• 제목/요약/키워드: Polycrystalline structure

검색결과 388건 처리시간 0.028초

새로운 방법으로 제조된 적층구조 $BaTiO_3$ 박막의 전기적 특성에 관한 연구 (Study on the electric properties of layered $BaTiO_3$ films prepared new stacking method)

  • 송만호;이윤희;한택상;오명환;윤기현
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 하계학술대회 논문집 C
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    • pp.1129-1132
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    • 1995
  • In the preparation of the layered $BaTiO_3$ thin films with high performance, the new stacking method using the continuous cooling of the substrate was introduced. Amorphous/polycrystalline $BaTiO_3$ layered structure was confirmed by SEM and index of refraction. The layered $BaTiO_3$ thin films formed by the new stacking method showed such a high dielectric constant that the layered structure could not be explained by a stacking structure of the two defined layers but could only be explained by multi-layered structure, i.e. amorphous/micro crystalline/polycrystalline structure. The layered $BaTiO_3$ thin film with a thickness of 240 nm showed higher capacitance per unit area and breakdown strength than the double layered $BaTiO_3$ thin film prepared by the conventional stacking method. And well defined ferroelectric hysteresis leer was observed in the layered $BaTiO_3$ thin film with a thickness of 200 nm.

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GaAs Thin Films Grown on Conducting Glass by Hot Wall Epitaxy for Solar Cell

  • Tu, Jielei;Chen, Tingjin;Zhang, Chenjing;Shi, Zhaoshun;Wu, Changshu
    • Journal of Korean Vacuum Science & Technology
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    • 제6권2호
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    • pp.71-75
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    • 2002
  • GaAs polycrystalline thin films with good performance were prepared on conducting glass by hot wall epitaxy (HWE), which were used for solar cell. Electron probe micro-analyzer (EPMA) was applied for the composition, morphology of surface and cross-section of grown films, and X-ray diffraction (XRD) for their phase structure; Raman scattering spectum (RSS) and photoluminescence (PL) were used for evaluating their optical characteristics. The results show that, there is textured structure on the surface of grown GaAs polycrystalline films, which is greatly promised to be suitable for the candidate of solar cell with low cost and high efficiency. It is concluded that the source and substrate at temperature of 900 ~ 930 $\^{C}$ and 500 $\^{C}$ respectively would be beneficial for such films.

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Three Dimensionally Ordered Microstructure of Polycrystalline Zirconia Ceramics with Micro-Porosity

  • Chang, Myung Chul
    • 한국세라믹학회지
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    • 제53권1호
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    • pp.50-55
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    • 2016
  • In order to make a highly ordered three-dimensionally macro-porous structure of zirconia ceramics, porogen precursors PMMA beads were prepared by emulsion polymerization using acrylic monomer. The monodisperse PMMA latex beads were closely packed by centrifugation as a porogen template for the infiltration of zirconium acetate solution. The mixed compound of PMMA and zirconium acetate was dried. According to the firing schedule, dry compacts of PMMA and zirconium acetate were calcined at $475^{\circ}C$ to obtain micro-, macro-, and meso- structures of polycrystalline zirconia with monodispersed porosity. Inorganic frameworks composed of $ZrO_2$ were formed and showed a three Dimensionally Ordered Microstructure [3DOM] of $ZrO_2$ ceramics. The obtained $ZrO_2$ skeleton was calcined at $710^{\circ}C$. The 3DOM $ZrO_2$ skeleton showed color tuning in solutions such as deionized [DI] $H_2O$ and/or methanol. The monodispersed crystalline micro-structure with micro/meso porosity was observed by FE-SEM.

PFC법에 있어서의 Al-Cu 다결정리본의 응고특성 (Solidification Characteristics of Al-Cu Polycrystalline Ribbons in Planar Flow Casting)

  • 이경구;이상목;홍준표
    • 한국주조공학회지
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    • 제15권4호
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    • pp.408-415
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    • 1995
  • Polycrystalline Al-Cu ribbons were produced by planar flow casting(PFC). Solidification behavior and microstructual changes of the ribbons have been investigated as a function of ribbon thickness and processing parameters. The solidification front velocity, V varies within the ribbon, decreasing with increasing the distance, S from the wheel-contact surface, as $V=17.6S^{-1}$. In Al-4.5wt%Cu alloy, rapid decrease in solidification velocity toward the free surface causes a change in solidification morphology from planar to cellular, and finally, to dendritic. The length and inclination of columnar grains solidified with planar front were related to the wheel velocity. The transition from particulate degenerate eutectic structure to regular lamellar eutectic structure was observed to be caused by a difference of the relative growth velocites of ${\alpha}-Al$ and ${\theta}$ during solidification in the Al-Cu eutectic alloy.

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Control of secondary electron emission coefficient with microstructural change of polycrystalline MgO films

  • Yu, Hak-Ki;Lee, Jong-Lam;Park, Eung-Chul;Kim, Jae-Sung;Ryu, Jae-Hwa
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1445-1447
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    • 2008
  • Micro crystal structure of polycrystalline MgO film is controlled by adjusting the energy of particles arrived at the substrate during deposition. The change of crystal structure affects on the total area of (200) surface where the oxygen vacancies are formed easily, resulting in the change of secondary electron emission (SEE) coefficient($\gamma$).

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Three-Dimensional Crystallizing $\pi$-bondings and Uniaxial tensile deformation in polycrystalline

  • Oh, Hunk-Kuk
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1995년도 춘계학술대회논문집
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    • pp.252-263
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    • 1995
  • It is visualized that dislocations move straightly in polycrystalline structure and the trans-grain dislocation moving occur from yield point to ultimate tensile stress. Some fracturemodes in uniaxial tensile test are ilustrated in order to explain that after the ultimate point the grains deforms by twins and the rotations of grains make cracks at the grain-boundaries by the incompatibility . The luders banks. which propagates along the axis of the specimen, are twin bands whcih are formed by rearrangement of the atoms within the structure of three-dimensional crystallizing $\pi$-bondings. The fatigue limit can be found through the atom's rolling back motion during elastic deformation inthe uniaxial tensile test by the change of the gradient.

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페로브스카이형 Ba계열의 미세구조 특성 (A Study on Property of Microstructuree for Ba System of Perovskite Structure)

  • 송민종;동경래;김창복;최성관;박용순
    • 대한디지털의료영상학회논문지
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    • 제13권4호
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    • pp.185-189
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    • 2011
  • To assess the prevalence of various radiological reduction methods for childhood intussusception in training hospitals by means of a nationwide phone survey, and to demonstrate recent trends in this area by comparing the findings with those obtained in a survey conducted. $BaTiO_3$ system was prepared by using fabrication of classical conditioning ceramics. Polycrystalline and surface structure characteristics of the specimens were measured by X-ray diffraction, SEM(Scanning Electron Microscopy) and EDAX (Energy Dispersive Spectrometer), respectively.

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Calcite Production by Bacillus amyloliquefaciens CMB01

  • Lee, Young-Nam
    • Journal of Microbiology
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    • 제41권4호
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    • pp.345-348
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    • 2003
  • The bio-mediated production of calcite crystals by calcinogenic bacteria has great applicable value for the restoration of deteriorated calcareous monuments, because of its high purity and coherency. An investigation of the conditions for calcite production by an alkalophilic Bacillus amyloliquefaciens CMB01 strain was made. Optimal calcite precipitation occurred when the bacterium was cultured at pH 8.0 and 30$^{\circ}C$, and in B4 medium that consisted of 0.4% yeast extract, 0.5% glucose, and 1.5% calcium acetate. Calcium ion of the bacterially induced calcite was analyzed by an inductively coupled plasma (ICP) spectrophotometer. Optical and scanning electron microscopy (SEM) of the calcite revealed a typical rombohedral polycrystalline structure.

XPS Studies of Oxygen Adsorption on Polycrystalline Nickel Surface

  • Lee, Soon-Bo;Boo, Jin-Hyo;Ahn, Woon-Sun
    • Bulletin of the Korean Chemical Society
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    • 제8권5호
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    • pp.358-362
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    • 1987
  • The interaction of oxygen with polycrystalline nickel surface has been studied by investigating the X-ray photoelectron spectra of O 1s, Ni $2p_{3/2}$, and their valence band electrons. By comparing the oxygen exposure of this work with the reported results of LEED, AES, and work function measurements, it is found that the atomic oxygen, adsorbed dissociatively in the initial stage of exposure, is responsible for a p(2 ${\times}$ 2) structure and a subsequent c(2 ${\times}$ 2) structure on the Ni(100) surface. This dissociatively adsorbed oxygen species forms surface NiO layer subsequently on further oxygen exposure. The NiO layer is more easily formed with the increasing temperature. Non-stoichiometric oxygen species is also found to accompany the NiO layer. It appears prior to the formation of bulk NiO at all of the temperatures of this work except at 523K.