• 한국농공학회지
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• 제35권2호
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• pp.81-91
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• 1993

This study was performed to evalute effects of fillers on the mixing characteristics and mechanical properties of polymer concrete. Two types of unsaturated polyester polymer and two types of epoxy resin were used as binder material, and the portland cement, a fly ash and heavy calcium carbonate were used as filler. Following conclusions were drawn from the research results. 1. Working life of polymer concrete was not affected by filler types, but affected significantly by polymer types and quantities of hardener and catalysts. 2. Without concerning polymer types, use of heavy calcuim carbonate as filler was the best in improving workability.3. The highest strength was achieved by heavy calcium carbonate in using unsaturated polyester resin and by fly ash in using epoxy resin type.4. Elastic modulus was in the range of 2.05X 10-5~2.6X 10-5gf/cm$^2$, which was approximatly 60% of that of cement concrete. Heavy calcium carbonate with unsaturated polyester resin and fly ash with epoxy resin showed relatively higher elastic modulus.

• Korean Chemical Engineering Research
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• 제48권5호
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• pp.638-642
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• 2010

선박의 엔진실 등 유증기가 많이 발생하는 위험한 환경에도 적용할 수 있는 대전방지용 폴리에스테르 수지를 개발할 목적으로, 폴리에스테르 수지의 표면저항과 인장강도에 미치는 대전방지제의 영향을 조사하였다. 대전방지제로는 3종의 유기성 대전방지제와 전도성 카본블랙을 단독 혹은 혼합 사용하였다. 이들 대전방지제들의 종류와 첨가량, 그리고 혼합 사용하였을 때의 효과 등에 대한 실험을 수행하였다. 대전방지제의 첨가량이 증가함에 따라 생성되는 폴리에스테르 수지의 표면저항과 인장강도는 전반적으로 감소하였으나, 유기성 대전방지제와 카본블랙을 혼합 사용하여 인장강도가 비교적 우수하면서도 표면저항이 낮은 폴리에스테르 수지를 제조할 수 있었다.

• Korean Chemical Engineering Research
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• 제50권1호
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• pp.30-34
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• 2012

선박용 부품에 적용할 수 있는 고분자 소재를 개발하기 위한 연구의 일환으로, 폴리에스테르 수지의 인장강도에 미치는 실리카와 절단 유리섬유의 영향을 조사하였다. 실리카와 절단 유리섬유의 첨가량 및 표면 개질에 사용된 커플링제의 농도를 변화시키면서 실험을 수행하였다. 표면 개질을 수행하지 않은 경우, 유리섬유의 첨가량이 증가하면 인장강도가 증가하였으나, 실리카는 첨가량이 증가할수록 인장강도가 감소하였다. 커플링제를 사용하여 첨가제의 표면을 개질하면 인장강도에 긍정적인 효과를 나타내었으며, 개질된 실리카와 절단 유리섬유를 혼합 첨가하면 인장강도의 증가에 상승효과를 나타내는 것을 알 수 있었다.

• 한국염색가공학회지
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• 제32권3호
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• pp.121-127
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• 2020

The analysis method of relative adsorption of disperse dyes on impregnated polyurethane resin and polyester fiber separately was investigated. The solvents for extracting the dyes from polyurethane resin and polyester fiber were determined by acetone and DMF, respectively. By extracting the dyed fibers with acetone at room temperature within 30 minutes, the dyes adsorbed only on the polyurethane resin could be extracted. And then by additional extracting the same fabrics with DMF at 95℃ for longer than 1 hour, the dyes adsorbed on polyester fabrics was extracted. This means that the dyes adsorbed on polyurethane and polyester could be extracted separately and that relative adsorption of the dyes on the both components could be analyzed quantitatively. Using this analysis method, the relative adsorption of a disperse dye was investigated after reduction clearing with various conditions.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.343-348
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• 1999

The purpose of this study is to evaluated the effects of added expanded polystyrene on the basic properties of UP mortar. Polyester resin mortars are prepared with expanded polystyrene ratio in styrene monomer (EPS/PS), and the ratio of total polystyrene resin to UP resin (PS/UP). And it is tested for viscosity of UP resin added PS resin, slump-flow test, working life, flexural and compressive strengths, and curing shrinkage test. From the test result, Viscosity of resin for polymer mortar increases with increasing PS content. Curing shrinkage of UP mortar is considerably smaller than that of plain UP mortar, nevertheless, reduction in the strengths is not recognized according to adding PS resin. In this study, we can obtain the optimum mix proportions of polymer mortar using PS resin.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 1997년도 추계학술대회 논문집
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• pp.76-81
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• 1997

In the past polyester was usually used as the matrix of all fiber-reinforced plastic (FRP). Nowadays, however, epoxy resin has taken the place of polyester due to its superior properties. If the cutting properties of epoxy resin are unknown, It is difficult to find the optimum cutting conditions of all fiber-reinforced plastic such as CFRP. AFRP. GFRP. In this paper, I will study the cutting properties of epoxy resin by testing surface roughness.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2003년도 학술발표논문집
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• pp.379-382
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• 2003

In this study, methyl methacrylate (MMA)- modified unsaturated polyester mortar, in which the MMA was added to the unsaturated polyester resin, was developed for improving the early-age strength and the workability of the conventional polymer concrete, binder of which was the unsaturated polyester resin. Then the strength properties of the MMA-modified unsaturated polyester mortar were surveyed. The experimental results showed that early-age strength was greater when the MMA contents were increased in the range of $20{\sim}40%$, but the strength rather showed a tendency of decrease when the MMA contents was 50%.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.449-452
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• 2003

The objective of this study is to investigate the basic properties of polyester mortars using ground calcium carbonate(GCC), blast furance slag(BFS), fly ash(FA), ordinary portland cement(OPC) as fillers. Particle size distribution, particle shape and resin absorption of GCC, BFS, FA and OPC are checked. Polyester mortars with GCC, BFS, FA and OPC are prepared with various MEKPO content and tested for working life. The flexural and compressive strengths of the polyester mortars with MEKPO content of 0.5phr are evaluated. As a test result, the average sizes of GCC, BFS, FA and OPC are 9.7$\mu\textrm{m}$, 11.6$\mu\textrm{m}$, 21.2$\mu\textrm{m}$, 29.9$\mu\textrm{m}$. Resin absorption of FA is 1.5times larger than other fillers. The polyester mortar with FA at a MEKPO content of 0.5phr has the longest working life and the maximum flexural and compressive strengths.

• 공업화학
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• 제29권2호
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• pp.201-208
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• 2018

올소-타입 불포화폴리에스테르 수지와 이소-타입 불포화폴리에스테르 수지를 합성하여 폴리머 모르타르 복합재료의 폴리머 결합재로 사용하였다. 불포화폴리에스테르 수지의 희석제로는 스티렌 모노머와 아크릴로니트릴을 사용하였고, 경화제로 methyl ethyl ketone peroxide (MEKPO), 가속제로 cobalt octoate (CoOc)를 사용하였다. 수지의 형태와 희석제의 종류에 따라 4종의 불포화폴리에스테르 수지를 제조하여 공시체 제조의 폴리머 결합재로 사용하였다. 폴리머 결합재의 첨가량에 따라 총 16종의 폴리머 모르타르 공시체를 제작하여 내열수성 시험을 행한 후 압축 및 휨강도시험, 세공분석 및 SEM 분석을 실시하였다. 시험결과, 이소-타입 불포화폴리에스테르 수지를 폴리머 결합재로 사용한 공시체가 올소-타입 불포화폴리에스테르 수지를 사용한 공시체보다 더 우수한 강도를 나타내었다. 내열수성시험 후에 측정한 총세공량과 세공의 평균직경은 시험 전에 측정한 값에 비하여 감소되었다. 내열수성시험 전에 관찰한 사진에서 폴리머 결합재와 충전재 및 잔골재가 co-matrix 상으로 견고하게 결합되어 있었으나 내열수성시험 후에 관찰한 사진에서는 폴리머 결합재가 대부분 분해되어 있는 것을 관찰할 수 있었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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• pp.235-239
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• 1994

Polymer mortars are mainly used as protective coatings in concrete, reinforced concrete, and more rarely, steel, while polymer concretes represent a new type of structural material capable of withstanding highly corrosive environments. The mechanical properties, chemical stability, and some other useful properties are the reasons research, design, and production organizations. However polymer mortars and polymer concretes have been introduced only recently, and many of their properties are still imperfectly known. And, the main technique in producing polymer concrete is to minimize void volume in the aggregate mass so as to reduce the quantity of the relatively impressive polymer necessary for binding the aggregate. In this study, compressive strength and flexural strength of unsaturated polyester resin concrete are related to quantity of resin and solid volume of aggregate. It was founded that the more solid volume of aggregate increase, the less using quantity of resin decrease with out reducing mechnical properties. When solid volume ratio of aggregate is 70.6%, using quantity of resin is minimized to 10wt.%.