• 한국염색가공학회지
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• 제33권1호
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• pp.10-23
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• 2021

In order to synthesize the dye suitable for supercritical carbon dioxide(ScCO2) dyeing, a series of azo based disperse dyes were prepared using various aniline derivatives as diazo components and indol derivatives as coupling components. Dyeing process in ScCO2 of the synthesized dyes was performed on PET fiber at 120℃ for 2 hrs under 250bar pressure with 0.5% o.w.f. of dye concentration. The absorption maxima varied from 400 to 580nm depending on the substituted groups in aniline derivatives and the indol derivatives. The dyes showed high molar extinction coefficients(ε) of 27,000~61,000M-1cm-1. Dyed PET fiber exhibited excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

• 한국염색가공학회지
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• 제34권4호
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• pp.224-233
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• 2022

Recently, consumer tastes of various classes at home and abroad prefer comfortable, unadorned, and simple clothing, and the athleisure trend, which can be used freely in daily life as well as exercise, has expanded to overall clothing products. Existing materials used for athleisure are composite knitted fabrics using polyester yarn and PU yarn, which has problems due to a chronic lack of color fastness and contamination by dyes even when PU laminating is applied, making it difficult to apply various colors. There is a quality problem in which deformation of the product occurs due to lack of durability. In this study, CDP yarn(75de/72f) and PU yarn(40de) were selected to commercialize the circular knitting for athleisure using CDP yarn in order to solve the problems that occur in the dyeing and laminating process when using polyester materials. CDP yarns were used to knit into single(CP75-S) and double(CP75-D) knit and single knit were found to be suitable as athleisure fabrics. After pretreatment and treatment under various conditions, the stainability of CDP circular knitting was examined. After pretreatment and dyeing process under various conditions, the property of scouring and dyeability of CP75-S were evaluated.

• 한국염색가공학회지
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• 제30권1호
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• pp.20-28
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• 2018

The near infrared ray camouflage fabric has a near infrared ray reluctance similar to the surrounding environment and has a camouflage effect on the surrounding environment. Synthetic fibers used in military uniforms are difficult to have gastrointestinal function as general commercial dyes, unlike cellulose fibers, which use some commercial vat dyes to impart infrared gastrointestinal function. In this study, we optimized the adsorption pH, temperature and time for NIR dye application for polyester fabrics, and established the optimum concentration for the evaluation of adsorption build-up characteristics. In addition, it is difficult to adsorb it since the polyester material has a dense crystal structure and the NIR dye is bulky. Therefore, a swelling agent used for dyeing meta-aramid fibers with high Tg and high crystallinity was introduced as a separate preparation to increase the affinity to polyester, which is a hydrophobic fiber, to thereby obtain an excellent adsorption rate. As a result of comparing before and after using swelling agent, the adsorption rate difference was 10 times or more when compared with before.

• 한국염색가공학회지
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• 제13권6호
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• pp.391-396
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• 2001

The physical properties and the dyeability of the easily dyeable polyester yarn(EDY) were investigated and compared with those of regular polyester (REG-PET). The EDY, copolymerized with small amount of polyethylene glycol(PEG), showed higher intensity of aliphatic CH peak in IR spectrum, lower density and lower compactness than those of the REG-PET from the analysis of IR, density gradient column and XRD respectively. In the physical properties, the EDY has lowers $T_g$, $T_m$, specific stress and initial modulus, and also has higher strain than that of the REG-PET The EDY can be dyed under atmospheric pressure and its dyeing Fate was faster than REG-PET due to low $T_d$, and this seems to be caused by the increased flexibility of Polymer chain in amorphous region of the EDY due to the copolymerization of PEG.

• 한국염색가공학회지
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• 제12권4호
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• pp.233-238
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• 2000

In this study, the control system of sodium hydroxide was demonstrated to systemize hydrolysis process in polyester dyeing. We mainly focused on the application method of acid-alkali titration for the polyester hydrolysis machine of liquor-flow type. Industrial pH meter with electrode type was used for identifying equivalence point. Three units which were analogue-to-digital card, microprocessor and digital output card were used to control NaOH concentration in the control part of the system. The yielded data are translated to the microprocessor through analogue-digital interfacing card. After calculating, NaOH concentration in NaOH storage tank was controlled through the digital output card and solenoid valves.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2000년도 추계학술발표회 논문집
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• pp.177-182
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• 2000

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2007년도 추계학술발표회
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• pp.119-120
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• 2007

• 한국염색가공학회지
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• 제30권4호
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• pp.275-287
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• 2018

In recent years, research on the development of eco-friendly synthetic suede based on water-dispersed polyurethane resin and non-fluorine water repellent has been conducted. Synthetic suede has a problem that the fastness to dyeing is greatly lowered after the water-repellent processing at a high temperature of $160^{\circ}C$ because the polyester is dyed with a disperse dye. Therefore, in this study, silica was added to water-dispersed polyurethane resin to improve dye fastness. To distribute the $PUD-SiO_2$ mixture evenly in the water-dispersed polyurethane resin, sufficient stirring was done for a period of time. When the $PUD-SiO_2$ mixture(PUD 1-5%) is applied to the substrate, it is confirmed through SEM that the mixture is uniformly applied without particle condensation. The results showed that silica with a diameter of 4~12nm and BET of $200{\sim}380g/m^2$ had the ability to improve dispersibility and fastness.

• 한국염색가공학회지
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• 제31권4호
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• pp.258-267
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• 2019

Synthetic suede without PFCs(perfluorinated compounds) are followed by subsequent high temperature treatment. But migration fastness of synthetic suede may be reduced due to sublimation of disperse dyes that results from the high temperature treatment. Therefore, in this study, chitosan treatment was used to improve the migration fastness before polyurethane dipping process. Polyester fiber was treated with sodium hydroxide aqueous solution before chitosan processing. This samples treated with a chitosan concentration upto 0.5% were dyed and coated with PUD(polyurethane dispersion). The migration fastness was most improved at 0.35% application. This is presumably due to the fact that the chitosan may increase the dye-binding capability through intermolecular hydrogen bonding.

• Fibers and Polymers
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• 제4권1호
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• pp.32-37
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• 2003

The nonionic surfactant properties of ethoxylated azo dyes, such ai cloud point and surface tension have been investigated. The synthesized ethoxylated azo dyes could dye polyester fabric without any special pre-treatment. When the average number of ethylene oxide (EO) in the ethoxylated azo dye reached 6, its fixation could exceed $90^{\circ}C$ from the thermosol dyeing process. The average degree of condensation of ethylene glycol in the chain was interrelated with the dyeing results and did not affect on the maximum absorption wavelength (λmax) of the polyoxyethylene dye. When the average length of polyoxyethylene chain decreased, the molecular weight of dyes became smaller and the fixation of dyes was improved.