggests that the insulation properties of PUF can be determined by both the size of the cell structure and the amount of closed cell contents in the system. The compression and flexural strengths of the PUF increased slightly when the aerosil 200, clay 30B and TEMS were added compared those of the neat PUF. The reaction profiles of the PUFs showed a similar gel and tack tree time with the reaction time among the PUFs synthesized with three different additives and neat PUF. This suggests that the nucleating additives used in this study do not affect the bubble growth of the chemical reaction, and the additives may act as nucleating agents during the formation of PUF. From the above results of the cell size, thermal conductivity, closed cell contents and reaction profile of the PUFs, liquid-type nucleating agent, such as TEMS, is more effective in decreasing the thermal conductivity of the PUF than solid-type nucleating agent, such as aerosil 200 and clay 30B.

• Composites Research
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• 제35권5호
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• pp.309-316
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• 2022

저온 환경에서 사용하는 장치의 급격한 개발 요구에 따라 내한성을 가지는 케이블 재료에 대한 요구도 급격하게 증가하고 있다. 열가소성 폴리머는 폴리머를 구성하는 약 20개 이상의 첨가제와 폴리머의 종류와 함량에 따라 내한특성이 크게 좌우된다. 저온에서의 고분자 경화현상은 단순 온도에 의한 효과와 유리 전이온도에서의 취화 및 경화, 고분자의 결정화에 의한 경화로 구분할 수 있다. 본 연구에서는 저온의 유리 전이온도를 가지는 열가소성 폴리머와 난연제 및 첨가제 등을 혼합하여 전선용 열가소성 고분자 복합재료의 기계적 특성 평가를 하였다. 첨가제와 상용화제의 첨가량에 따라 기계적 물성과 가공성 등이 결정되는 것을 확인하였고 본 연구는 저온용으로 개발하는 전선 요구성능 충족을 위한 최적화의 기초 데이터로 활용할 수 있을 것으로 사료된다.

• 설비공학논문집
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• 제12권3호
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• pp.251-257
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• 2000

District heating and cooling systems offer highly efficient energy utilization and maintenance by centralizing heat management. More pumping power, however, is required because the water has to travel long distance from heat source to the users. In the present study, a trace of drag reduction additives is added to the District Cooling system to achieve a significant drag reduction and save pumping power. Water-soluble polymers, surfactants, and environment-friendly degradable polymers are used as effective drag reducing additives. Time dependent percent drag reductions are compared for various additive solutions at 100 wppm concentration for different water velocity. Without as an anionic surfactant, copolymer was most effective in percent drag reduction. It is found that there exists an optimal condition when copolymer is mixed with SDS. An environment-friendly degradable polymer, xanthan gum, is found to be a significant drag reduction additive. Ice slurry systems, can give less pressure drops compared with chilled water system for certain condtions. Drag reduction additives were also effective for the ice slurry system.

• 폴리머
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• 제26권2호
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• pp.270-278
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• 2002

저밀도 2-D 탄소/탄소 복합재료의 저속 충격에 의한 파괴 거동과 첨가제에 따른 충격 에너지 흡수 경향을 연구하였다. 저속 충격시험은 mini tower 낙추 충격 시험기를 이용하였으며, 흑연, 카본블랙, 분쇄탄소섬유를 첨가제로 선택하였다. 흑연의 첨가는 최대하중값을 증가시켰으며, 전체적인 관통이 일어나기까지 응력을 오랫동안 유지시키는 효과를 나타내었다. 특히 9 vol%의 함량에서 흑연이 첨가되지 않은 씨편보다 약 42%의 충격 흡수 개선을 보였다. 약 0.4 J의 낮은 충격에너지에 의한 충격 회수에 따른 실험에서 첨가제가 첨가되지 않은 시편의 경우, 충격에너지는 층간분리에 의해 소모되고, 흑연의 함량이 증가함에 따라 파괴 경향은 시편의 관통으로 변화함을 관찰할 수 있었다.

• 한국재료학회지
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• 제29권7호
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• pp.399-407
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• 2019

This research is carried out to analyze the effects of Styrene and PVP on the properties of silicone hydrogel lenses. Styrene group and PVP(Polyvinylpyrrolidone) are used as additives for a basic combination containing silicone monomer, TSMA(trimethylsilyl methacrylate) and DMA(n,n-dimethylacrylamide) added to the mix at ratios of 1~10 %. Silicone hydrogel lens is produced by cast-mold method. The polymerized lens sample is hydrated in a 0.9 % saline solution for 24 hours before its optical and physical characteristics are measured. Measurement of the physical characteristics of the produced material shows that the refractive index is 1.3682~1.4321, water content 77.11~45.73 %, visible light transmittance 95.14~88.20 %, and tensile strength 0.0652~0.3113 kgf. The results show a decrease of refractive index as the ratio of additives and water content decreases. The result of the stabilization test of polymerization show an increase of extractables along with increase of the ratio of additives, but the difference is not significant for all samples, so it can be judged that the stabilization of the polymer is maintained. Therefore, the additions of styrene and PVP should be taken into consideration for their effects on the physical properties of silicone hydrogel lens.

• BMB Reports
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• 제31권4호
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• pp.384-390
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• 1998

DNA fragments (51-587 bp) were separated by capillary electrophoresis using entangled polymer, hydroxyethylcellulose, in uncoated fused silica capillary columns. The factors affecting the separation of DNA fragments with hydroxyethylcellulose media were evaluated, i.e., the concentration of buffer and entangled polymer, effects of additives (methanol, ethidium bromide, EDTA), temperature, and injection methods. Maximum performance was obtained by adding 5% methanol in 0.5% hydroxyethylcellulose solution at $30^{\circ}C$. Addition of methanol in polymer media increased the resolution of small size DNA fragments (< 100 bp). On the other hand, addition of ethidium bromide and EDTA, which are commonly used in conventional DNA separation, reduced the resolution of DNA fragments in the polymer solution. It turns out that the separation behavior of DNA in entangled polymer is more sensitive to the running condition compared to that in polyacrylamide gel-filled capillary, but the reproducibility of DNA separation in entangled polymer is reliable.

• 한국세라믹학회지
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• 제35권9호
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• pp.958-968
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• 1998

Porous silica ceramics were prepared using DCCA(Drying Control Chemical Additives) Such as uncharged polymer(Polyethylene glycol) and protein (Lipase) under H2O/Low-grade TEOS=10 C2H5OH/Low-grade TEOS=1 HC1/Low=grade TEOS=0.01 After Plain which doesn't added DCCA and samples of 11 sorts which varied molecular weight of PEG(Mw=600, 1000, 2000) quantity of Lipase and concentration of wat-er were synthesized gellation time and thermal analysis were investigated. After heat-treated at 600, cry-stal structures analyses of SiO2 polymer and characteristics of pores were investigated. Gellation time was retarded about 2-6 times as compared with plain resulting in addition of DCCA and crystal structures ex-hibited amorphous state. Moreover as increase of water a short gellation time was obtained. The samples added PEG showed increase of specific surface areas up to 20-40% and had micropores while those of Lipase were decreased about 90% and showed broad pore size distribution.

• 한국자동차공학회논문집
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• 제4권3호
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• pp.176-186
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• 1996

The phenomena of drag reduction using small quantities of a liner macromolecules has attracted the attention of many experimental investigations. On the other hand drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to flow with cavitation which occurs pump impellers. But the research on dragreduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction, mean liquid velocity and turbulent intensity whether polymer additives a horizontal single and two phase system or not. Flow pattern of air-water two phase flow was classified by electrical conductivity probe signal. Velocities and turbulent intensities of signal were measured simultaneously with a Hot-film anemometer.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.221-224
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• 2003

Polyvinyl chloride (PVC)/gypsum Polymer blend materials were prepared by melt blending of PVC with gypsum and additives. Effect of gypsum content on the properties of PVC/gypsum Polymer blend material was studied by investigating physico-mechanical properties, thermal properties and morphology development. It was found that the replacement of gypsum for methylene-butadiene-sarene (MBS) component in PVC/gypsum polymer blend material enhanced the tensile strength, but gradually decreased its impact strength. Besides, with the increase of gypsum content, the elongation at break of material gradually decreased. The Presence of the different gypsum contents made a shift of g1ass transition temperature and increased the thermal stability as well as the processing temperature range of polymer blends. The observation of morphology, the results of the physico-mechanical properties and thermal properties proved simultaneously that PVC/gypsum Polymer blend material with the gypsum content of 22.56 wt.% reached the optimum results among five kinds of PVC/gypsum Polymer blend materials investigated.