• Title/Summary/Keyword: Polyester resin

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Effects of Fillers on Mixing and Mechanical Properties of Polymer Concrete (충진재가 폴리머 콘크리트의 배합과 역학적 성질에 미치는 영향)

  • 연규석;김광우;김기성;김관호
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.35 no.2
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    • pp.81-91
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    • 1993
  • This study was performed to evalute effects of fillers on the mixing characteristics and mechanical properties of polymer concrete. Two types of unsaturated polyester polymer and two types of epoxy resin were used as binder material, and the portland cement, a fly ash and heavy calcium carbonate were used as filler. Following conclusions were drawn from the research results. 1. Working life of polymer concrete was not affected by filler types, but affected significantly by polymer types and quantities of hardener and catalysts. 2. Without concerning polymer types, use of heavy calcuim carbonate as filler was the best in improving workability.3. The highest strength was achieved by heavy calcium carbonate in using unsaturated polyester resin and by fly ash in using epoxy resin type.4. Elastic modulus was in the range of 2.05X 10-5~2.6X 10-5gf/cm$^2$, which was approximatly 60% of that of cement concrete. Heavy calcium carbonate with unsaturated polyester resin and fly ash with epoxy resin showed relatively higher elastic modulus.

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Surface Resistance and Tensile Strength of Polyester Resin by Anti-static Agents (대전방지제에 의한 폴리에스테르 수지의 표면저항과 인장강도 특성)

  • Lee, Jeon-Kyu;Choi, Hwan-Oh;Kim, Eun-Bong;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.638-642
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    • 2010
  • In order to develope anti - static polyester resin which may be employed to dangerous circumstance with high organic vapor content, the effect of anti - static agents on the surface resistance and tensile strength of polyester resin were studied. Three organic anti - static agents and a conductive carbon black were adapted and used separately and together. The effects of anti - static agents, their contents, and synergic effect of anti - static agents were experimentally examined. Surface resistance and tensile strength of the polyester resin were decreased with the content of anti - static agents, and polyester resin with low surface resistance and relatively high tensile strength could be prepared by synergic effect of organic anti - static agent and carbon black.

Improvement of Tensile Strength of Polyester Resin Using Silica/Chopped Glass Fiber Modified by Coupling Agent (실란 처리된 실리카 및 절단 유리섬유에 의한 폴리에스테르 수지의 인장강도 향상)

  • Lee, Jeon-Kyu;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.30-34
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    • 2012
  • For the purpose of development of polymeric material for marine applications, the effects of silica and chopped glass fiber on tensile strength of polyester resin were studied. A series of experiments were performed with different contents of silica and chopped glass fiber. Tensile strength of polyester resin was increased with the contents of unmodified glass fiber, and decreased with that of silica. The surfaces of silica and chopped glass fiber were modified with coupling agent at different concentrations, and the modification showed positive effect on the increase of tensile strength of polyester resin. Synergistic effect on the tensile strength of polyester resin was observed by modified silica and chopped glass fiber.

Quantitative Analysis of Relative Adsorption of Disperse Dyes on Polyurethane in Polyurethane-impregnated Polyester Microfibers (폴리우레탄함침 폴리에스터 극세사 소재의 분산염료 염색시 폴리우레탄 성분에 대한 염료의 상대염착률 정량분석)

  • Jun, Heejeong;Park, Suhyeon;Lee, Junheon;Kim, Taekyeong
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.121-127
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    • 2020
  • The analysis method of relative adsorption of disperse dyes on impregnated polyurethane resin and polyester fiber separately was investigated. The solvents for extracting the dyes from polyurethane resin and polyester fiber were determined by acetone and DMF, respectively. By extracting the dyed fibers with acetone at room temperature within 30 minutes, the dyes adsorbed only on the polyurethane resin could be extracted. And then by additional extracting the same fabrics with DMF at 95℃ for longer than 1 hour, the dyes adsorbed on polyester fabrics was extracted. This means that the dyes adsorbed on polyurethane and polyester could be extracted separately and that relative adsorption of the dyes on the both components could be analyzed quantitatively. Using this analysis method, the relative adsorption of a disperse dye was investigated after reduction clearing with various conditions.

A study on the Shrinkage Reduction and Strengths of Unsaturated Polyester Mortar (불포화 폴리에스테르 레진 모르타르의 수축저감 및 강도특성에 관한 연구)

  • 최낙운;최길섭;김완기;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.343-348
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    • 1999
  • The purpose of this study is to evaluated the effects of added expanded polystyrene on the basic properties of UP mortar. Polyester resin mortars are prepared with expanded polystyrene ratio in styrene monomer (EPS/PS), and the ratio of total polystyrene resin to UP resin (PS/UP). And it is tested for viscosity of UP resin added PS resin, slump-flow test, working life, flexural and compressive strengths, and curing shrinkage test. From the test result, Viscosity of resin for polymer mortar increases with increasing PS content. Curing shrinkage of UP mortar is considerably smaller than that of plain UP mortar, nevertheless, reduction in the strengths is not recognized according to adding PS resin. In this study, we can obtain the optimum mix proportions of polymer mortar using PS resin.

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A Study of the Cutting Properties of Epoxy Resins (에폭시 수지의 절삭가동에 관한 연구)

  • 김희남
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1997.10a
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    • pp.76-81
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    • 1997
  • In the past polyester was usually used as the matrix of all fiber-reinforced plastic (FRP). Nowadays, however, epoxy resin has taken the place of polyester due to its superior properties. If the cutting properties of epoxy resin are unknown, It is difficult to find the optimum cutting conditions of all fiber-reinforced plastic such as CFRP. AFRP. GFRP. In this paper, I will study the cutting properties of epoxy resin by testing surface roughness.

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Strength Properties of MMA-Modified Unsaturated Polyester Mortar (MMA 개질 불포화 폴리에스터 모르타르의 강도 특성)

  • Yeon, Kyu-Seok;Jo, Kyu-Woo;Choi, Jong-Yun;Jeong, Jung-Ho
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2003.10a
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    • pp.379-382
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    • 2003
  • In this study, methyl methacrylate (MMA)- modified unsaturated polyester mortar, in which the MMA was added to the unsaturated polyester resin, was developed for improving the early-age strength and the workability of the conventional polymer concrete, binder of which was the unsaturated polyester resin. Then the strength properties of the MMA-modified unsaturated polyester mortar were surveyed. The experimental results showed that early-age strength was greater when the MMA contents were increased in the range of $20{\sim}40%$, but the strength rather showed a tendency of decrease when the MMA contents was 50%.

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The Properties of Polyester Mortars with Various Fillers (충전재에 다른 폴리에스테르 모르타르의 특성)

  • 김성범;윤성진;최낙운;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.449-452
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    • 2003
  • The objective of this study is to investigate the basic properties of polyester mortars using ground calcium carbonate(GCC), blast furance slag(BFS), fly ash(FA), ordinary portland cement(OPC) as fillers. Particle size distribution, particle shape and resin absorption of GCC, BFS, FA and OPC are checked. Polyester mortars with GCC, BFS, FA and OPC are prepared with various MEKPO content and tested for working life. The flexural and compressive strengths of the polyester mortars with MEKPO content of 0.5phr are evaluated. As a test result, the average sizes of GCC, BFS, FA and OPC are 9.7$\mu\textrm{m}$, 11.6$\mu\textrm{m}$, 21.2$\mu\textrm{m}$, 29.9$\mu\textrm{m}$. Resin absorption of FA is 1.5times larger than other fillers. The polyester mortar with FA at a MEKPO content of 0.5phr has the longest working life and the maximum flexural and compressive strengths.

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Hot Water Resistance of Polymer Mortar Composites Depending on Unsaturated Polyester Resin Types (불포화폴리에스테르 수지의 형태에 따른 폴리머 모르타르 복합재료의 내열수성)

  • Hwang, Eui-Hwan;Song, Min-Kyu;Kim, Yong-Yeon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.201-208
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    • 2018
  • The ortho- and iso- type unsaturated polyester resins were synthesized and used as a polymer binder of the polymer mortar composite. Styrene monomer and acrylonitrile were used as a diluent for the unsaturated polyester resin. Methyl ethyl ketone peroxide (MEKPO) and cobalt octoate (CoOc) were used as a curing agent and an accelerator, respectively. Four kinds of unsaturated polyester resins were prepared according to types of the resin and diluent, and used as a polymer binder in the preparation of the specimen. A total of 16 polymer mortar specimens were prepared according to the added amount of the polymer binder and subjected to a hot water resistance test, followed by compressive and flexural strength tests, and pore and SEM analyses. As a result, it was found that the strength of the specimen using the iso-type unsaturated polyester resin as the polymer binder was better than that of using the ortho-type unsaturated polyester resin. The total pore volume and diameter measured after the hot water resistance test were reduced compared to the values before the test. In the micrographs observed before the hot water resistance test, the polymer binder, filler and fine aggregate were firmly combined to the co-matrix, but the polymer binder was mostly decomposed in the micrographs observed after the test.

Effects of Resin Quantity on the Strength Properties of Polyester Resin Concrete (폴리에스터 레진콘크리트에서 수지 사용량에 따른 강도특성)

  • 황광률;소형석;소승영;박홍신;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.235-239
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    • 1994
  • Polymer mortars are mainly used as protective coatings in concrete, reinforced concrete, and more rarely, steel, while polymer concretes represent a new type of structural material capable of withstanding highly corrosive environments. The mechanical properties, chemical stability, and some other useful properties are the reasons research, design, and production organizations. However polymer mortars and polymer concretes have been introduced only recently, and many of their properties are still imperfectly known. And, the main technique in producing polymer concrete is to minimize void volume in the aggregate mass so as to reduce the quantity of the relatively impressive polymer necessary for binding the aggregate. In this study, compressive strength and flexural strength of unsaturated polyester resin concrete are related to quantity of resin and solid volume of aggregate. It was founded that the more solid volume of aggregate increase, the less using quantity of resin decrease with out reducing mechnical properties. When solid volume ratio of aggregate is 70.6%, using quantity of resin is minimized to 10wt.%.

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