• Title/Summary/Keyword: Polyether

Search Result 189, Processing Time 0.026 seconds

A STUDY ON DIMENSIONAL STABILITY OF THE RUBBER IMPRESSION MATERIALS FOLLOWING IMMERSION WITH CHEMICAL DISINFECTANTS (수종의 화학소독제에 침적시킨 고무인상체의 크기안정성에 관한 연구)

  • Kim, Hyung-Sik;Kim, Chang-Whe
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.27 no.2
    • /
    • pp.249-259
    • /
    • 1989
  • Dental impression materials often become contaminated with patients' saliva and blood which creates the potential for cross-infection. It was the purpose of this study to investigate the effects of disinfection of three different rubber impression materials with four different disinfecting solutions. Polysulfide, vinyl polysiloxane and polyether impression materials were mixed according to the manufacturer's directions and samples were formed on a stainless steel model. On removal from the standard model, impressions were immersed in a disinfectant (acid-potentiated glutaraldehyde, phenollic compound, chlorine compound, iodophor) at room tempera tures for ten minutes. After disinfection, the distance between reference points(linear dimension) was measured using the non-contact automatic cordinate measuring projector(MZ-1, Nikon). Through statistical analyses on the data from this study,. the following conclusions were obtained. 1. Polysulfide, vinyl polysiloxane impressions were disinfected without dimensional change.(p>0.05) 2. Polyether impressions which were immersed in acid-potentiated glutaraldehyde were statistically different from control group.(p<0.05) But the amount of shrinkage(0.04%) would not be clinically significant. 3. By immersion of polysulfide, vinyl polysiloxane, polyether impressions in Banicide, Biocide, Multicide plus, sodium hypochlorite for ten minutes, clinically accurate impressions were obtained without dimensional change.

  • PDF

Preparation and Characterization of SPEEK/Cellulose Polymer Composite Membranes for Water Electrolysis (수전해용 술폰화 폴리에테르 에테르 케톤과 셀룰로오스 고분자 복합막의 제조 및 특성)

  • SONG, YURI;CHA, JINSAN;YOON, YOUNGYO;MOON, SANG-BONG;CHUNG, JANG-HOON
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.27 no.5
    • /
    • pp.478-484
    • /
    • 2016
  • Polyether ether ketone (PEEK) composite membranes have been intensively investigated for polymer electrolyte membrane water electrolysis (PEMWE). Covalently linked (CL) sulfonated polyether ether ketone (SPEEK) and cellulose polymer composite membranes were prepared and characterized. Polyether ether ketone (PEEK) and cellulose were sulfonated and then were covalently linked by 1,4-diiodobutane to produce covalently linked SPEEK and cellulose polymer composite membranes. The composite membranes showed better thermostability and electrochemical properties than SPEEK. The membranes were prepared by sol-gel casting method. CL-SPEEK/Cellulose composite membrane featured 0.2453 S/cm of proton conductivity at $80^{\circ}C$ which was better than that of Nafion.

Syntheses and Potentiometric Properties of Polyethers Containing Thiazole and Oxazole Derivatives

  • 최준혁;고영국;권일전;김홍석;박현주;김상진;차근식;남학현
    • Bulletin of the Korean Chemical Society
    • /
    • v.20 no.5
    • /
    • pp.581-586
    • /
    • 1999
  • A series of polyethers containing the thiazole or oxazole subcyclic moiety have been synthesized. Reaction of 2-aryl-4-hydroxymethylthiazole with tetra- and pentaethylene glycol di-p-tosylate in THF provided corresponding α,ω-bis[2'-aryl-4'-methylthiazole]polyethylene glycol in good yields. Similar treatment of 2-phenyl-4-hydroxymethyloxazole 7 and 2-phenyl-5-hydroxymethyloxazole 8 with tetraethylene glycol di-p-tosylate yielded the corresponding 1,13-bis [2'-phenyl-4'-methyloxazole]tetraethylene glycol 16 and 1,13-bis[2'-phenyl-5'-methyloxazole]tetraethylene glycol 17 in 69 and 43% yields in respectively. The potentiometric properties of PVC-based ion selective membranes containing 66 wt% o-nitrophenyloctyl ether (NPOE) and 4 wt% polyethers 9-17 have been examined. The membranes containing thiazole and oxazole polyether derivatives exhibited high selectivity toward silver (I) ion. It was observed that the response slopes of the electrodes to silver ion vary with the length of polyether chain linking two thiazole subcyclic moiety. Potentiometric data suggest that the number of ether units, CH2OCH2, for phenylthiazole derivatives be greater than 5 to result in near-Nernstian response. However, the response behaviors of the membrane electrodes based on phenyloxazole podands 16 and 17, which have different orientation, were correspondingly similar to those of the electrodes based on phenylthiazole podands 9 and 10. On the other hand, the ISEs based on thiazole polyether derivatives with different terminal substituents, e.g., phenyl 10, naphtyl 14, and thienyl 15, except that with pyridyl 12, exhibited little difference in their potentiometric properties.

Comparative Study of the Rheologic Properties of Elastic Impression Materials (수종 고무인상재의 유변학적 특성에 관한 비교)

  • Hong, Jun-Won;Ahn, Seung-Geun;Park, Ju-Mi;Song, Kwang-Yeob
    • Journal of Dental Rehabilitation and Applied Science
    • /
    • v.25 no.1
    • /
    • pp.31-40
    • /
    • 2009
  • The rheologic properties of elastic impression materials is a very important role as taking high accuracy impression. But, the studies that are focused on the rheologic properties of Korean elastic impression materials are not sufficient. The purpose of this study is to help clinical high accuracy impression taking by testing rheologic properties of elastic impression material that is made by Korea and other countries. Six type III elastic impression materials are tested. Subjects are 2 Korean polyvinylsiloxane(PVS), 2 imported PVS, 1 polyether, and 1 polysulfide. HAAKE RheoStress $1^{(R)}$(Thermo Electron Co. Germany)is used in measuring. HAAKE RheoStress $1^{(R)}$ is plate to plate type rheometer. All subjects is tested 3 times and measuring time is 900 seconds. We measured G′ and loss tangent after mixing. All elastic impression materials had a sigmoid shape on increasing G′ by time and decreasing loss tangent after setting, maximum G' is appeared highest in polyether, and lowest in polysulfide. Initial loss tangent is highest in polyether, and is lowest in Koreans PVS. Significant difference is showed in initial loss tangent between Korean PVS and imported PVS.

Nucleotide Sequence and Analysis of the Genes for Type II Polyketide Synthase Isolated from Streptomyes albus (Streptomyces albus로부터 분리된 Type II Polyketide Synthase 유전자의 염기 서열 및 분석)

  • ;Huchinson, C.R.
    • Microbiology and Biotechnology Letters
    • /
    • v.23 no.2
    • /
    • pp.178-186
    • /
    • 1995
  • Streptomyces albus wild type ATCC 21838 produced salinomycin, polyether antibiotic. To clone genes related salinomycin production, a genomic library was screened using actI as a DNA hybridization probe. pWHM 210 was isolated, which contained an approximately 24 kb of insert DNA. A 3.8 kb region in the 24 kb insert DNA was hybridized to actI and the nucleotide sequence of this region was determinied. Two open reading frames found in the same direction were homologous to genes for $\beta$-keto acyl synthase/acyl transferase and chain length determining factor in type II PKS (polyketide synthase). The genes were components of minimal type II PKS genes, highly conserved and showed the strong simiarity to other type II PKS genes known today.

  • PDF

치과용 인상재의 비교 응용

  • Kim, Cheol-Wi
    • The Journal of the Korean dental association
    • /
    • v.24 no.3 s.202
    • /
    • pp.199-203
    • /
    • 1986
  • 치과용 인상재는 구강내에서 치아나 주위조직을 정확히 인기하여야 하며 조작이 간편하고 유동성이 충분하며 경화시간이 적당하고 값도 저렴해야 한다. 또 구강내에서 제거할 때 영구변형이나 파절되지 않는 충분한 강도와 크기의 정확성도 있어야 하며 자극이나 독성이 없고 인체에 안정성이 있고 모형재와 친화성이 있으며 보관중에도 변질해서는 안된다. 그러나 인상재는 서로 상이한 특성이 있고 장단점이 각각 다르므로 모든 조건에 일치하는 인상재는 거의 없다. 따라서 여러 인상재중에서 가장 적합한 인상재를 선택하는 것이 중요한 과정이다. 즉 인상재의 특성과 응용을 알고 선택할땐 보다 정밀한 모형을 얻을 수 있다. 기록에 의하면 18~19세기경에 최초로 인상용 왁스를 사용한 이래 19세기 중엽에 인상용 석고, 1925년에 agar, 1930년 ZOE, 1945년 앨지네이트, 1957년 실리콘, 1967년 polyether 및 1975년 부가중합형 실리콘이 사용되었으며 인상재가 유연성과 탄성이 있는가 경고하며 비탄성인가 또는 온도변화와 화학반응으로 경화되는 가에 따라서 ZOE paste, 인상용 석고, 인상용 왁스, 인상용 콤파운드, 수성콜로이드(agar, 앨지네이트), polysulfide, 실리콘(축중합형, 부가중합형) 및 polyether 인상재등 10여종으로 분류된다.

  • PDF